Conductometric Study of Nimesulide in Aqueous Solutions of Hydrotropic Agents at Different Temperatures

Conductance values of nimesulide have been determined in water in 0.1, 0.2, 0.4, 0.6, 0.8, 1 and 2 mol dm-3 aqueous solutions of hydrotropic agents (sodium benzoate, sodium salicylate, sodium bromide and nicotinamide) at temperatures 298.15, 303.15, 308.15 and 313.15 K. The conductance values have been used to evaluate the limiting molar conductance and association constants by means of Shedlovsky extrapolation technique. Thermodynamic parameters for the association process of nimesulide in aqueous solutions of hydrotropic agents have also been calculated

Characterization of microstructure, weld heat input, and mechanical properties of Mg−Al−Zn alloy GTA weldments

The present study investigated the influence of welding speed on the microstructure, hardness, and tensile properties of the AZ31 Mg alloy gas tungsten arc (GTA) welds that were prepared using alternating current (AC). A microstructural examination of the weld metal and base metal was performed using stereo, optical, and scanning electron microscopy (HR-SEM and EDS) techniques. The microstructure of all fusion zones consists of two parts: a columnar zone, adjacent to the fusion boundary, and equiaxed grains, in the centre of the weld fusion zone. It is shown that the average width of the equiaxed zone present at the centre of the fusion zone increases with increasing welding speed. Metallographic examination shows that the highest welding speed (5 mm/s) results in the smallest average grain size. The welds prepared with high welding speed exhibit an increase in strength, hardness, and ductility compared with other welding speeds, which is attributed to low heat input

Wear properties of metal matrix composites Al-Cu and Al-Cu-TiB2

Tensile and wear properties of aluminium (Al) based metal matrix composites (MMCs) was prepared by added titanium diboride (TiB2) with in-situ technique by salt route. The salts used in this research were potassium hexafluorotitanate (K2TiF6) and potassium tetrafluoroborate (KBF4). Nanocomposite samples were prepared by casting technique associated with incorporating 3 and 6 wt.% of TiB2 into matrix of Al-6wt.%Cu. Instron and wear tests machine were used to characterize the tensile and wear Al-Cu alloys properties. Results showed that increase in TiB2 content gave the high properties of tensile and wear behavior. The study indicates that TiB2 particles have giving improvement the wear performance of the Al–6wt.%Cu alloy. For a constant load and sliding speed, the wear rate decreases as a function of amount of TiB2 in the composite. The wear rate decrease with increasing in wt.% TiB2 particles for the all loads applied. However, addition of TiB2 particle to the Al–6 wt%. Cu matrix has show the coefficient value of wear decreases regardless of applied load. Study of the wear surfaces both alloy and composites by optical microscope suggests that the improvement in wear resistance is mainly due to the formation of finer groove or debris by content of TiB2

Mechanical properties of titanium-hydroxyapatite (Ti-HA) composite coating on stainless steel prepared by thermal spraying

Addition of hydroxyapatite (HA) can enhance the bioactivity of the common metallic implant due to its similarity with natural bones and teeth. In this investigation, high velocity oxy-fuel (HVOFT) technique was used to deposit titanium-hydroxyapatite (Ti-HA) composite on stainless steel substrate plate with different percentage of HA for biomedical applications. The aim of this research is to investigate the mechanical properties of Ti-HA coating such as hardness, adhesion strength and wear behaviour. The hardness and strength was determined by using SHIMADZU-microhardness Vickers tester and PosiTest AT portable adhesion tester respectively. The wear test was performed by using pin-on-disk equipment and field emission scanning electron microscope (FESEM) used to determine the extent of surface damage. From the results obtained, mechanical properties such as hardness and adhesion strength of titanium (Ti) coating decreased with the increased of HA contents. Meanwhile, the coefficient of friction of Ti-10% HA coating shows the highest value compare to others as three-body abrasion had occurred during the test

Preliminary study on properties of aluminium-silicon (Al-Si) alloys reinforced by in situ titanium diboride (TiB2)

Aluminum-silicon (Al-Si) alloys are an important class of materials, alloys which have great interested in wide industries whether in light or heavy industries, due to their superior properties like high strength to weight ratio, corrosion resistance, and excellent castability. The mechanical strength and the effect of modifying alloys have been studied. To evaluate the strength and revealed the structural of these alloys, the Instron tensile and Shimidzu Vickers hardness tester have been employed while the fracture surfaces have been observed by Scanning electron microscope (SEM). From results obtained, the microstructure of Al-Si with TiB 2 has much finer microstructure compared to unfine Al-Si alloy. It showed that the eutectic silicon microstructure in Al-Si alloy changed from needles-look or acicular to fine grain size or globular when the added of TiB 2 . The mechanical studies showed that the ductility of Al-Si alloy was much lower in the absence of grain refiner, TiB 2 . The tensile strength of unrefined Al-Si and Al-Si with 6 wt.%TiB 2 as grain refinement were recorded 275 and 312 MPa respectively. The hardness value for the unrefined Al-Si alloy also shows less compared with Al-Si with grain refiner, 6 wt.%TiB 2 , which are 74 and 78 MPa. This showed the results were significant improvements in mechanical properties have been obtained with the use of TiB 2 as grain refiner to Al-Si alloy

New heat treatment technique (tempering-austempered in single treatment) for matrix transformation and mechanical properties of ductile iron / Bulan Abdullah … [et al.]

