132 research outputs found
Challenges and opportunities for the utilisation of ionic liquids as solvents for CO2 capture
Ionic Liquids have been extensively investigated as promising materials for several gas separation processes, including CO 2 capture. They have the potential to outperform traditional solvents, in terms of their capacity, selectivity, regenerability and stability. In fact, hundreds of ionic liquids have been investigated as potential sorbents for CO 2 capture. However, most studies focus on enhancing equilibrium capacity, and neglect to consider other properties, such as transport prop- erties, and hence ignore the effect that the overall set of properties have on process performance, and therefore on cost. In this study, we propose a new methodology for their evaluation using a range of monetised and non-monetised process performance indices. Our results demonstrate that whilst most research effort is focused on improving CO 2 solubility, viscosity, a transport prop- erty, and heat capacity, a thermochemical property, might preclude the use of ionic liquids, even those which are highly CO 2 -philic, and therefore increased effort on addressing the challenges associated with heat capacity and viscosity is an urgent necessity. This work highlights a range of potential challenges that ionic liquids will face before they can be applied at process scale, and identifies some key research opportunities
Recognizing the value of collaboration in delivering carbon dioxide removal
In delivering the Paris climate target, bioenergy with carbon capture and storage (BECCS) is likely to play an important role, both as a climate mitigation and a carbon dioxide removal technology. However, regional drivers of BECCS sustainability and cost remain broadly unknown and the regional attribution of a global CO2 removal burden remains largely undetermined. This study explores the mechanisms behind cost-optimal BECCS deployment with evolving regional CO2 removal targets and energy sectors to provide insights into the ways in which different regional players will interact as a function of their bio-geophysical endowments and their ability to trade these assets. An important finding is that inter-regional cooperationâin choosing the right burden-sharing principle to establish regional targetsâand collaborationâin trading negative emissions credits and biomassâare central to sustainably and affordably meeting these targets. This multilateralism in biomass and carbon credits trading constitutes important value creation opportunities for key providers of CO2 removal.The authors thank Imperial College London for the funding of a President's PhD Scholarship, as well as the Greenhouse Gas Removal (GGR) grant, funded by the Natural Environment Research Council (NERC), under grant NE/P019900/1. The authors also thank Solène Chiquier from Imperial College London for curating the CO2 storage capacity dataset
A novel methodological approach for achieving $/MWh cost reduction of CO2 capture and storage (CCS) processes
Carbon capture and storage is widely recognised as essential for the cost effective decarbonisation of the power and industrial sectors. However its capital and operating costs remain a barrier to deployment, with significant reduction in the cost per unit of decarbonised product considered vital. In the context of power generation, this is best expressed in terms of cost per MWh of electricity generated. To achieve a meaningful reduction in the cost of low carbon electricity, capital costs must also be reduced. Thus, this work presents a novel approach for identifying system improvements via a combination of process integration and intensification based on minimisation of thermodynamic losses. Application of this methodology to an oxy-combustion CCS process led to a 3% increase of net efficiency and a 13% reduction of ÂŁ/MWh of electricity
Quantifying the Value of CCS for the Future Electricity System
Many studies have quantified the cost of Carbon Capture and Storage (CCS) power plants, but relatively few discuss or appreciate the unique value this technology provides to the electricity system. CCS is routinely identified as a key factor in least-cost transitions to a low-carbon electricity system in 2050, one with significant value by providing dispatchable and low-carbon electricity. This paper investigates production, demand and stability characteristics of the current and future electricity system. We analyse the Carbon Intensity (CI) of electricity systems composed of unabated thermal (coal and gas), abated (CCS), and wind power plants for different levels of wind availability with a view to quantifying the value to the system of different generation mixes. As a thought experiment we consider the supply side of a UK-sized electricity system and compare the effect of combining wind and CCS capacity with unabated thermal power plants. The resulting capacity mix, system cost and CI are used to highlight the importance of differentiating between intermittent and firm low-carbon power generators. We observe that, in the absence of energy storage or demand side management, the deployment of intermittent renewable capacity cannot significantly displace unabated thermal power, and consequently can achieve only moderate reductions in overall CI. A system deploying sufficient wind capacity to meet peak demand can reduce CI from 0.78 tCO2 /MWh, a level according to unabated fossil power generation, to 0.38 tCO2 /MWh. The deployment of CCS power plants displaces unabated thermal plants, and whilst it is more costly than unabated thermal plus wind, this system can achieve an overall CI of 0.1 tCO2 /MWh. The need to evaluate CCS using a systemic perspective in order to appreciate its unique value is a core conclusion of this study
Techno-economic feasibility of grid-independent residential roof-top solar PV systems in Muscat, Oman
Oman is a country characterised by high solar availability, yet very little electricity is produced using solar energy. As the residential sector is the largest consumer of electricity in Oman, we develop a novel approach, using houses in Muscat as a case study, to assess the potential of implementing roof-top solar PV/battery technologies, that operate without recourse to the electricity grid. Such systems target the complete decarbonisation of electricity demand per household and are defined in this study as grid-independent systems. The approach adopted starts with a technical assessment of grid-independent systems that evaluates the characteristics of the solar panel and the battery facility required to provide grid-independence. This is then compared to a similar grid-connected system and any techno-economic targets necessary to enhance the feasibility of residential roof-top PV systems in Muscat are identified. Such an analysis was achieved through developing a detailed techno-economic mathematical model describing four sub-systems; the solar panel DC source, the grid-independent sub-system, the grid-connected sub-system and the economic sub-system. The model was implemented in gPROMS and uses real hourly weather and climate conditions matched with real demand data, over a simulated period of 20 years. The results indicate that, in the context of the system studied, grid-independent PV systems are not feasible. However, combined with a sufficiently high electricity price, grid-independent systems can become economically feasible only with significant reductions in battery costs (>90% reductions)
