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A study of the antioxidant capacity of oak wood used in wine ageing and the correlation with polyphenol composition
The antioxidant capacity of oak wood used in the ageing of wine was studied by four different methods: measurement of scavenging capacity against a given radical (ABTS, DPPH), oxygen radical absorbance capacity (ORAC) and the ferric reducing antioxidant power (FRAP). Although, the four methods tested gave comparable results for the antioxidant capacity measured in oak wood extracts, the ORAC method gave results with some differences from the other methods. Non-toasted oak wood samples displayed more antioxidant power than toasted ones due to differences in the polyphenol compositon. A correlation analysis revealed that ellagitannins were the compounds mainly responsible for the antioxidant capacity of oak wood. Some phenolic acids, mainly gallic acid, also showed a significant correlation with antioxidant capacity
Susceptibility inhomogeneity and non-Fermi liquid behavior in UCu_{5-x}Pt_x
Transverse-field muSR shifts and relaxation rates have been measured in the
non-Fermi liquid (NFL) alloy system UCu_{5-x}Pt_x, x = 1.0, 1.5, and 2.5. At
low temperatures the fractional spread in Knight shifts delta K/K approx
deltachi/chi is gtrsim 2 for x = 1, but is only half this value for x = 1.5 and
2.5. In a disorder-driven scenario where the NFL behavior is due to a broadly
distributed (Kondo or Griffiths-phase cluster) characteristic energy E, our
results indicate that delta E/E_{rm av} approx (delta K/K)_{T=0} is similar for
UCu_{5-x}Pd_x (x = 1 and 1.5) and UCu_4Pt, but is reduced for UCu_{5-x}Pt_x, x
= 1.5 and 2.5. This reduction is due to a marked increase of E with increasing
x; the spread delta E is found to be roughly independent of x. Our results
correlate with the observed suppression of other NFL anomalies for x > 1 in
UCu_{5-x}Pt_x but not in UCu_{5-x}Pd_x, and are further evidence for the
importance of disorder in the NFL behavior of both these alloy systems.Comment: 4 pages, 2 figures, submitted to 10th International Conference on
Muon Spin Rotation, Relaxation, and Resonance, Oxford, UK, August 200
Short-range antiferromagnetic correlations in Kondo insulators
We study the influence of short range antiferromagnetic correlations between
local -electrons on the transport and thermodynamic properties of Kondo
insulators, as first proposed by Coqblin et al. for metallic heavy fermions.
The inter-site magnetic correlations produce an effective bandwidth for the
-electrons. They are treated on the same footing as the local Kondo
correlations such that two energy scales appear in our approach. We discuss the
competition between these two scales on the physical properties.Comment: 13 pages, 13 figures. To be published in Physics Letters
X-boson cumulant approach to the periodic Anderson model
The Periodic Anderson Model (PAM) can be studied in the infinite U limit by
employing the Hubbard X operators to project out the unwanted states. We have
already studied this problem employing the cumulant expansion with the
hybridization as perturbation, but the probability conservation of the local
states (completeness) is not usually satisfied when partial expansions like the
Chain Approximation (CHA) are employed. Here we treat the problem by a
technique inspired in the mean field approximation of Coleman's slave-bosons
method, and we obtain a description that avoids the unwanted phase transition
that appears in the mean-field slave-boson method both when the chemical
potential is greater than the localized level Ef at low temperatures (T) and
for all parameters at intermediate T.Comment: Submited to Physical Review B 14 pages, 17 eps figures inserted in
the tex
Desingularization of vortices for the Euler equation
We study the existence of stationary classical solutions of the
incompressible Euler equation in the plane that approximate singular
stationnary solutions of this equation. The construction is performed by
studying the asymptotics of equation -\eps^2 \Delta
u^\eps=(u^\eps-q-\frac{\kappa}{2\pi} \log \frac{1}{\eps})_+^p with Dirichlet
boundary conditions and a given function. We also study the
desingularization of pairs of vortices by minimal energy nodal solutions and
the desingularization of rotating vortices.Comment: 40 page
Geometric Phase: a Diagnostic Tool for Entanglement
Using a kinematic approach we show that the non-adiabatic, non-cyclic,
geometric phase corresponding to the radiation emitted by a three level cascade
system provides a sensitive diagnostic tool for determining the entanglement
properties of the two modes of radiation. The nonunitary, noncyclic path in the
state space may be realized through the same control parameters which control
the purity/mixedness and entanglement. We show analytically that the geometric
phase is related to concurrence in certain region of the parameter space. We
further show that the rate of change of the geometric phase reveals its
resilience to fluctuations only for pure Bell type states. Lastly, the
derivative of the geometric phase carries information on both purity/mixedness
and entanglement/separability.Comment: 13 pages 6 figure
The effect of the hookworm Ancylostoma ceylanicum on the mucosal architecture of the small intestine in hamsters
