2,499 research outputs found

    Torsion and Curvature in Continuously Defective Solid Crystals

    Get PDF
    I show how one can utilize the concept of a canonical connection on a homogeneous space to describe defectiveness of a continuous elastic crystal solid

    Molecular electronics exploiting sharp structure in the electrode density-of-states. Negative differential resistance and Resonant Tunneling in a poled molecular layer on Al/LiF electrodes

    Full text link
    Density-functional calculations are used to clarify the role of an ultrathin LiF layer on Al electrodes used in molecular electronics. The LiF layer creates a sharp density of states (DOS), as in a scanning-tunneling microscope (STM) tip. The sharp DOS, coupled with the DOS of the molecule leads to negative differential resistance (NDR). Electron transfer between oriented molecules occurs via resonant tunneling. The I-V characteristic for a thin-film of tris (8-hydroxyquinoline)- aluminum (AlQ) molecules, oriented using electric-field poling, and sandwiched between two Al/LiF electrodes is in excellent agreement with theory. This molecular device presents a new paradigm for a convenient, robust, inexpensive alternative to STM or mechanical break-junction structures.Comment: 5 pages, 3 figure

    Focused Ion Beam Milling and Deposition of Tungsten Contacts on Exfoliated Graphene for Electronic Device Applications

    No full text
    We demonstrate a rapid-prototyping method for the fabrication of electrical structures from exfoliated graphene using focused ion beam (FIB) assisted deposition of tungsten and milling. Alignment accuracies of less than 250 nm are achieved without imaging of the graphene using the FIB beam. Parameters for the FIB assisted deposition on graphene have to be controlled exactly to avoid damage to the underlying graphene. Measured channel resistance of 58 k? shows a good electrical contact between deposited tungsten and graphene

    Theoretical Simulationof the Zeke Spectra ofNaphthalene From SingleVibronic Levels of S1

    Get PDF
    We present the simulations and analysis of the two-color ZEKE spectra of naphthalene, performed with the help of quantum chemical calculations of molecular parameters followed by the modelling of vibronic intensities. Ab initio and semi-empirical calculations were carried out to obtain molecular structures of neutral and ionic naphthalene, and vibronic perturbations that couple the electronic states. It is shown that the intensities, simulated with a model based on the perturbative expansion of vibronic states, nicely reproduce the observed spectra and contribute to reassign some of the ground state frequencies of naphthalene cation

    Negated Complementary Commonsense using Large Language Models

    Full text link
    Larger language models, such as GPT-3, have shown to be excellent in many tasks. However, we demonstrate that out-of-ordinary questions can throw the model off guard. This work focuses on finding answers to negated complementary questions in commonsense scenarios. We illustrate how such questions adversely affect the model responses. We propose a model-agnostic methodology to improve the performance in negated complementary scenarios. Our method outperforms few-shot generation from GPT-3 (by more than 11 points) and, more importantly, highlights the significance of studying the response of large language models in negated complementary questions. The code, data, and experiments are available under: https://github.com/navidre/negated_complementary_commonsense.Comment: Appeared in Natural Language Reasoning and Structured Explanations Workshop (NLRSE) - ACL 202

    O idei współpłatności za studia dzienne

    Get PDF
    The authors justify the need for the introduction of partial tuition (sharing in the cost) in Poland by the necessity of eliminating existing pathologies in this field and creating conditions for the rational management of resources. The size of the fees should be linked to the costs of the teaching process on the one hand, and on the other - to the system of financial aim for students (in the form of loans).Autorzy uzasadniają potrzebę wprowadzenia w Polsce częściowej odpłatności za studia (współpłatności) koniecznością likwidacji istniejących obecnie patologii w tej dziedzinie oraz stworzenia warunków do racjonalnego gospodarowania zasobami. Wysokość opłat powinna być powiązana z jednej strony z wysokością kosztów realizacji procesu dydaktycznego, a z drugiej strony - z systemem pomocy materialnej dla studentów (w formie pożyczek)

    Supernova explosions and the birth of neutron stars

    Get PDF
    We report here on recent progress in understanding the birth conditions of neutron stars and the way how supernovae explode. More sophisticated numerical models have led to the discovery of new phenomena in the supernova core, for example a generic hydrodynamic instability of the stagnant supernova shock against low-mode nonradial deformation and the excitation of gravity-wave activity in the surface and core of the nascent neutron star. Both can have supportive or decisive influence on the inauguration of the explosion, the former by improving the conditions for energy deposition by neutrino heating in the postshock gas, the latter by supplying the developing blast with a flux of acoustic power that adds to the energy transfer by neutrinos. While recent two-dimensional models suggest that the neutrino-driven mechanism may be viable for stars from about 8 solar masses to at least 15 solar masses, acoustic energy input has been advocated as an alternative if neutrino heating fails. Magnetohydrodynamic effects constitute another way to trigger explosions in connection with the collapse of sufficiently rapidly rotating stellar cores, perhaps linked to the birth of magnetars. The global explosion asymmetries seen in the recent simulations offer an explanation of even the highest measured kick velocities of young neutron stars.Comment: 10 pages, 8 figures, 19 ps files; to be published in Proc. of Conf. "40 Years of Pulsars: Millisecond Pulsars, Magnetars, and More", August 12-17, 2007, McGill Univ., Montreal, Canada; high-resolution images can be obtained upon request; incorrect panel in fig.8 replace