A new heat treatment process which synthesized using the concepts from Austempered Ductile Cast Iron (ADI), Tempering and Quenching technology. The metallurgy of materials matrix transformation on each sequential cycle with different parameter such as time and temperature will be determine through the mechanical properties of ductile iron. Samples for the testing specimen will produce using the C02 casting. The compositions of samples will be determined by using the spectrometer machine. The heat treatment process consists of Quenching, Austempering and new developed heat treatment process with different parameter such as time and temperature. The new developed heat treatment process will be synthesized using the concepts from Austempered Ductile Cast Iron (ADI) and Quenching technology. The micro structure of specimens will be observed on each sequential cycle of heat treatment process. The chemical information of matrix surface will gain through the energy Dispersive X-Ray spectroscopy (EDX). The hardness, impact (ASTM E23), tensile (TS 138 EN10002-1) and density test were carried out before and after heat treatment process. The fracture surface of the tensile and impact samples will examine under Scanning Electron Microscope (SEM). A treatment process is expected possessed the better mechanical properties compared to conventional heat treatment can be used for the specific application that suite th

Characterisation of Microstructure and Mechanical Properties of Linear Friction Welded α+β Titanium Alloy to Nitinol

A variable area nozzle integrated into the design of a high-bypass-ratio turbofan engine effectively saves up to 10% in aircraft fuel consumption. Additionally, noise emissions can be lowered at airports during take-off and landing by having better control of the nozzle diameter. Shape memory capabilities of Nitinol alloys could be availed in the form of actuators in the construction of such a nozzle. However, these Nitinol actuators must be joined to Ti-6Al-4V, a prominent alloy making up most of the rest of the nozzle. Because of the huge differences in the physical and metallurgical properties of these alloys, fusion welding is not as effective as solid-state welding. In the current study, a linear friction welding process was adopted to join Ti-6Al-4V to Nitinol successfully. The effect of friction welding on the evolution of weld macro and microstructures; hardness and tensile properties were studied and discussed. The macrostructure of Ti-6Al-4V and Nitinol’s dissimilar joint revealed flash formation mainly on the Ti-6Al-4V side due to its reduced flow strength at high temperatures. Optical microstructures revealed fine grains in Ti-6Al-4V immediately adjacent to the interface due to dynamic recrystallisation and strain hardening effects. In contrast, Nitinol remained mostly unaffected. An intermetallic compound (Ti2Ni) was seen to have formed at the interface due to the extreme rubbing action, and these adversely influenced the tensile strength and elongation values of the joints

Conductometric Study of Nimesulide in Aqueous Solutions of Hydrotropic Agents at Different Temperatures

Conductance values of nimesulide have been determined in water in 0.1, 0.2, 0.4, 0.6, 0.8, 1 and 2 mol dm-3 aqueous solutions of hydrotropic agents (sodium benzoate, sodium salicylate, sodium bromide and nicotinamide) at temperatures 298.15, 303.15, 308.15 and 313.15 K. The conductance values have been used to evaluate the limiting molar conductance and association constants by means of Shedlovsky extrapolation technique. Thermodynamic parameters for the association process of nimesulide in aqueous solutions of hydrotropic agents have also been calculated

Influence of Microstructure and Mechanical Properties of Dissimilar Rotary Friction Welded Inconel to Stainless Steel Joints

The present study aims to evaluate the microstructure, grain size, and mechanical properties of the dissimilar AISI 316L/Inconel 718 (IN 718) rotary friction welded joints under both the as-welded and post-weld heat treatment (PWHT) conditions. Because of reduced flow strength at elevated temperatures, the AISI 316L and IN 718 dissimilar weldments exhibited more flash formation on the AISI 316L side. At higher rotating speeds during friction welding, an intermixing zone was created at the weld joint interface due to the material softening and squeezing. The dissimilar welds exhibited distinctive regions, including the fully deformed zone (FDZ), heat-affected zone (HAZ), thermo-mechanically affected zone (TMAZ), and the base metal (BM), located on either side of the weld interface. The dissimilar friction welds, AISI 316L/IN 718 ST and AISI 316L/IN 718 STA, exhibited yield strength (YS) of 634 ± 9 MPa and 602 ± 3 MPa, ultimate tensile strength (UTS) of 728 ± 7 MPa and 697± 2 MPa, and % elongation (% El) of 14 ± 1.5 and 17 ± 0.9, respectively. Among the welded samples, PWHT samples exhibited high strength (YS = 730 ± 2 MPa, UTS = 828 ± 5 MPa, % El = 9 ± 1.2), and this may be attributed to the formation of precipitates. Dissimilar PWHT friction weld samples resulted in the highest hardness among all the conditions in the FDZ due to the formation of precipitates. On the AISI 316L side, prolonged exposure to high temperatures during PWHT resulted in grain growth and decreased hardness. During the tensile test at ambient temperature, both the as-welded and PWHT friction weld joints failed in the HAZ regions of the AISI 316L side