5,140 research outputs found
Enhancement of perfluorooctanoate and perfluorooctanesulfonate activity at acoustic cavitation bubble interfaces
Acoustic cavitation driven by ultrasonic irradiation decomposes and mineralizes the recalcitrant perfluorinated surfactants perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA). Pyrolytic cleavage of the ionic headgroup is the rate-determining step. In this study, we examine the sonochemical adsorption of PFOX, where X = S for PFOS and A for PFOA, by determining kinetic order and absolute rates over an initial PFOX concentration range of 20 nM to 200 μM. Sonochemical PFOX kinetics transition from pseudo-first-order at low initial concentrations, [PFOX]_i 40 μM, as the bubble interface sites are saturated. At PFOX concentrations below 100 μM, concentration-dependent rates were modeled with Langmuir−Hinshelwood (LH) kinetics. Empirically determined rate maximums, V_(Max)^(−PFOA) = 2230 ± 560 nM min^−1 and V_(Max)^(−PFOS) = 230 ± 60 nM min^−1, were used in the LH model, and sonochemical surface activities were estimated to be K_(Sono)^(PFOS) = 120000 M^−1 and K_(Sono)^(PFOA) = 28500 M^−1, 60 and 80 times greater than equilibrium surface activities, K_(Eq)^(PFOS) and K_(Eq)^(PFOA). These results suggest enhanced sonochemical degradation rates for PFOX when the bubble interface is undersaturated. The present results are compared to previously reported sonochemical kinetics of nonvolatile surfactants
COMPARING FUNCTIONAL DATA ANALYSIS AND HYSTERESIS LOOPS WHEN TESTING TREATMENTS FOR REDUCING HEAT STRESS IN DAIRY COWS
Various techniques are commonly used to reduce heat stress, including sprayers and misters, shading, and changes in feed. Oftentimes studies are performed where researchers do not control the times when animals use shading or other means available to reduce heat stress, making it hard to test differences between treatments. Two methods are used on data from a study where Holstein cows were given free access to weight activated “cow showers.” Functional data analysis can be used to model body temperature as a function of time and environmental variables such as the Heat Load Index. Differences between treatment groups can be tested using a Functional Bayesian MCMC model. Alternatively hysteresis loops, such as the ellipse, formed by a plot of air temperature or the Heat Load Index against body temperature over the course of a day can be estimated and their parameters used to test differences between cows with access to showers and cows without. Results from an R package hysteresis, which can estimate these loops and their parameters are illustrated. Functional data analysis allows for looser assumptions regarding the body temperature curve and the ability to look for differences between groups at specific time points, while hysteresis loops give the ability to look at heat stress over the course of a day holistically in terms of parameters such as amplitude, lag, internal heat load and central values
COMPARISON OF SAS PROC NLIN AND NLMIXED FOR PARAMETER ESTIMATION IN PET MODEL
Cattle body temperatures were measured under semi-controlled hot cyclic chamber temperatures. The four-parameter nonlinear PET model, is used to estimate body temperature in cattle challenged by heat stress. For each steer, the parameters can be estimated by the Nlin procedure and the sensitivity of each animal can be studied. It is also desirable to generalize the results by using the Nlmixed procedure to combine both the fixed and random effects. When comparing the results from the two procedures, we found heterogeneity among animals and/or days caused convergence problems for proc Nlmixed. Simulation studies were used to study how deviations from homogeneity effected the accuracy of parameter estimates, coverage of confidence intervals, and measures of nonlinear behavior when using the PET model to describe the dynamics of heat stress in cattle
Solution processed amorphous silicon surface passivation layers
Amorphous silicon thin films, fabricated by thermal conversion of neopentasilane, were used to passivate crystalline silicon surfaces. The conversion is investigated using X ray and constant final state yield photoelectron spectroscopy, and minority charge carrier lifetime spectroscopy. Liquid processed amorphous silicon exhibits high Urbach energies from 90 to 120 meV and 200 meV lower optical band gaps than material prepared by plasma enhanced chemical vapor deposition. Applying a hydrogen plasma treatment, a minority charge carrier lifetime of 1.37 ms at an injection level of 1015 cm3 enabling an implied open circuit voltage of 724 mV was achieved, demonstrating excellent silicon surface passivatio
The K-Band Galaxy Luminosity Function
We measured the K-band luminosity function using a complete sample of 4192
morphologically-typed 2MASS galaxies with 7 < K < 11.25 mag spread over 2.12
str. Early-type (T -0.5) galaxies have similarly
shaped luminosity functions, alpha_e=-0.92+/-0.10 and alpha_l=-0.87+/-0.09. The
early-type galaxies are brighter, M_*e=-23.53+/-0.06 mag compared to
M_*l=-22.98\pm0.06 mag, but less numerous, n_*e=(0.0045+/-0.0006)h^3/Mpc^3
compared to n_*l=(0.0101+/-0.0013)h^3/Mpc^3 for H_0=100h km/s Mpc, such that
the late-type galaxies slightly dominate the K-band luminosity density,
j_late/j_early=1.17+/-0.12. Our morphological classifications are internally
consistent, consistent with previous classifications and lead to luminosity
functions unaffected by the estimated uncertainties in the classifications.
These luminosity functions accurately predict the K-band number counts and
redshift distributions for K < 18 mag, beyond which the results depend on
galaxy evolution and merger histories.Comment: submitted to ApJ, 25 pages, 6 figures, complete redshift survey.
