La comunicación como medio educativo

La comunicación constituye un medio para la regulación del comportamiento social al igual que la educación lo es para la adaptación de los individuos a su entorno socioecológico. Los sujetos expresan la necesidad de comunicarse en la medida en que pretenden unos determinados objetos que sólo pueden ser alcanzados a partir del intercambio de informaciones. Estas no sólo son transmitidas a través del lenguaje verbal sino también de gestos y expresiones corporales, que muchas veces contradicen lo significado por aquel. Es por ello que el estudio de la comunicación no verbal presenta un gran interés tanto desde el punto de vista de la semiótica como del de las relaciones educativas. Educación y Comunicación no son, sin embargo, realidades coincidentes. Aunque ambas son actividades sociales producidas de forma intencional difieren en los fines así como en otros aspectos relacionados con la transmisión de información.<br /

El Español en los círculos comerciales de los Países Bajos en el siglo XVI : transcripción, presentación de un corpus : análisis del sistema vocálico de los textos transcritos

Tesi de Llicenciatura per a la obtenció del Grau de Filologia. Facultat de Filologia. Departament de Filologia Hispànica. Universitat de Barcelona. Directora: Emma Martinell. setembre 1995

Estructura pitching audiovisual. Projectes 2

Projecte: 2016 PID-UB/026Darrera actualització: gener de 2019Presentem una guia per planificar un pitching audiovisual de 7 minuts de durada. La guia inclou l'estructura del pitching i algunes estratègies persuasives

Platinum(II) and palladium(II) complexes derived from 1-ferrocenylmethyl-3,5-diphenylpyrazole. Coordination, cyclometallation or transannulation?

The synthesis and characterization of the novel pyrazole derivative [1-(Fc-CH2)-3,5-Ph-2-(C3HN2)] (2) {Fc = (eta(5) -C5H5)Fe(eta(5)-C5H4)-} with a ferrocenylmethyl substituent on position 1 of the heterocycle is described. The study of the reactivity of 2 with cis-[MCl2L2] (M = Pt and L = dmso or M = Pd and L = dmso or CH3CN), Pd(AcO)(2) or Na-2[PdCl4] under different experimental conditions, has allowed us to isolate and characterize a wide variety of platinum(II) or palladium(II) complexes: trans-[Pt{1-(Fc-CH2)-3,5-Ph2-(C3HN2)} Cl-2(dmso)] (3), the cis-isomers of [M{1-(Fc-CH2)-3,5-Ph-2-(C3HN2)}Cl-2(dmso)] {M = Pt (4) or Pd (7)}, trans-[Pd{1-(Fc-CH2)-3,5-Ph-2-(C3HN2)}(2)Cl-2] (8), the cyclometallated compounds [M{1-(Fc-CH2)-(3-C6H4)-5-Ph-(C3HN2)}Cl(L)] {with M = Pt and L = dmso (5) or PPh3 (6) or M = Pd and L = PPh3 (9)} and the palladium(II) complex [Pd{1-[(eta(5)-C5H4)Fe{(eta(5)-C5H4)-CH2]-3,5-Ph-2-(C3HN2)}Cl(PPh3)] (10) that arises from a transannulation process. The crystal structures of the free ligand 2 and compounds 4, 7, 9 and 10 are also reported and confirm the cis-disposition of the Cl- ligands in 4 and 7, the trans-arrangement of the phosphorous and the nitrogen atoms in 9 and 10, the mode of binding of the ligand in 4, 7, 9 and 10 and the nature of the metallated carbon atom {C(sp(2), phenyl) in 9 or the C(sp(2), ferrocenyl) of the C5H5 ring in 10}. In order to rationalize the different nature of the products isolated in the reactions of 2 with Pd(AcO)(2) or Na-2[PdCl4] and NaAcO density functional theory (DFT) calculations of the complexes have also been carried out

Wavelength-Diverse Polarization Modulators for Stokes Polarimetry

Information about the three-dimensional structure of solar magnetic fields is encoded in the polarized spectra of solar radiation by a host of physical processes. To extract this information, solar spectra must be obtained in a variety of magnetically sensitive spectral lines at high spatial, spectral, and temporal resolution with high precision. The need to observe many different spectral lines drives the development of Stokes polarimeters with a high degree of wavelength diversity. We present a new paradigm for the design of polarization modulators that operate over a wide wavelength range with near optimal polarimetric efficiency and are directly applicable to the next generation of multi-line Stokes polarimeters. These modulators are not achromatic in the usual sense because their polarimetric properties vary with wavelength, but they do so in an optimal way. Thus we refer to these modulators as polychromatic. We present here the theory behind polychromatic modulators, illustrate the concept with design examples, and present the performance properties of a prototype polychromatic modulator.Comment: 13 pages, 1 table, 5 figures, accepted for publication in Applied Optic

