Performance of alumina-supported Pt catalysts in an electron-beam-sustained CO2 laser amplifier

The performance of an alumina-supported Pt catalyst system used to maintain the gas purity in an electron-beam-sustained (636) isotope CO2 laser amplifier has been tested. The system characteristics using the two-zone, parallel flow reactor were determined for both continuous- and end-of-day reactor operation using on-line mass spectrometric sampling. The laser amplifier was run with an energy loading of typically 110 J-l/atm and an electron-beam current of 4 mA/sq cm. With these conditions and a pulse repetition frequency of 10 Hz for up to 10,000 shots, increases on the order of 100 ppm O2 were observed with the purifier on and 150 ppm with it off. The 1/e time recovery time was found to be approximately 75 minutes

Microscopic origin of magnetism and magnetic interactions in ferropnictides

One year after their initial discovery, two schools of thought have crystallized regarding the electronic structure and magnetic properties of ferropnictide systems. One postulates that these are itinerant weakly correlated metallic systems that become magnetic by virtue of spin-Peierls type transition due to near-nesting between the hole and the electron Fermi surface pockets. The other argues these materials are strongly or at least moderately correlated, the electrons are considerably localized and close to a Mott-Hubbard transition, with the local magnetic moments interacting via short-range superexchange. In this paper we argue that neither picture is fully correct. The systems are moderately correlated, but with correlations driven by Hund's rule coupling rather than by the on-site Hubbard repulsion. The iron moments are largely local, driven by Hund's intra-atomic exchange. Superexchange is not operative and the interactions between the Fe moments are considerably long-range and driven mostly by one-electron energies of all occupied states

Signatures of valence fluctuations in CeCu2Si2 under high pressure

Simultaneous resistivity and a.c.-specific heat measurements have been performed under pressure on single crystalline CeCu2Si2 to over 6 GPa in a hydrostatic helium pressure medium. A series of anomalies were observed around the pressure coinciding with a maximum in the superconducting critical temperature, $T_c^{max}$. These anomalies can be linked with an abrupt change of the Ce valence, and suggest a second quantum critical point at a pressure $P_v \simeq 4.5$ GPa, where critical valence fluctuations provide the superconducting pairing mechanism, as opposed to spin fluctuations at ambient pressure. Such a valence instability, and associated superconductivity, is predicted by an extended Anderson lattice model with Coulomb repulsion between the conduction and f-electrons. We explain the T-linear resistivity found at $P_v$ in this picture, while other anomalies found around $P_v$ can be qualitatively understood using the same model.Comment: Submitted to Phys. Rev.

Quantum criticality in inter-band superconductors

In fermionic systems with different types of quasi-particles, attractive interactions can give rise to exotic superconducting states, as pair density wave (PDW) superconductivity and breached pairing. In the last years the search for these new types of ground states in cold atom and in metallic systems has been intense. In the case of metals the different quasi-particles may be the up and down spin bands in an external magnetic field or bands arising from distinct atomic orbitals that coexist at a common Fermi surface. These systems present a complex phase diagram as a function of the difference between the Fermi wave-vectors of the different bands. This can be controlled by external means, varying the density in the two-component cold atom system or, in a metal, by applying an external magnetic field or pressure. Here we study the zero temperature instability of the normal system as the Fermi wave-vectors mismatch of the quasi-particles (bands) is reduced and find a second order quantum phase transition to a PDW superconducting state. From the nature of the quantum critical fluctuations close to the superconducting quantum critical point (SQCP), we obtain its dynamic critical exponent. It turns out to be $z=2$ and this allows to fully characterize the SQCP for dimensions $d \ge 2$.Comment: 5 pages, 1 figur

Extremely Large and Anisotropic Upper Critical Field and the Ferromagnetic Instability in UCoGe

Magnetoresistivity measurements with fine tuning of the field direction on high quality single crystals of the ferromagnetic superconductor UCoGe show anomalous anisotropy of the upper critical field H_c2. H_c2 for H // b-axis (H_c2^b) in the orthorhombic crystal structure is strongly enhanced with decreasing temperature with an S-shape and reaches nearly 20 T at 0 K. The temperature dependence of H_c2^a shows upward curvature with a low temperature value exceeding 30 T, while H_c2^c at 0 K is very small (~ 0.6 T). Contrary to conventional ferromagnets, the decrease of the Curie temperature with increasing field for H // b-axis marked by an enhancement of the effective mass of the conduction electrons appears to be the origin of the S-shaped H_c2^b curve. These results indicate that the field-induced ferromagnetic instability or magnetic quantum criticality reinforces superconductivity.Comment: 5 pages, 4 figures, accepted for publication in J. Phys. Soc. Jp

Operator method in solving non-linear equations of the Hartree-Fock type

The operator method is used to construct the solutions of the problem of the polaron in the strong coupling limit and of the helium atom on the basis of the Hartree-Fock equation. $E_0=-0.1085128052\alpha^2$ is obtained for the polaron ground-state energy. Energies for 2s- and 3s-states are also calculated. The other excited states are briefly discussed.Comment: 7 page

Renormalization Group Technique Applied to the Pairing Interaction of the Quasi-One-Dimensional Superconductivity

A mechanism of the quasi-one-dimensional (q1d) superconductivity is investigated by applying the renormalization group techniques to the pairing interaction. With the obtained renormalized pairing interaction, the transition temperature Tc and corresponding gap function are calculated by solving the linearized gap equation. For reasonable sets of parameters, Tc of p-wave triplet pairing is higher than that of d-wave singlet pairing due to the one-dimensionality of interaction. These results can qualitatively explain the superconducting properties of q1d organic conductor (TMTSF)2PF6 and the ladder compound Sr2Ca12Cu24O41.Comment: 18 pages, 9 figures, submitted to J. Phys. Soc. Jp

A Tale of Two Fractals: The Hofstadter Butterfly and The Integral Apollonian Gaskets

This paper unveils a mapping between a quantum fractal that describes a physical phenomena, and an abstract geometrical fractal. The quantum fractal is the Hofstadter butterfly discovered in 1976 in an iconic condensed matter problem of electrons moving in a two-dimensional lattice in a transverse magnetic field. The geometric fractal is the integer Apollonian gasket characterized in terms of a 300 BC problem of mutually tangent circles. Both of these fractals are made up of integers. In the Hofstadter butterfly, these integers encode the topological quantum numbers of quantum Hall conductivity. In the Apollonian gaskets an infinite number of mutually tangent circles are nested inside each other, where each circle has integer curvature. The mapping between these two fractals reveals a hidden threefold symmetry embedded in the kaleidoscopic images that describe the asymptotic scaling properties of the butterfly. This paper also serves as a mini review of these fractals, emphasizing their hierarchical aspects in terms of Farey fractions

Coexistence of Singlet and Triplet Attractive Channels in the Pairing Interactions Mediated by Antiferromagnetic Fluctuations

We propose a phase diagram of quasi-low-dimensional type II superconductors in parallel magnetic fields, when antiferromagnetic fluctuations contribute to the pairing interactions. We point out that pairing interactions mediated by antiferromagnetic fluctuations necessarily include both singlet channels and triplet channels as attractive interactions. Usually, a singlet pairing is favored at zero field, but a triplet pairing occurs at high fields where the singlet pairing is suppressed by the Pauli paramagnetic pair-breaking effect. As a result, the critical field increases divergently at low temperatures. A possible relation to experimental phase diagrams of a quasi-one-dimensional organic superconductor is briefly discussed. We also discuss a possibility that a triplet superconductivity is observed even at zero field.Comment: 4 pages, 1 figure (Latex, revtex.sty, epsf.sty