Table 1 included in sourc
CHARACTERIZING THERMAL HYSTERESIS IN BODY TEMPERATURE FOR A HEAT STRESSED STEER
Studies have shown that exposure of animals to a high ambient temperature environment poses serious threats to their health, performance and productivity. Above a certain threshold an animal\u27s body temperature (Tb) appears to be driven by the hot ambient temperature (Ta). For steers challenged by heat stress, the Tb-Ta relationship shows a dramatic increase in Tb per unit change of Ta and the dynamics of the Tb-Ta relationship follow a pattern which depends on whether Ta is increasing or decreasing. A delay becomes noticeable in a steer’s thermo-regulatory response to Ta when Ta is controlled to be sinusoidal in the steer’s heat stress chamber. In other words, Tb lags behind Ta. Consequently when plotted in a Tb-Ta phase diagram, a hysteresis effect appears in the form of a hysteresis loop, indicating the steer is thermally challenged. The hysteresis loop shows a rotated elliptical pattern which depends on the delay (or lag) between Tb and Ta. The angle of rotation of the hysteresis loop indicates the correlation (and lag) between Tb and Ta. The area of the elliptical hysteresis loop can be used to quantify the amount of heat stress during the period of thermal challenge. For example, results of a thermal challenge of 32±7oC applied to a Hereford steer showed, the delay is longer (4 hr lag) and ellipse is larger in an acute stage than in a chronic stage (3 hr lag). A greater delay (or lag) suggests more time is needed to dissipate the heat stress. This result suggests, steers in an acute stage require more energy to dissipate heat than steers in a chronic stage
Connectivity and tree structure in finite graphs
Considering systems of separations in a graph that separate every pair of a
given set of vertex sets that are themselves not separated by these
separations, we determine conditions under which such a separation system
contains a nested subsystem that still separates those sets and is invariant
under the automorphisms of the graph.
As an application, we show that the -blocks -- the maximal vertex sets
that cannot be separated by at most vertices -- of a graph live in
distinct parts of a suitable tree-decomposition of of adhesion at most ,
whose decomposition tree is invariant under the automorphisms of . This
extends recent work of Dunwoody and Kr\"on and, like theirs, generalizes a
similar theorem of Tutte for .
Under mild additional assumptions, which are necessary, our decompositions
can be combined into one overall tree-decomposition that distinguishes, for all
simultaneously, all the -blocks of a finite graph.Comment: 31 page
Generalized Interpolation Material Point Approach to High Melting Explosive with Cavities Under Shock
Criterion for contacting is critically important for the Generalized
Interpolation Material Point(GIMP) method. We present an improved criterion by
adding a switching function. With the method dynamical response of high melting
explosive(HMX) with cavities under shock is investigated. The physical model
used in the present work is an elastic-to-plastic and thermal-dynamical model
with Mie-Gr\"uneissen equation of state. We mainly concern the influence of
various parameters, including the impacting velocity , cavity size , etc,
to the dynamical and thermodynamical behaviors of the material. For the
colliding of two bodies with a cavity in each, a secondary impacting is
observed. Correspondingly, the separation distance of the two bodies has a
maximum value in between the initial and second impacts. When the
initial impacting velocity is not large enough, the cavity collapses in a
nearly symmetric fashion, the maximum separation distance increases
with . When the initial shock wave is strong enough to collapse the cavity
asymmetrically along the shock direction, the variation of with
does not show monotonic behavior. Our numerical results show clear indication
that the existence of cavities in explosive helps the creation of ``hot
spots''.Comment: Figs.2,4,7,11 in JPG format; Accepted for publication in J. Phys. D:
Applied Physic
Distance and the pattern of intra-European trade
Given an undirected graph G = (V, E) and subset of terminals T ⊆ V, the element-connectivity κ ′ G (u, v) of two terminals u, v ∈ T is the maximum number of u-v paths that are pairwise disjoint in both edges and non-terminals V \ T (the paths need not be disjoint in terminals). Element-connectivity is more general than edge-connectivity and less general than vertex-connectivity. Hind and Oellermann [21] gave a graph reduction step that preserves the global element-connectivity of the graph. We show that this step also preserves local connectivity, that is, all the pairwise element-connectivities of the terminals. We give two applications of this reduction step to connectivity and network design problems. • Given a graph G and disjoint terminal sets T1, T2,..., Tm, we seek a maximum number of elementdisjoint Steiner forests where each forest connects each Ti. We prove that if each Ti is k element k connected then there exist Ω( log hlog m) element-disjoint Steiner forests, where h = | i Ti|. If G is planar (or more generally, has fixed genus), we show that there exist Ω(k) Steiner forests. Our proofs are constructive, giving poly-time algorithms to find these forests; these are the first non-trivial algorithms for packing element-disjoint Steiner Forests. • We give a very short and intuitive proof of a spider-decomposition theorem of Chuzhoy and Khanna [12] in the context of the single-sink k-vertex-connectivity problem; this yields a simple and alternative analysis of an O(k log n) approximation. Our results highlight the effectiveness of the element-connectivity reduction step; we believe it will find more applications in the future
All Oxide Ferromagnet/Semiconductor Epitaxial Heterostructures
Oxide based ferromagnet/semiconductor heterostructures offer substantial
advantages for spin electronics. We have grown (111) oriented Fe3O4 thin films
and Fe3O4/ZnO heterostructures on ZnO(0001) and Al2O3(0001) substrates by
pulsed laser deposition. High quality crystalline films with mosaic spread as
small as 0.03 degree, sharp interfaces, and rms surface roughness of 0.3 nm
were achieved. Magnetization measurements show clear ferromagnetic behavior of
the magnetite layers with a saturation magnetization of 3.2 muB/f.u. at 300 K.
Our results demonstrate that the Fe3O4/ZnO system is an intriguing and
promising candidate for the realization of multi-functional heterostructures.Comment: 4 pages, 3 figure
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