174 research outputs found
Total Synthesis of a Dimeric Thymol Derivative Isolated from Arnica sachalinensis
The total synthesis of a dimeric thymol derivative (thymarnicol) isolated from Arnica sachalinensis was accomplished in 6 steps. A key biomimetic DielsâAlder dimerization was found to occur at ambient temperature and the final oxidative cyclization occurs when the substrate is exposed to air and visible light. These results indicate that this natural product is likely the result of spontaneous (nonâenzymeâmediated) reactivity
ChemInform Abstract: Synthesis of 2,4-Disubstituted 2,3-Dihydro-1H-1,5-benzodiazepines (III) in the 1,3-Indandione Series.
ChemInform Abstract: DIE CHEMIE DES BENZO(B)SELENOPHENS 5. MITT. DIE MERCURIERUNG VON BENZO(B)SELENOPHEN
ChemInform Abstract: Theoretical Investigation of a Pd(phosphine)2 Group as a Donor Towards [70]Fullerene. Pyramidalized Ethylenes as a Model of Different Sites on [70]Fullerene Surface
ChemInform Abstract: ELECTROPHILIC ADDITION OF TETRAMETHYLENEBROMOSELENONIUM BROMIDE TO OLEFINS
ChemInform Abstract: Palladium-Polypyrrole Nanoparticles-Catalyzed Sonogashira Coupling.
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