Simultaneous Titrimetric Determination of La(lII) & Ce(IV) in Their Mixtures

518-52

Cation Exchange Sorption of Some Metal Ions from Aqueous Ammonium Acetate Medium: Separation of Ce(IV) from Ce(III), La(III) & Other Metal Ions

438-44

Global, regional, and national burden of disorders affecting the nervous system, 1990–2021: a systematic analysis for the Global Burden of Disease Study 2021

BackgroundDisorders affecting the nervous system are diverse and include neurodevelopmental disorders, late-life neurodegeneration, and newly emergent conditions, such as cognitive impairment following COVID-19. Previous publications from the Global Burden of Disease, Injuries, and Risk Factor Study estimated the burden of 15 neurological conditions in 2015 and 2016, but these analyses did not include neurodevelopmental disorders, as defined by the International Classification of Diseases (ICD)-11, or a subset of cases of congenital, neonatal, and infectious conditions that cause neurological damage. Here, we estimate nervous system health loss caused by 37 unique conditions and their associated risk factors globally, regionally, and nationally from 1990 to 2021.MethodsWe estimated mortality, prevalence, years lived with disability (YLDs), years of life lost (YLLs), and disability-adjusted life-years (DALYs), with corresponding 95% uncertainty intervals (UIs), by age and sex in 204 countries and territories, from 1990 to 2021. We included morbidity and deaths due to neurological conditions, for which health loss is directly due to damage to the CNS or peripheral nervous system. We also isolated neurological health loss from conditions for which nervous system morbidity is a consequence, but not the primary feature, including a subset of congenital conditions (ie, chromosomal anomalies and congenital birth defects), neonatal conditions (ie, jaundice, preterm birth, and sepsis), infectious diseases (ie, COVID-19, cystic echinococcosis, malaria, syphilis, and Zika virus disease), and diabetic neuropathy. By conducting a sequela-level analysis of the health outcomes for these conditions, only cases where nervous system damage occurred were included, and YLDs were recalculated to isolate the non-fatal burden directly attributable to nervous system health loss. A comorbidity correction was used to calculate total prevalence of all conditions that affect the nervous system combined.FindingsGlobally, the 37 conditions affecting the nervous system were collectively ranked as the leading group cause of DALYs in 2021 (443 million, 95% UI 378–521), affecting 3·40 billion (3·20–3·62) individuals (43·1%, 40·5–45·9 of the global population); global DALY counts attributed to these conditions increased by 18·2% (8·7–26·7) between 1990 and 2021. Age-standardised rates of deaths per 100 000 people attributed to these conditions decreased from 1990 to 2021 by 33·6% (27·6–38·8), and age-standardised rates of DALYs attributed to these conditions decreased by 27·0% (21·5–32·4). Age-standardised prevalence was almost stable, with a change of 1·5% (0·7–2·4). The ten conditions with the highest age-standardised DALYs in 2021 were stroke, neonatal encephalopathy, migraine, Alzheimer's disease and other dementias, diabetic neuropathy, meningitis, epilepsy, neurological complications due to preterm birth, autism spectrum disorder, and nervous system cancer.InterpretationAs the leading cause of overall disease burden in the world, with increasing global DALY counts, effective prevention, treatment, and rehabilitation strategies for disorders affecting the nervous system are needed

Cation exchange chromatographic separation of a number of metal ions in ammonium iodide media

901-902The cation exchange behaviour of 11metal ions in NH4I at various concentrations (0.096-2.08 M) has been studied with Dowex 50W-X4 resin (200-400 Mesh, NH-form). The distribution coefficients are determined by batch technique to evaluate the conditions for column chromatographic separation. A number of binary, ternary and quaternary separation of synthetic mixtures have been reported

Anion exchange selectivities of Zn(II), Cd(II), Hg(II) and Ba(II) in KI solutions

285-287Potassium iodide provides a suitable medium for the anion exchange separation of a number of binary, ternary and quaternary metal ion mixtures. The procedure is rapid, convenient and is based on the quantitative formation of the anionic species [MI4]2-, in which Cd(II) and Hg(II) separations have been achieved from other metal ions. The separations are clear cut and the method can be applied for the removal and isolation of mercury by the conventional anion exchanger instead of using a chelating type where the elution process is rather difficult

