433 research outputs found
Pulsed laser deposition of KNbO<sub>3</sub> thin films
The laser ablation of stationary KNbO3 single crystal targets induces a Nb enrichment of the target surface. In rotated targets this effect is observed only in those areas irradiated with low laser fluence. The composition of the plasma formed close to the target surface is congruent with the target composition; however, at further distances K-deficient films are formed due to the preferential backscattering of K in the plasma. This loss may be compensated for by using K-rich ceramic targets. Best results so far have been obtained with [K]/[Nb] = 2.85 target composition, and crystalline KNbO3 films are formed when heating the substrates to 650 °C. Films formed on (100)MgO single crystals are usually single phase and oriented with the (110) film plane parallel to the (100) substrate surface. (100)NbO may coexist with KNbO3 on (100)MgO. At substrate temperatures higher than 650 °C, niobium diffuses into MgO forming Mg4Nb2O9 and NbO, leading to K evaporation from the film. Films formed on (001) alpha-Al2O3 (sapphire) show the coexistence of (111), (110), and (001) orientations of KNbO3, and the presence of NbO2 is also observed. KNbO3 films deposited on (001)LiNbO3 crystallize with the (111) plane of the film parallel to the substrate surface. For the latter two substrates the Nb diffusion into the substrate is lower than in MgO and consequently the K concentration retained in the film is comparatively larger
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Evaporation studies of simulated low-heat waste and post-aluminum dissolution waste
Successive evaporations were performed on simulated low-heat waste and post-aluminum dissolution waste spiked with depleted uranium. Waste compositions were determined for supernate and saltcake samples
3-D case studies of monitoring dynamic structural tests using long exposure imagery
Structural health monitoring uses non-destructive testing programmes to detect long-term degradation phenomena in civil
engineering structures. Structural testing may also be carried out to assess a structure’s integrity following a potentially damaging
event. Such investigations are increasingly carried out with vibration techniques, in which the structural response to artificial or
natural excitations is recorded and analysed from a number of monitoring locations. Photogrammetry is of particular interest here
since a very high number of monitoring locations can be measured using just a few images. To achieve the necessary imaging
frequency to capture the vibration, it has been necessary to reduce the image resolution at the cost of spatial measurement accuracy.
Even specialist sensors are limited by a compromise between sensor resolution and imaging frequency.
To alleviate this compromise, a different approach has been developed and is described in this paper. Instead of using high-speed
imaging to capture the instantaneous position at each epoch, long-exposure images are instead used, in which the localised image of
the object becomes blurred. The approach has been extended to create 3D displacement vectors for each target point via multiple
camera locations, which allows the simultaneous detection of transverse and torsional mode shapes. The proposed approach is
frequency invariant allowing monitoring of higher modal frequencies irrespective of a sampling frequency. Since there is no
requirement for imaging frequency, a higher image resolution is possible for the most accurate spatial measurement. The results of a
small scale laboratory test using off-the-shelf consumer cameras are demonstrated. A larger experiment also demonstrates the
scalability of the approach
Charge and Current Sum Rules in Quantum Media Coupled to Radiation
This paper concerns the equilibrium bulk charge and current density
correlation functions in quantum media, conductors and dielectrics, fully
coupled to the radiation (the retarded regime). A sequence of static and
time-dependent sum rules, which fix the values of certain moments of the charge
and current density correlation functions, is obtained by using Rytov's
fluctuational electrodynamics. A technique is developed to extract the
classical and purely quantum-mechanical parts of these sum rules. The sum rules
are critically tested in the classical limit and on the jellium model. A
comparison is made with microscopic approaches to systems of particles
interacting through Coulomb forces only (the non-retarded regime). In contrast
with microscopic results, the current-current correlation function is found to
be integrable in space, in both classical and quantum regimes.Comment: 19 pages, 1 figur
Congested Traffic States in Empirical Observations and Microscopic Simulations
We present data from several German freeways showing different kinds of
congested traffic forming near road inhomogeneities, specifically lane
closings, intersections, or uphill gradients. The states are localized or
extended, homogeneous or oscillating. Combined states are observed as well,
like the coexistence of moving localized clusters and clusters pinned at road
inhomogeneities, or regions of oscillating congested traffic upstream of nearly
homogeneous congested traffic. The experimental findings are consistent with a
recently proposed theoretical phase diagram for traffic near on-ramps [D.
Helbing, A. Hennecke, and M. Treiber, Phys. Rev. Lett. {\bf 82}, 4360 (1999)].
We simulate these situations with a novel continuous microscopic single-lane
model, the ``intelligent driver model'' (IDM), using the empirical boundary
conditions. All observations, including the coexistence of states, are
qualitatively reproduced by describing inhomogeneities with local variations of
one model parameter.
We show that the results of the microscopic model can be understood by
formulating the theoretical phase diagram for bottlenecks in a more general
way. In particular, a local drop of the road capacity induced by parameter
variations has practically the same effect as an on-ramp.Comment: Now published in Phys. Rev. E. Minor changes suggested by a referee
are incorporated; full bibliographic info added. For related work see
http://www.mtreiber.de/ and http://www.helbing.org
The institutional shaping of management: in the tracks of English individualism
Globalisation raises important questions about the shaping of economic action by cultural factors. This article explores the formation of what is seen by some as a prime influence on the formation of British management: individualism. Drawing on a range of historical sources, it argues for a comparative approach. In this case, the primary comparison drawn is between England and Scotland. The contention is that there is a systemic approach to authority in Scotland that can be contrasted to a personal approach in England. An examination of the careers of a number of Scottish pioneers of management suggests the roots of this systemic approach in practices of church governance. Ultimately this systemic approach was to take a secondary role to the personal approach engendered by institutions like the universities of Oxford and Cambridge, but it found more success in the different institutional context of the USA. The complexities of dealing with historical evidence are stressed, as is the value of taking a comparative approach. In this case this indicates a need to take religious practice as seriously as religious belief as a source of transferable practice. The article suggests that management should not be seen as a simple response to economic imperatives, but as shaped by the social and cultural context from which it emerges
Dipolar origin of the gas-liquid coexistence of the hard-core 1:1 electrolyte model
We present a systematic study of the effect of the ion pairing on the
gas-liquid phase transition of hard-core 1:1 electrolyte models. We study a
class of dipolar dimer models that depend on a parameter R_c, the maximum
separation between the ions that compose the dimer. This parameter can vary
from sigma_{+/-} that corresponds to the tightly tethered dipolar dimer model,
to R_c --> infinity, that corresponds to the Stillinger-Lovett description of
the free ion system. The coexistence curve and critical point parameters are
obtained as a function of R_c by grand canonical Monte Carlo techniques. Our
results show that this dependence is smooth but non-monotonic and converges
asymptotically towards the free ion case for relatively small values of R_c.
This fact allows us to describe the gas-liquid transition in the free ion model
as a transition between two dimerized fluid phases. The role of the unpaired
ions can be considered as a perturbation of this picture.Comment: 16 pages, 13 figures, submitted to Physical Review
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