WSi 2 /Si multilayer sectioning by reactive ion etching for multilayer Laue lens fabrication

SPIE Conference paper/talk presentation: Introduction: Reactive ion etching (RIE) has been employed in a wide range of fields such as semiconductor fabrication, MEMS (microelectromechanical systems), and refractive x-ray optics with a large investment put towards the development of deep RIE. Due to the intrinsic differing chemistries related to reactivity, ion bombardment, and passivation of materials, the development of recipes for new materials or material systems can require intense effort and resources. For silicon in particular, methods have been developed to provide reliable anisotropic profiles with good dimensional control and high aspect ratios1,2,3, high etch rates, and excellent material to mask etch selectivity..

Exciton spectroscopy of hexagonal boron nitride using non-resonant x-ray Raman scattering

We report non-resonant x-ray Raman scattering (XRS) measurements from hexagonal boron nitride for transferred momentum from 2 to 9 $\mathrm{\AA}^{-1}$ along directions both in and out of the basal plane. A symmetry-based argument, together with real-space full multiple scattering calculations of the projected density of states in the spherical harmonics basis, reveals that a strong pre-edge feature is a dominantly $Y_{10}$-type Frenkel exciton with no other \textit{s}-, \textit{p}-, or \textit{d}- components. This conclusion is supported by a second, independent calculation of the \textbf{q}-dependent XRS cross-section based on the Bethe-Salpeter equation

Hard x ray spectroscopy and imaging by a reflection zone plate in the presence of astigmatism

The feasibility of an off axis x ray reflection zone plate to perform wavelength dispersive spectroscopy, on axis point focusing, and two dimensional imaging is demonstrated by means of one and the same diffractive optical element DOE at a synchrotron radiation facility. The resolving power varies between 30 and 400 in the range of 7.6 keV to 9.0 keV, with its maximum at the design energy of 8.3 keV. This result is verified using an adjustable entrance slit, by which horizontal H and vertical V focusing to 0.85 amp; 956;m H and 1.29 amp; 956;m V is obtained near the sagittal focal plane of the astigmatic configuration. An angular and axial scan proves an accessible field of view of at least 0.6 arcmin 0.8 arcmin and a focal depth of plus minus 0.86 mm. Supported by the grating efficiency of around 17.5 and a very short pulse elongation, future precision x ray fluorescence and absorption studies of transition metals at their K edge on an ultrashort timescale could benefit from our finding

Takagi-Taupin Description of X-ray Dynamical Diffraction from Diffractive Optics with Large Numerical Aperture

We present a formalism of x-ray dynamical diffraction from volume diffractive optics with large numerical aperture and high aspect ratio, in an analogy to the Takagi-Taupin equations for strained single crystals. We derive a set of basic equations for dynamical diffraction from volume diffractive optics, which enable us to study the focusing property of these optics with various grating profiles. We study volume diffractive optics that satisfy the Bragg condition to various degrees, namely flat, tilted and wedged geometries, and derive the curved geometries required for ultimate focusing. We show that the curved geometries satisfy the Bragg condition everywhere and phase requirement for point focusing, and effectively focus hard x-rays to a scale close to the wavelength.Comment: 18 pages, 12 figure

Laterally graded multilayer double-monochromator.

The authors describe a tunable multilayer monochromator with an adjustable bandpass to be used for reflectivity and grazing incidence diffraction studies on surfaces at energies near 10 keV. Multilayers have a bandpass typically 100 times larger than the Si(111) reflection, and by using multilayers an experimenter can significantly increase data collection rates over those available with a Si monochromator. The transmission through 1 and 2 laterally graded multilayer (LGML) reflections was recorded versus photon energy. The identical LGMLs were comprised of 60 bilayers of W and C on 100 x 25 x 3 mm float glass with a bilayer spacing varying from 35 to 60 {angstrom}. The average gradient was 0.27 {angstrom}/mm along the long dimension. The rms deviation of the data for the bilayer spacing from a linear fit was 0.36 {angstrom}. Data were obtained for a nondispersive ({+-}) double-multilayer arrangement. The relative bandpass width (FWHM) when the two multilayers exposed the same bilayer spacing was measured to be 2.2% with a transmission of 78.7 {+-} 1.6%. This value is consistent with the transmission of 88.9% that they also measured for a single LGML at HASYLAB beamline D4. The bandpass was tunable in the range 1.1% to 2.2%

