A Density Functional Theory Investigation of Carboranethiol Self-Assembled Monolayer on Au(111)

Isolated and full monolayer adsorption of various carboranethiol (C$_2$B$_{10}$H$_{12}$S) isomers on gold (111) surface have been investigated using both the standard and van der Waals density functional theoretical calculations. The effect of differing molecular dipole moment orientations on the low energy adlayer geometries, the binding characteristics and the electronic properties of the self-assembled monolayers of these isomers have been studied. Specifically, the binding energy and work function changes associated with different molecules show a correlation with their dipole moments. The adsorption is favored for the isomers with dipole moments parallel to the surface. Of the two possible unit cell structures, the (5$\times$5) was found to be more stable than the ($\sqrt{19}\times\sqrt{19}$)R23.4$^o$ one.Comment: 22 pages, 6 figures and 3 table

Single production of excited electrons at future e^-e^+, ep and pp colliders

We analyzed the potential of the LC with $\sqrt{s}=0.5$ TeV, LC$\times$LHC based ep collider with $\sqrt{s}=3.74$ TeV and LHC with $\sqrt{s}=14$ TeV to search for excited electrons through transition magnetic type couplings with gauge bosons. The $e^{\star}\to e\gamma$ signal and corresponding backgrounds are studied in detail.Comment: 11 pages, 11 figures, 3 table

Quantum-dot-spin single-photon interface

Using background-free detection of spin-state-dependent resonance fluorescence from a single-electron charged quantum dot with an efficiency of 0:1%, we realize a single spin-photon interface where the detection of a scattered photon with 300 picosecond time resolution projects the quantum dot spin to a definite spin eigenstate with fidelity exceeding 99%. The bunching of resonantly scattered photons reveals information about electron spin dynamics. High-fidelity fast spin-state initialization heralded by a single photon enables the realization of quantum information processing tasks such as non-deterministic distant spin entanglement. Given that we could suppress the measurement back-action to well below the natural spin-flip rate, realization of a quantum non-demolition measurement of a single spin could be achieved by increasing the fluorescence collection efficiency by a factor exceeding 20 using a photonic nanostructure

Oleogeles de aceites de oliva virgen con cera de carnaúba y monoglicéridos como productos para untar

The oleogels of virgin olive oil with carnauba wax and monoglyceride were prepared to determine the most suitable spreadable product. The oil binding capacities of monoglyceride oleogels were higher than those of the carnauba wax oleogels. There was no true crystalline structure with carnauba wax at 3%. Although the highest solid fat content was in the 10% monoglyceride oleogel (9.38%), it was 12.15% in the commercial breakfast margarine at 20 °C. The peak melting temperature of the margarine was 47.11 °C, and among all oleogels, monoglyceride oleogel at 7% addition had the closest value (48.70 °C). The melting enthalpies of the oleogels ranged from 1.25 to 103.97 J·g−1, while it was 94.19 J·g−1 for the margarine sample. The firmness and stickiness values were usually lower in the oleogel samples than those of the margarine sample. There was no significant change in the texture parameters during storage, indicating good structural stability. The polarized light microscopy pictures revealed rod-like crystals for carnauba wax and rosette-like aggregates for monoglyceride oleogels. X-ray diffraction patterns of the samples have revealed a β´-type polymorphic structure for the oleogels. These oleogels can be used in a spreadable, breakfast margarin-like product to promote new consumption habits for this healthy oil.Se prepararon oleogeles de aceites de oliva virgen con cera de carnaúba y monoglicéridos para encontrar el producto más adecuado para untar. La capacidad de unión de aceites de oleogeles de monoglicéridos fue más alto que el de los oleogeles de cera de carnaúba. No hubo ninguna estructura cristalina verdadera con cera de carnaúba al 3%. Aunque el mayor contenido de grasa sólida fue con el 10 % de oleogeles de monoglicérido (9,38 %), fue del 12.15 % en el de margarina comercial a 20 °C. La temperatura pico de fusión de la margarina fue 47,11 ºC, y entre todos los oleogeles, los de monoglicérido al 7 % tuvo el valor más próximo (48,70 °C). La entalpía de fusión de los oleogeles estaban en el rango entre 1,25 y 103,97 J·g−1 , mientras que fue de 94,19 J·g−1 para la muestra de la margarina. Los valores de firmeza y adherenciafueron por lo general más bajas en las muestras de oleogeles que en la muestra de margarina. Mientras que no hubo cambios significativos en los parámetros de textura durante el almacenamiento, indicando una buena estabilidad estructural. Las imágenes de microscopía de luz polarizada reveló cristales en forma de varilla de cera de carnauba y agregados en forma de rosetones para los oleogeles monoglicéridos. Los diagramas de difracción de rayos X de las muestras reveló tener estructura polimórfica estándar tipo-β´ para los oleogeles. Estos oleogeles pueden ser productos tipo margarina untable para el desayuno y proporcionar nuevos hábitos de consumo saludable

Breeding properties of Tinca tinca (L., 1758) living in Kapulukaya Reservoir (Kirikkale, Turkey)

This study involves the investigation of Tinca tinca (L., 1758) living in Kapulukaya Reservoir in Turkey. It was observed that the fish reach sexual maturity at the age of III and the breeding period starts in May and ends in July. The mean monthly gonadosomatic indices varied from 1.38 ±0.06 (in October) to 8.01±1.03 (in May). According to monthly variations of the GSI, spawning of the tench takes place between May (8.01 ± 1.03) and June (5.50 ± 0.57). The average egg number per fish was estimated to be 23403 ± 17047 . The eggs diameters varied from 0.50 mm to 1.33 mm (mean 0.86 mm). The relations between the fecundity (F) and body length (L) and body weight (W) were found as F = 0.037799 × L 1.0212 (r = 0.70) and F = 0. 00000175 × W 2.8696 (r = 0.62)

Histopathologic and immunohistochemical investigations of dental abscess formed in maxillofacial area

Background: An abscess is a pocket of pus that forms around the root of an infected tooth. In this study, we aimed to investigate the extracellular matrix proteases ADAMTS1, ADAMTS4, osteonectin, and osteopontin expressions in abscess fluid cells in jaws after implantation and prosthesis operation. Materials and methods: In this clinical study, abscess fluids belonging to 17 patients who applied to the Department of Oral and Maxillofacial Surgery were examined histopathologically and immunohistochemically. In the histopathological examination of the abscess fluid, separation of chromatin bridges in the nuclei of neutrophil cells, pyknosis and apoptotic changes in the nucleus, degenerative change in the cytoplasm, and occasional vacuolar structures were observed. Results: The positive reaction of ADAMTS1 was observed in fibroblast cells, plasma cells, and macrophage cells. The positive reaction of ADAMTS4 was observed in fibroblast cells, osteoclast cells, and some apoptotic leukocyte cells. Osteopontin expression in osteoclastic cells and polymorphonuclear cells was defined as positive. Osteonectin expression was positive in polymorphonuclear leukocytes and hypertrophic fibroblast cells. Conclusions: ADAMTS1 and ADAMTS4 may induce bone destruction with its distinctive property in alveolar bone resorption, which promotes the activation of osteoclasts, which can accelerate the destruction of the extracellular matrix in the acute phase. Furthermore, osteoclastic activity increased with the increase of osteonectin and osteopontin protein expression due to inflammation in the abscess cases