Folk and Traditional Music of the Western Continents

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/68787/2/10.2307_3344648.pd

Longitudinal Relationships Between Parent Factors, Children’s Bullying, and Victimization Behaviors

Longitudinal data from NICHD Study of Early Child Care and Youth Development tested direct, indirect and reciprocal effects of maternal depressive symptoms, stress/support factors on child bullying and peer victimization through mother–child relationship quality at grades 3, 5, 6. Data from 828 mother-child dyads indicated small significant effects of some hypothesized pathways, including a small direct effect of maternal depressive symptoms at grade 3 on peer victimization at grade 5, but not on bullying behaviors. Mother–child relationship quality at grade 5 negatively predicted bullying at grade 6, but not peer victimization. There were small effects of bullying behaviors at grade 5 on decreased mother–child relationship quality at grade 6. Maternal employment at grade 3 predicted decreased bullying behaviors at grade 6 through mother–child relationship quality at grade 5. Findings are relevant for parent inclusive research and approaches to anti-bully intervention strategies and prevention policies

Gamma–ray spectroscopy with single–carrier collection in high–resistivity semiconductors

With the standard plane–parallel configuration of semiconductor detectors, good γ–ray spectra can only be obtained when both electrons and holes are completely collected. We show by calculations (and experiments) that with contacts of hemispherical configuration one can obtain γ–ray spectra of adequate resolution and with signal heights of nearly full amplitude even when only one type of carrier is collected. Experiments with CdTe detectors for which the µτ product for electrons is about 10^(3) times that of the holes confirm these calculations. The adoption of hemispherical contacts thus widens the range of high–resistivity semiconductors potentially acceptable for γ–ray detection at room temperature

Spatial and seasonal patterns and long term variability of the composition of the haze in the United States: an analysis of data from the IMPROVE network

July 1996.Principal investigators: William C. Malm, Marc L. Pitchford.Includes bibliographical references.This report describes data for the three year period, March 1992 through February 1995, of the Interagency Monitoring of Protected Visual Environments (IMPROVE) measurement program. IMPROVE is a cooperative visibility monitoring effort between the United States Environmental Protection Agency, (EPA) federal land management agencies, and state air agencies

Composition-Dependent Hydrogen-Bonding Motifs and Dynamics in Brønsted Acid-Base Mixtures

In recent years the interaction of organophosphates and imines, which is at the core of Brønsted acid organocatalysis, has been established to be based on strong ionic hydrogen bonds. Yet, besides the formation of homodimers consisting of two acid molecules and heterodimers consisting of one acid and one base, also multimeric molecular aggregates are formed in solution. These multimeric aggregates consist of one base and several acid molecules. The details of the intermolecular bonding in such aggregates, however, have remained elusive. To characterize compositiondependent bonding and bonding dynamics in these aggregates, we use linear and nonlinear infrared (IR) spectroscopy at varying molar ratios of diphenyl phosphoric acid and quinaldine. We identify the individual aggregate species, giving rise to the structured, strong, and very broad infrared absorptions, which span more than 1000 cm −1. Linear infrared spectra and density functional theory calculations of the proton transfer potential show that doubly ionic intermolecular hydrogen bonds between the acid and the base lead to absorptions which peak at ∼2040 cm −1. The contribution of singly ionic hydrogen bonds between an acid anion and an acid molecule is observed at higher frequencies. As common to such strong hydrogen bonds, ultrafast IR spectroscopy reveals rapid, ∼ 100 fs, dissipation of energy from the proton transfer coordinate. Yet, the full dissipation of the excess energy occurs on a ∼0.8−1.1 ps time scale, which becomes longer when multimers dominate. Our results thus demonstrate the coupling and collectivity of the hydrogen bonds within these complexes, which enable efficient energy transfer