11 research outputs found
Significant and Concurrent Enhancement of Stiffness, Strength, and Toughness for Paraffin Wax Through Organoclay Addition
Simulation of Pressure Transients Due to Valve Chattering in a Heat Transport Circuit of a Process Plant
Structural Requirements for the Intercalation of Polyether Polyols into Sodium-Montmorillonite: The Role of Oxyethylene Sequences
Removal of sulfide ions from aqueous solutions using carbon- and silicon-containing sorbents
Bio-inspired cross-linking with borate for enhancing gas-barrier properties of poly(vinyl alcohol)/graphene oxide composite films
Strategies for Producing Improved Oxygen Barrier Materials Appropriate for the Food Packaging Sector
Swelling of Ionic and Nonionic Surfactant Micelles by High Pressure Gases
The influence of different solvent environments on the size, shape, and characteristics of surfactant micelles of Pluronic F127 and CTAB was investigated by small-angle neutron scattering (SANS). SANS experiments were undertaken on dilute micellar surfactant solutions of F127 and CTAB that between them were exposed to liquid and supercritical carbon dioxide, liquid propane, ethane, and heptane under various pressures and temperatures. Swelling of the surfactant micelles could be directly related to the solubility of the solvents within the micelles, especially within their cores. Carbon dioxide produced the largest swelling of the Pluronic F127 micelles, compared to propane and ethane, which mirrors the solubility of the gases in the PPO core of the micelles. Conversely, the extent of swelling of the cores of CTAB micelles was greater with propane compared to carbon dioxide, which again relates to the solubility of the solvents in the alkane core of the CTAB micelles