Distribution of calcareous nannoplankton in surface sediments along the northern KwaZulu-Natal Bight, South Africa

The coccolith assemblages from seafloor sediments over the inner shelf in the northern region of the KwaZulu- Natal Bight on the east coast of South Africa were identified and their distribution determined. In all, 29 Recent species and taxonomic groups, as well as 29 reworked species were recorded. The distribution of the Recent species appears to be governed by environmental features that have been documented in other studies: temperature, salinity, nutrient concentration and water circulation pattern, which reveals the long-term existence of a circulation cell in the sector between Durban Bay and the Thukela River. The outer edge of the cell consists of nutrient-enriched mixed layers and is characterised by an enhanced abundance of Gephyrocapsa oceanica, whereas the central region consists of a stratified nutrient-depleted water mass with elevated abundance of Umbilicosphaera sibogae, Florisphaera profunda, and a group of umbelliform species. The elevated levels of G. oceanica, coupled with the rarity of U. sibogae, F. profunda and the umbelliform species, confirm the presence of a permanent upwelling cell off Richards Bay. The maximum abundance of F. profunda found between Richards Bay and Lake Nhlabane indicates a region of nutrient-depleted (except for nitrite) conditions.Keywords: Agulhas Current, Holocene, Indian Ocean, nutrients, quantitative analysi

Boron-rich benzene and pyrene derivatives for the detection of thermal neutrons

A synthetic methodology is developed to generate boron rich aromatic small molecules based on benzene and pyrene moieties for the detection of thermal neutrons. The prepared aromatic compounds have a relatively high boron content up to 7.4 wt%, which is important for application in neutron detection as (10)B (20% of natural abundance boron) has a large neutron induced reaction cross-section. This is demonstrated by preparing blends of the synthesized molecules with fluorescent dopants in poly(vinyltoluene) matrices resulting in comparable scintillation light output and neutron capture as state-of-the art commercial scintillators, but with the advantage of much lower cost. The boron-rich benzene and pyrene derivatives are prepared by Suzuki conditions using both microwave and traditional heating, affording yields of 40–93%. This new procedure is simple and straightforward, and has the potential to be scaled up