Characterization of Complex Interactions at the Gas-Solid Interface with in Situ Spectroscopy: The Case of Nitrogen-Functionalized Carbon

Interactions at the gas-solid interface drive physicochemical processes in many energy and environmental applications; however, the challenges associated with characterization and development of these dynamic interactions in complex systems limit progress in developing effective materials. Therefore, structure-property-performance correlations greatly depend on the development of advanced techniques and analysis methods for the investigation of gas-solid interactions. In this work, adsorption behavior of O2 and humidified O2 on nitrogen-functionalized carbon (N-C) materials was investigated to provide a better understanding of the role of nitrogen species in the oxygen reduction reaction (ORR). N-C materials were produced by solvothermal synthesis and N-ion implantation, resulting in a set of materials with varied nitrogen amount and speciation in carbon matrices with different morphologies. Adsorption behavior of the N-C samples was characterized by in situ diffuse reflectance infrared Fourier-transform spectroscopy (DRIFTS) and ambient pressure X-ray photoelectron spectroscopy (AP-XPS) experiments. A new analysis method for the interpretation of AP-XPS data was developed, allowing both the determination of overall adsorption behavior of each N-C material and identification of which nitrogen species were responsible for adsorption. The complementary information provided by in situ DRIFTS and AP-XPS indicates that O2 adsorption primarily takes place on either electron-rich nitrogen species like pyridine, hydrogenated nitrogen species, or graphitic nitrogen. Adsorption of O2 and H2O occurs competitively on solvothermally prepared N-Cs, whereas adsorption of H2O and O2 occurs at different sites on N-ion implanted N-Cs, highlighting the importance of tuning the composition of N-C materials to promote the most efficient ORR pathway