Hookworms are known to cause marked changes to the intestinal mucosa, especially in relation to erosion of the villi. However, since the development of enteropathy has not been examined thoroughly through quantitative experiments on infected animals, the results of experiments conducted in hamsters infected with Ancylostoma ceylanicum are reported. Changes to intestinal architecture were first apparent between 12 and 14 days after infection, and then increased in intensity for 3–4 weeks, persisting for as long as worms were present (>63 days). Following infection, the height of villi declined from a mean of 1002 μm in naïve controls to less than 200 μm and as low as 18 μm in one case. The depth of the crypts of Lieberkuhn increased from a baseline value of 166 μm in naïve controls to in excess of 600 μm within 6 weeks of infection. Mitotic figures had a baseline value of 5.5 per villus-crypt unit, and this rose to in excess of 25 in some experiments. Changes were dependent on the intensity of the parasite burden on day 20, but by 30 days after infection changes in all three values were maximal and density-dependent relationships were no longer clearly apparent. Villus height and crypt depth returned to near normal values within a week of the removal of worms, although group means for both remained different from naïve controls for at least 3 weeks after treatment. Cellular division, as reflected in numbers of mitotic figures, stayed elevated for over 5 weeks after removal of worms. The results suggest that enteropathy in hookworm infections stems from a combination of intestinal immune responses and from the grazing activities of the adult worms on the mucosal surface, but is not sufficient per se for expulsion of this parasit
Taming the Scalar Mass Problem with a Singlet Higgs Boson
We investigate the fine-tuning problem in the Standard Model and show that
Higgs boson and top quark masses consistent with current experimental bounds
cannot be obtained unless one extends the particle spectrum. A minimal
extension which achieves this involves addition of a singlet real scalar and
one generation of vectorlike fermions. We show that this leads to a
phenomenologically viable prediction for the mass of the Standard Model Higgs
boson.Comment: (LaTeX file), 13 pages, preprint no. SINP-TNP/94-1
Vibrio vulnificus MO6-24/O Lipopolysaccharide Stimulates Superoxide Anion, Thromboxane B\u3csub\u3e2\u3c/sub\u3e, Matrix Metalloproteinase-9, Cytokine and Chemokine Release by Rat Brain Microglia in Vitro
Although human exposure to Gram-negative Vibrio vulnificus (V. vulnificus) lipopolysaccharide (LPS) has been reported to result in septic shock, its impact on the central nervous system’s innate immunity remains undetermined. The purpose of this study was to determine whether V. vulnificus MO6-24/O LPS might activate rat microglia in vitro and stimulate the release of superoxide anion (O2−), a reactive oxygen species known to cause oxidative stress and neuronal injury in vivo. Brain microglia were isolated from neonatal rats, and then treated with either V. vulnificus MO6-24/O LPS or Escherichia coli O26:B6 LPS for 17 hours in vitro. O2− was determined by cytochrome C reduction, and matrix metalloproteinase-2 (MMP-2) and MMP-9 by gelatinase zymography. Generation of cytokines tumor necrosis factor alpha (TNF-α), interleukin-1 alpha (IL-1α), IL-6, and transforming growth factor-beta 1 (TGF-β1), chemokines macrophage inflammatory protein (MIP-1α)/chemokine (C-C motif) ligand 3 (CCL3), MIP-2/chemokine (C-X-C motif) ligand 2 (CXCL2), monocyte chemotactic protein-1 (MCP-1)/CCL2, and cytokine-induced neutrophil chemoattractant-2alpha/beta (CINC-2α/β)/CXCL3, and brain-derived neurotrophic factor (BDNF), were determined by specific immunoassays. Priming of rat microglia by V. vulnificus MO6-24/O LPS in vitro yielded a bell-shaped dose-response curve for PMA (phorbol 12-myristate 13-acetate)-stimulated O2− generation: (1) 0.1–1 ng/mL V. vulnificus LPS enhanced O2− generation significantly but with limited inflammatory mediator generation; (2) 10–100 ng/mL V. vulnificus LPS maximized O2− generation with concomitant release of thromboxane B2 (TXB2), matrix metalloproteinase-9 (MMP-9), and several cytokines and chemokines; (3) 1000–100,000 ng/mL V. vulnificus LPS, with the exception of TXB2, yielded both attenuated O2− production, and a progressive decrease in MMP-9, cytokines and chemokines investigated. Thus concentration-dependent treatment of neonatal brain microglia with V. vulnificus MO6-24/O LPS resulted in a significant rise in O2− production, followed by a progressive decrease in O2− release, with concomitant release of lactic dehydrogenase (LDH), and generation of TXB2, MMP-9, cytokines and chemokines. We hypothesize that the inflammatory mediators investigated may be cytotoxic to microglia in vitro, by an as yet undetermined autocrine mechanism. Although V. vulnificus LPS was less potent than E. coli LPS in vitro, inflammatory mediator release by the former was clearly more efficacious. Finally, we hypothesize that should V. vulnificus LPS gain entry into the CNS, it would be possible that microglia might become activated, resulting in high levels of O2− as well as neuroinflammatory TXB2, MMP-9, cytokines and chemokines
Modeling electrolytically top gated graphene
We investigate doping of a single-layer graphene in the presence of
electrolytic top gating. The interfacial phenomena is modeled using a modified
Poisson-Boltzmann equation for an aqueous solution of simple salt. We
demonstrate both the sensitivity of graphene's doping levels to the salt
concentration and the importance of quantum capacitance that arises due to the
smallness of the Debye screening length in the electrolyte.Comment: 7 pages, including 4 figures, submitted to Nanoscale Research Letters
for a special issue related to the NGC 2009 conference
(http://asdn.net/ngc2009/index.shtml
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