Heterodi- (Fe, Pd/Pt) and heterotrimetallic (Fe2, Pd) complexes derived from 4-(ferrocenylmethyl)-N-(2-methoxyethyl)-3,5-diphenylpyrazole as potential antitumoral agents

The study of the reactivity of the pyrazole derivative 1-[MeO-(CH2)2]-3,5-Ph2-4-(CH2Fc) (C3N2) (1, Fc = ferrocenyl) with Na2[PdCl4], Pd(OAc)2, and [MCl2(dmso)2] (M = Pd or Pt,dmso = dimethyl sulfoxide) has allowed us to isolate trans-[Pd{κ-N-(1-{MeO(CH2)2}-3,5-Ph2-4-{CH2Fc} {C3N2})}2Cl2] (2), [Pd{κ2-C,N(1-{MeO(CH2)2}-3-{C6H4}-5-Ph-{C3N2})}{κ-N-(1-{MeO(CH2)2}-3,5-Ph2-4-{CH2Fc} {C3N2})}Cl] (3), [Pd{κ2-C,N(1-{MeO(CH2)2}-3-{C6H4}-4-{CH2Fc}-5-Ph-{C3N2})}Cl-(PPh3)] (4), and the trans (5) and cis (6) isomers of [Pt{κ-N-(1-{MeO(CH2)2}-3,5-Ph24-{CH2Fc} {C3N2})}Cl2(dmso)]. Compound 1 acts as a N (in 2, 5, and 6) or (C,N) donor ligand (in 4) and shows both binding modes in 3. The cytotoxic assessment of 1 6 against MCF7, MDA-MB231 (breast), and HCT-116 (colon) cancer cell lines reveal that (1) 1 is more potent than 1-[MeO(CH2)2]-3,5-Ph2-(C3HN2) (V), (2) 2 6 have cytotoxic activity, (3) 2 and 3 are less active than 4 6, and (4) 6 is the most potent compound against the three cancer cell lines

Pd(II) complexes with N-substituted pyrazoles as ligands. The influence of the R group [OMe versus NMe2] of [1-{R(CH2)2}-3,5-Ph2(C3HN2)] on their cytotoxic activity on breast cancer cell lines

The study of the reactivity of the novel pyrazole derivative [1-{MeOe(CH2)2e}-3,5-Ph2e(C3HN2)] (1) with Na2[PdCl4] or Pd(OAc)2 under different experimental conditions has allowed us to isolate and characterize the trans-isomers of [Pd{[1-{MeOe(CH2)2e}-3,5-Ph2e(C3HN2)]}2(X)2] [X ¼ Cl (2) or OAc (3)] and the di-m-ligand bridged cyclopalladated complexes [Pd{k2,C,N[1-{MeOe(CH2)2e}-3-(C6H4),5-Ph- (C3HN2)]}(m-X)]2 [X ¼ OAc (4) or Cl (5)]. Further treatment of compounds 4 or 5 with PPh3 in CH2Cl2 produced the bridge splitting and the formation of [Pd{k2,C,N[1-{MeOe(CH2)2e}-3-(C6H4),5-Ph- (C3HN2)]}X(PPh3)] [X ¼ OAc (6) or Cl (7)]. The cytotoxic assessment of the free ligand (1) and the Pd(II) complexes on the two breast cancer cell lines MCF7 and MDA-MB231 reveals that: a) compound 1 is less active than its analogue [1-{Me2Ne(CH2)2e}-3,5-Ph2e(C3HN2)] (Ic) and b) palladacycles 4e7 showed a remarkable cytotoxic activity in the MDA-MB231 cell line (with IC50 values in the range 9.1e14.4 mM)

La persuasión

Guía para preparar una unidad didáctica sobre Pesuasión en el ámbito de la comunicación audiovisua

Quality indicators: developing 'MOOCs' in the European Higher Education Area

The objective of this research is to design an integrated system of evaluation of the quality of the Massive Open Online Courses (MOOC) taking into account the features of this type of courses. The criteria included in the evaluation of the quality of e-learning training in a broad sense are considered, and specifically those developed for the MOOCs. Using a quantitative, descriptive and sectional design, a team of experts have valued those indicators proposed by the scientific literature. To do this, eight courses, focusing on the field of entrepreneurship and innovation, were selected. Most of the analysed courses meet designated quality criteria by having a clear and organized academic structure. In addition, each course states clearly the timing and hours of dedication by the learner. However, only a few courses do that on the open Internet and on their own academic institutions' websites. None of the MOOCs establishes the admission requirements. The main contribution of the current research is that it gives MOOC developers some quality indicators, related to course design and platform, to better plan their applied design and implementation, which has a decisive positive impact on the educational quality of such e-learning platforms

Comunicació a la Xarxa: Lloc web per a la projecció professional: rúbrica d'avaluació

Aquest document és una eina d'avaluació de l'assignatura Comunicació a la Xarx