    Carboniferous–Permian magmatism and Mo–Cu (W) mineralization in the contact zone between the Małopolska and Upper Silesia Blocks (south Poland): an echo of the Baltica–Gondwana collision

    Get PDF
    The Kraków–Lubliniec tectonic zone (KLFZ) in southern Poland, which divides the Małopolska Block (MB) from the Upper Silesia Block (USB), is a portion of the SW margin of the Trans-European Suture Zone. Zircon U–Pb dating of a variety of igneous rocks (granodiorites, dacites, lamprophyre and diabase) from the subsurface Kraków–Lubliniec igneous belt along the KLFZ shows that magmatism spanned within a narrow time period (ca. 10 Ma) between 303.8 ± 2.2 and 292.7 ± 4.9 Ma. The earlier magmatism (303.8 ± 2.2–294.7 ± 2.3 Ma) was felsic calc-alkaline, and the contemporaneous or/and slightly later alkaline volcanism (294.4 ± 4.9–292.7 ± 4.9 Ma) was of mafic–intermediate composition. The felsic rocks (granitoids and dacitoids) are weakly peraluminous, medium to high K, moderate Mg# (0.39–0.46), weakly evolved and I-type rocks. Due to the intensive development of hydrothermal alteration, these rocks are commonly strongly altered and locally mineralized by porphyry and other types of Mo–Cu (W) ores that are closely related to the felsic magmatism in space and time. The zircon U–Pb dating yielded ages which are similar to the previously measured Re–Os ages of molybdenites from the KLFZ. Felsic magmatism at the Myszków Mo–Cu–W deposit yielded ages in the range 301.0 ± 2.1–295.9 ± 2.9 Ma. The youngest rocks dated are from the Mysłów area in the USB—volcanic alkaline rocks (lamprophyre and diabase) of shoshonitic character, with low Mg# (0.49 and 0.69, respectively) and Ni contents (< 62 ppm), indicative of a relatively juvenile magma composition. Inherited zircon cores, remnant detrital zircon from a sediment component in the source rocks, were dated to be ranging from ca. 2775 to 575 Ma. Inheritance of ca. 600 Ma (Cadomian basement) and ca. 1.40 Ga (Mesoproterozoic) is common in the rocks from both blocks, but those from the MB contain additional inheritance with dates of 2.78–2.67 and 2.05–1.92 Ga, both ages characteristic of zircon from the Svecofennian of northern Europe (Baltica). The inherited zircon from the youngest alkaline rocks provided evidence for Mesoproterozoic (ca. 1.55–1.44 and 1.09 Ga) and Palaeoproterozoic (1.96 Ga) thermal events in the USB, and its possible affinity to Avalonian cratonic crust as a source for its igneous protolith. U–Pb isotopic studies of zircons from KL igneous belt indicate its inherited signatures from the crustal sources and magma emplacements during the KLFZ wrenching which allowed channels and room for magma emplacement along the MB and USB in upper Carboniferous–lower Permian on SW margin of the East-European Craton. Mo–Cu (W) ore mineralization, associated with the ~ 300 Ma felsic magmatism, represents rather the product of decompression melting induced in the areas of decreased pressure, undergone in the regional wrench fault zones than the classic Mo–Cu porphyry-style mineralization.The analytical work was supported by the National Committee for Scientifc Research, Grant no. N N525 393739 for S. Mikulski

    Nadroparin in the prophylaxis and treatment of thromboembolic complications in cancer patients

    Get PDF
    Thromboembolic events are the most frequent complications and second leading cause of death among cancer patients. The most common forms include deep venous thrombosis of lower extremities and pulmonary embolism. The risk of thrombosis is correlated with underlying, patient’s clinical characteristic, functions of coagulation system as well as anticancer treatment. There is a well-established evidence for using of antithrombotic prophylaxis in cancer patients undergoing surgery and hospitalised due to different causes. There are some scores, based on laboratory and clinical factors, that facilitate qualification to the prophylaxis (e.g. Caprini score, Padua Prediction Score). The role of low-molecular-weight heparins (LMWH) in prophylaxis of thrombosis in cancer patients was established based on the results of many randomised clinical trials. Currently, the use this group of drugs — both in the treatment and in prophylaxis of venous thromboembolism (VTE) — is a part of standard of care. Nadroparin is one of the LMWHs with well-documented efficacy and safety in cancer patients

    Hexagonal Structure of Baby Skyrmion Lattices

    Full text link
    We study the zero-temperature crystalline structure of baby Skyrmions by applying a full-field numerical minimization algorithm to baby Skyrmions placed inside different parallelogramic unit-cells and imposing periodic boundary conditions. We find that within this setup, the minimal energy is obtained for the hexagonal lattice, and that in the resulting configuration the Skyrmion splits into quarter-Skyrmions. In particular, we find that the energy in the hexagonal case is lower than the one obtained on the well-studied rectangular lattice, in which splitting into half-Skyrmions is observed.Comment: RevTeX, 7 pages, 6 figure
    corecore