Vibration problem of a spherical tank containing jet propellant: numerical simulations

This document is the final report on the joint research project on vibration problem of a spherical tank containing jet propellant between IHI, Japan and SES, University of Southampton, UK. The background of the project is described. The fundamental principles and numerical method used in numerical simulations are presented. The detailed FEA models for each studied cases are given. The calculation results are presented using tables, curves, figures as well as the attached data files. The available experiment results are listed to compare with the numerical calculations. The calculation results show a fundamental agreement with the experiment results. The numerical analysis confirms that:1)Due to water – tank interaction, the natural frequencies of the water – tank system are decreased with the water level increase. For the 25% water level, the natural frequencies, especially heave mode frequency, shows a significant decrease compared with the empty case. However, with continuing increase the filed water more than 25% level, the decrease gradient of the natural frequencies gradually tends to zero. In the 100% water case, the natural frequency of heave mode is about 200 Hz which can not equal zero.2)Considering free surface wave effect produces a lot of sloshing modes of very low frequencies compared with the natural frequencies of the dry tank structure. Therefore, for dynamic response analysis with high frequency excitations, the free surface wave may be neglected. However, to assess loads caused by sloshing modes, the free surface waves have to be considered.3)There exist relative big deformations at the four tank support places in several vibration modes, which may produce a large local stress at support places to cause the product fail in vibration environment. A strengthen local design at the support places is needed.4)The dynamic response results are affected by damping coefficients of all modes used in the dynamic response analysis. The damping coefficients are approximately presented and therefore, the numerical results are good reference for practical designs.The report confirms that the original purpose of this joint research project has well completed by IHI and SES

Mott metal-insulator transition on compressible lattices

The critical properties of the finite temperature Mott endpoint are drastically altered by a coupling to crystal elasticity, i.e., whenever it is amenable to pressure tuning. Similar as for critical piezoelectric ferroelectrics, the Ising criticality of the electronic system is preempted by an isostructural instability, and long-range shear forces suppress microscopic fluctuations. As a result, the endpoint is governed by Landau criticality. Its hallmark is thus a breakdown of Hooke's law of elasticity with a non-linear strain-stress relation characterized by a mean-field exponent. Based on a quantitative estimate, we predict critical elasticity to dominate the temperature range DeltaT/Tc ~ 8% close to the Mott endpoint of kappa-(BEDT-TTF)2X.Comment: 4 pages, 6 figure

A box model study on photochemical interactions between VOCs and reactive halogen species in the marine boundary layer

International audienceA new chemical scheme is developed for the multiphase photochemical box model SEAMAC (size-SEgregated Aerosol model for Marine Air Chemistry) to investigate photochemical interactions between volatile organic compounds (VOCs) and reactive halogen species in the marine boundary layer (MBL). Based primarily on critically evaluated kinetic and photochemical rate parameters as well as a protocol for chemical mechanism development, the new scheme has achieved a near-explicit description of oxidative degradation of up to C3-hydrocarbons (CH4, C2H6, C3H8, C2H4, C3H6, and C2H2) initiated by reactions with OH radicals, Cl- and Br-atoms, and O3. Rate constants and product yields for reactions involving halogen species are taken from the literature where available, but the majority of them need to be estimated. In particular, addition reactions of halogen atoms with alkenes will result in forming halogenated organic intermediates, whose photochemical loss rates are carefully evaluated in the present work. Model calculations with the new chemical scheme reveal that the oceanic emissions of acetaldehyde (CH3CHO) and alkenes (especially C3H6) are important factors for regulating reactive halogen chemistry in the MBL by promoting the conversion of Br atoms into HBr or more stable brominated intermediates in the organic form. The latter include brominated hydroperoxides, bromoacetaldehyde, and bromoacetone, which sequester bromine from a reactive inorganic pool. The total mixing ratio of brominated organic species thus produced is likely to reach 10-20% or more of that of inorganic gaseous bromine species over wide regions over the ocean. The reaction between Br atoms and C2H2 is shown to be unimportant for determining the degree of bromine activation in the remote MBL. These results imply that reactive halogen chemistry can mediate a link between the oceanic emissions of VOCs and the behaviors of compounds that are sensitive to halogen chemistry such as dimethyl sulfide, NOx, and O3 in the MBL