Cathodic reduction of oxygen at new iron complexes

The redox behaviour of some new iron complexes has been studied in both acidic and alkaline solutions. The complexes were adsorbed irreversibly at the pyrolytic graphite disc of a rotating ring(Pt)-disc electrode (RRDE) from a 10–3 m solution of the complex in N,N-dimethylformamide (DMF). Moreover, the electrocatalytic properties of these complexes for the cathodic reduction of oxygen were investigated. Both the redox behaviour and the electrocatalytic effect are discussed in relation to the medium composition as well as the molecular structure of the complex

Evaluation of N-(3-(dimethyl hexadecyl ammonio)propyl) palmitamide bromide as cationic surfactant corrosion inhibitor for API N80 steel in acidic environment

A new cationic surfactant named (N-(3-(dimethyl hexadecyl ammonio)propyl) palmitamide bromide has been evaluated as corrosion inhibitor for API N80 Steel Pipelines in 1M HCl solution. Four different techniques have been utilized for studying the corrosion behavior of the synthesized cationic amphipathic corrosion inhibitor. The prepared corrosion inhibitor was evaluated at five different temperatures 25, 30, 40, 50 and 60 °C, using weight loss technique. The three other techniques which are potentiodynamic polarization, Electrochemical impedance (EIS) and Electrochemical frequency modulation (EFM) were used for evaluation at room temperature (25 °C ± 1). The results outlined that the synthesized DMHPP amphipathic corrosion inhibitor was good inhibitor and their inhibition efficiencies were directly proportional with both the inhibitor concentration and temperature. Polarization curve revealed that the studied inhibitor act as a mixed-type of inhibitor. The adsorption of the used inhibitor led to a reduction in the double layer capacitance and an increase in the charge transfer resistance. The adsorption behavior of the amphipathic inhibitor obey Langmuir adsorption model. The change in free energy of adsorption of the synthesized inhibitor range from −40.5 to −45.5 kJ mol−1 as an indication for chemisorption process between inhibitor and steel. A clear correlation was found between corrosion inhibition efficiency and theoretical parameters obtained using density functional theory (DFT). Keywords: Steel, Cationic surfactant, Potentiodynamic polarization, EIS, EFM, Quantum chemical calculatio