Development of spatially diverse and complex dune-field patterns: Gran Desierto Dune Field, Sonora, Mexico

The pattern of dunes within the Gran Desierto of Sonora, Mexico, is both spatially diverse and complex. Identification of the pattern components from remote-sensing images, combined with statistical analysis of their measured parameters demonstrate that the composite pattern consists of separate populations of simple dune patterns. Age-bracketing by optically stimulated luminescence (OSL) indicates that the simple patterns represent relatively short-lived aeolian constructional events since ~25 ka. The simple dune patterns consist of: (i) late Pleistocene relict linear dunes; (ii) degraded crescentic dunes formed at ~12 ka; (iii) early Holocene western crescentic dunes; (iv) eastern crescentic dunes emplaced at ~7 ka; and (v) star dunes formed during the last 3 ka. Recognition of the simple patterns and their ages allows for the geomorphic backstripping of the composite pattern. Palaeowind reconstructions, based upon the rule of gross bedform-normal transport, are largely in agreement with regional proxy data. The sediment state over time for the Gran Desierto is one in which the sediment supply for aeolian constructional events is derived from previously stored sediment (Ancestral Colorado River sediment), and contemporaneous influx from the lower Colorado River valley and coastal influx from the Bahia del Adair inlet. Aeolian constructional events are triggered by climatic shifts to greater aridity, changes in the wind regime, and the development of a sediment supply. The rate of geomorphic change within the Gran Desierto is significantly greater than the rate of subsidence and burial of the accumulation surface upon which it rests

Paleoecology reconstruction from trapped gases in a fulgurite from the late Pleistocene of the Libyan Desert

When lightning strikes the ground, it heats, melts, and fuses the sand in soils to form glass tubes known as fulgurites. We report here the composition of CO<SUB>2</SUB>, CO, and NO contained within the glassy bubbles of a fulgurite from the Libyan Desert. The results show that the fulgurite formed when the ground contained 0.1 wt% organic carbon with a C/N ratio of 10-15 and a δ<SUP>13</SUP>C of −13.96‰, compositions similar to those found in the present-day semiarid region of the Sahel, where the vegetation is dominated by C<SUB>4</SUB> plants. Thermoluminescence dating indicates that this fulgurite formed ~15 k.y. ago. These results imply that the semiarid Sahel (at 17°N) reached at least to 24°N at this time, and demonstrate that fulgurite gases and luminescence geochronology can be used in quantitative paleoecology

Numerical dating of a Late Quaternary spit-shoreline complex at the northern end of Silver Lake playa, Mojave Desert, California: a comparison of the applicability of radiocarbon, luminescence, terrestrial cosmogenic nuclide, electron spin resonance, U-series and amino acid racemization methods

A Late Quaternary spit-shoreline complex on the northern shore of Pleistocene Lake Mojave of southeastern California, USA was studied with the goal of comparing accelerator mass spectrometry (AMS) radiocarbon, luminescence, electron spin resonance (ESR), terrestrial cosmogenic radionuclide (TCN) surface exposure, amino acid racemization (AAR) and U-series dating methods. The pattern of ages obtained by the different methods illustrates the complexity of processes acting in the lakeshore environment and highlights the utility of a multi-method approach. TCN surface exposure ages (mostly ~20-30 ka) record the initial erosion of shoreline benches, whereas radiocarbon ages on shells (determined in this and previous studies) within the spit, supported by AAR data, record its construction at fluctuating lake levels from ~16 to 10 ka. Luminescence ages on spit sediment (~6-7 ka) and ESR ages on spit shells (~4 ka) are anomalously young relative to radiocarbon ages of shells within the same deposits. The significance of the surprisingly young luminescence ages is not clear. The younger ESR ages could be a consequence of post-mortem enrichment of U in the shells. High concentrations of detrital thorium in tufa coating spit gravels inhibited the use of single-sample U-series dating. Detailed comparisons such as this provide one of the few means of assessing the accuracy of Quaternary dating techniques. More such comparisons are needed