Upstream sources of the Denmark Strait Overflow : observations from a high-resolution mooring array

© The Author(s), 2016. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part I: Oceanographic Research Papers 112 (2016): 94-112, doi:10.1016/j.dsr.2016.02.007.We present the first results from a densely instrumented mooring array upstream of the Denmark Strait sill, extending from the Iceland shelfbreak to the Greenland shelf. The array was deployed from September 2011 to July 2012, and captured the vast majority of overflow water denser than 27.8 kgm-3 approaching the sill. The mean transport of overflow water over the length of the deployment was 3.54 ± 0.16 Sv. Of this, 0.58 Sv originated from below sill depth, revealing that aspiration takes place in Denmark Strait. We confirm the presence of two main sources of overflow water: one approaching the sill in the East Greenland Current and the other via the North Icelandic Jet. Using an objective technique based on the hydrographic properties of the water, the transports of these two sources are found to be 2.54 ± 0.17 Sv and 1.00 ± 0.17 Sv, respectively. We further partition the East Greenland Current source into that carried by the shelfbreak jet (1.50 ± 0.16 Sv) versus that transported by a separated branch of the current on the Iceland slope (1.04 ± 0.15 Sv). Over the course of the year the total overflow transport is more consistent than the transport in either branch; compensation takes place among the pathways that maintains a stable total overflow transport. This is especially true for the two East Greenland Current branches whose transports vary out of phase with each other on weekly and longer time scales. We argue that wind forcing plays a role in this partitioning.The mooring and analysis work was supported by NSF OCE research grants OCE-0959381 and OCE-1433958, by the European Union 7th Framework Programme (FP7 2007-2013) under grant agreement n. 308299 NACLIM, and and by the Research Council of Norway through the Fram Centre Flaggship project 6606-299.2017-03-2

Upstream sources of the Denmark Strait Overflow : observations from a high-resolution mooring array

© The Author(s), 2016. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Deep Sea Research Part I: Oceanographic Research Papers 112 (2016): 94-112, doi:10.1016/j.dsr.2016.02.007.We present the first results from a densely instrumented mooring array upstream of the Denmark Strait sill, extending from the Iceland shelfbreak to the Greenland shelf. The array was deployed from September 2011 to July 2012, and captured the vast majority of overflow water denser than 27.8 kgm-3 approaching the sill. The mean transport of overflow water over the length of the deployment was 3.54 ± 0.16 Sv. Of this, 0.58 Sv originated from below sill depth, revealing that aspiration takes place in Denmark Strait. We confirm the presence of two main sources of overflow water: one approaching the sill in the East Greenland Current and the other via the North Icelandic Jet. Using an objective technique based on the hydrographic properties of the water, the transports of these two sources are found to be 2.54 ± 0.17 Sv and 1.00 ± 0.17 Sv, respectively. We further partition the East Greenland Current source into that carried by the shelfbreak jet (1.50 ± 0.16 Sv) versus that transported by a separated branch of the current on the Iceland slope (1.04 ± 0.15 Sv). Over the course of the year the total overflow transport is more consistent than the transport in either branch; compensation takes place among the pathways that maintains a stable total overflow transport. This is especially true for the two East Greenland Current branches whose transports vary out of phase with each other on weekly and longer time scales. We argue that wind forcing plays a role in this partitioning.The mooring and analysis work was supported by NSF OCE research grants OCE-0959381 and OCE-1433958, by the European Union 7th Framework Programme (FP7 2007-2013) under grant agreement n. 308299 NACLIM, and and by the Research Council of Norway through the Fram Centre Flaggship project 6606-299.2017-03-2

Achieving hard X-ray nanofocusing using a wedged multilayer Laue lens

We report on the fabrication and the characterization of a wedged multilayer Laue lens for x-ray nanofocusing. The lens was fabricated using a sputtering deposition technique, in which a specially designed mask was employed to introduce a thickness gradient in the lateral direction of the multilayer. X-ray characterization shows an efficiency of 27% and a focus size of 26 nm at 14.6 keV, in a good agreement with theoretical calculations. These results indicate that the desired wedging is achieved in the fabricated structure. We anticipate that continuous development on wedged MLLs will advance x-ray nanofocusing optics to new frontiers and enrich capabilities and opportunities for hard X-ray microscopy