11 research outputs found

    Geometrical complexity of conformations of ring polymers under topological constraints

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    One measure of geometrical complexity of a spatial curve is the number of crossings in a planar projection of the curve. For NN-noded ring polymers with a fixed knot type, we evaluate numerically the average of the crossing number over some directions. We find that the average crossing number under the topological constraint are less than that of no topological constraint for large NN. The decrease of the geometrical complexity is significant when the thickness of polymers is small. The simulation with or without a topological constraint also shows that the average crossing number and the average size of ring polymers are independent measures of conformational complexity.Comment: 8 pages, 4figure

    Gyration radius of a circular polymer under a topological constraint with excluded volume

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    It is nontrivial whether the average size of a ring polymer should become smaller or larger under a topological constraint. Making use of some knot invariants, we evaluate numerically the mean square radius of gyration for ring polymers having a fixed knot type, where the ring polymers are given by self-avoiding polygons consisting of freely-jointed hard cylinders. We obtain plots of the gyration radius versus the number of polygonal nodes for the trivial, trefoil and figure-eight knots. We discuss possible asymptotic behaviors of the gyration radius under the topological constraint. In the asymptotic limit, the size of a ring polymer with a given knot is larger than that of no topological constraint when the polymer is thin, and the effective expansion becomes weak when the polymer is thick enough.Comment: 12pages,3figure
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