Solvent selection and design for CO2 capture - how we might have been missing the point
Carbon capture and storage (CCS) is a vital technology for the cost-effective mitigation of anthropogenic CO2 emissions. However, a key obstacle to its deployment on a large scale remains its cost â both capital and operating costs. In this context, the development of improved sorbents is a key research priority. Consequently, there is a vast global effort to develop new materials for this purpose, with literally thousands of new materials having been proposed since the beginning of the millennium. One common element of these contributions is that they focus on the equilibrium capacity of the material to absorb CO2 and rarely, if ever, other key factors such as transport properties. To date, the majority of this effort has cost significant amounts of time and resources and has almost exclusively focused on developing sorbents with increased CO2 capacity and/or reduced heat of regeneration. Given that sorbent regeneration largely dictates operational cost, this would, on the surface, appear rational. However, it is vital to recall that the cost structure of $ per MWh of electricity generated is composed of contributions from both capital and operational costs. Consequently, this single-minded focus on equilibrium CO2 capacity and heat of regeneration excludes the contribution of transport and kinetic properties which determine the equipment size and thus the capital cost. Therefore, in order to develop sorbents which will result in a non-negligible cost reduction, it is essential to move beyond equilibrium-based metrics of sorbent performance. In this paper, we present a new methodological approach for sorbent screening which explicitly includes rate-based phenomena. Our approach uses both monetised and non-monetised performance indicators. Our results suggest that whilst equilibrium CO2 capacity is a key determinant of process performance, transport properties (e.g., viscosity) and other thermophysical properties (e.g., heat capacity) have a significant effect on the capital cost, and thus on the price of the carbon captured. The key contribution of this work is the identification of the minimum set of thermophysical and kinetic parameters which must be reported in order to justify the claim of adequacy for a new sorbent for CO2 capture in particular and gas separations in general
CO2 capture and storage (CCS) cost reduction via infrastructure right-sizing
Carbon capture and storage (CCS) will be a critical component of a portfolio of low-carbon energy technologies required to combat climate change (Technology Roadmap, 2013). As such, an extensive transportation infrastructure will be required to transport captured CO2 from different sources to the available sinks. Several studies in the literature suggest that shared oversized pipeline networks may be the most efficient long term option compared to single source to sink pipelines, based on increased CCS deployment over the years and therefore increased CO2 flowrate to the transport network. However, what is neglected in this vision is that the deployment of intermittent renewable energy tends to displace thermal power generation. This directly reduces the amount of fossil fuel burned, CO2 produced, captured and transported through the network. This paper presents an optimisation methodology to âright-sizeâ CO2 transport infrastructure, explicitly accounting for the transient flow of CO2 arising from the co-deployment of intermittent renewable energy generators. By application of this methodology, we demonstrate that capital cost reductions of up to 28% are possible relative to a business-as-usual design case
Structural evolution of the UK electricity system in a below 2°C World
We employ an electricity system model to determine the least-cost transition necessary to meet a given carbon dioxide removal (CDR) burden in the UK. The results show that, while sufficient in the medium term, a system dominated by intermittent renewable energy technologies (IRES) cannot deliver CDR at the scale required in a cost-effective manner. The marginal value of IRES for climate change mitigation diminishes with time, especially in the context of the Paris Agreement. Deeper decarbonization precipitates a resurgence of thermal generation from bioenergy and gas (with carbon capture and storage) and nuclear. Such a system is inherently centralized and will require maintenance of existing transmission and distribution infrastructure. Current policy direction, however, encourages the proliferation of renewables and decentralization of energy services. To avoid locking the power system into a future where it cannot meet climate change mitigation ambitions, policy must recognize and adequately incentivize the new technologies (CCS) and services (CDR) necessary
Geospatial analysis of regional climate impacts to accelerate cost-efficient direct air capture deployment
Carbon dioxide (CO2) removal from the atmospheric will be essential if we are to achieve net-zero emissions targets. Direct air capture (DAC) is a CO2 removal method with the potential for large-scale deployment. However, DAC operational costs, and thus deployment potential, is dependent on performance, which can vary under different climate conditions. Here, to further develop our understanding of the impact of regional climate variation on DAC performance, we use high-resolution hourly based global weather profiles between 2016 and 2020 and weighted average capital costs to obtain DAC regional performance and levelized cost of DAC (LCOD). We found that relatively cold and drier regions have favorable DAC performance. Moreover, approximately 25% of the worldâs land is potentially unsuitable due to very cold ambient temperatures for a substantial part of the year. For the remaining regions, the estimated LCOD is 540 per tCO2 at an electricity cost of $50 MWhâ1. Our results improve the understanding of regional DAC performance, which can provide valuable insights for sustainable DAC deployment and effective climate action
A closed-loop analysis of grid scale battery systems providing frequency response and reserve services in a variable inertia grid
With increasing penetration of wind and solar generation the deployment of fast response plant, principally batteries, is currently considered necessary to mitigate reduced system inertia and the possibility of demand-supply imbalances. In this work the impact of these factors on battery cycling rates, taking into account the input from the batteries themselves, are analysed by applying the swing equation to a future inertia based on forecast generation mix. The operational capacity of batteries is a determining factor in their cycling rate, though the depth of discharge appears to be less well correlated. It is found that reducing system inertia does not, of itself, significantly impact on frequency volatility where the volatility of the generation to load imbalance is unchanged. However, the potential for a reduction in the damping of frequency deviations as a result of an increase in inverter connected motor drives may have a large impact on battery cycling characteristics. Provision of reserve services from battery systems requires a more complex operational strategy to ensure services are always deliverable and results in a significantly different cycling profile that may lead to greater battery degradation and consequently higher operational costs
- âŚ