Exact implicit Solution of Nonlinear Heat Transfer in Rectangular Straight Fin Using Symmetry Reduction Methods

In this paper, the exact implicit solution of the second order nonlinear ordinary differential equation which governing heat transfer in rectangular fin is obtained using symmetry reduction methods. General relationship among the temperature at the fin tip, the temperature gradient at the fin base, the mode of heat transfer, and the fin parameters and ℰ is obtained. Some numerical examples are discussed and it is shown that the temperature of fin increases when approaching from the heat source. The relationship between the fin efficiency and the temperature of fin tip is obtained for any value of the mode of heat transfer . The relationship between the fin efficiency and both the parameter and ε the temperature gradient at the fin base is obtained. To our best knowledge, solutions obtained in this paper are new

Spectrophotometric studies on some nitrosonaphthols

1018-1021The UV and visible absorption spectra of some nitrosonaphthol derivatives have been studied in organic solvents of varying polarities. The dependence of the band shift on the nature of substituent, dielectric effect and specific solvation has been studied. The absorption spectra have also been studied in buffer solutions of varying pH values and the acid dissociation constants of the different ionisable groups have been determined using the half-height and the modified limiting absorbance methods. It is found that the nitroso substituent leads to a decrease in ionisation constants of the naphthalenic OH group

Simultaneous determination of paracetamol and tramadol in pharmaceutical tablets by derivative UV-Vis absorption spectrophotometry

A comparative study of the use of first derivative zero order crossing spectra for the resolution of Paracetamol and Tramadol hydrochloride in mixtures has been achieved showing the success of the first derivative method in resolving and quantifying both compounds. Using the first derivative, rather than the second derivative, results in improved signal to noise ratio. The absorption spectra of prepared mixtures were scanned in the range of 200-500 nm. The linear concentration ranges were 25-112 and 6-48 µg mL-1 for paracetamol and Tramadol hydrochloride, respectively. The method has been successfully used for prediction of concentrations of both compounds in mixtures with good selectivity, high sensitivity and extremely low relative error. Statistical comparison was performed using t-test at 95% confidence level. There was no significant statistical difference between the results obtained by the first derivative method and the accepted values for both compounds. Also, the percentage errors were very low which adds to the merits of our work in terms of both sensitivity and accuracy

Synthesis and Applications of a New Polysiloxane-Immobilized Macrocyclic Ligand System

Insoluble porous solid, macrocyclic 22-membered ring, 1-oxa-6,9,12,15,18-pentaaza-2,22-disilacyclododocosane polysiloxane ligand system has been prepared by the reaction of a macro-silane agent with tetraethylorthosilicate. The macro-silane agent was prepared by the reaction of imino-bis(N-2-aminoethylacetamide) ligand with 3-iodopropyltrimethoxysilane in 1:3 molar ratio. The new prepared polysiloxane system exhibits variable potentials for the extraction of metal ions (Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Ag+, Cd2+, Hg2+, and Pb2+) from aqueous solutions. The ligand system shows high capacity to extract silver, lead, and mercury. Chemisorption of the metal ions by the ligand system at the optimum conditions was found in the order Ag + > Pb2+ > Hg2+ > Cu2+ > Ni2+ > Fe3+ > Co2+ > Cd2+ > Zn2+

Electrical properties of organic light emitting diodes with post fabrication heat and electric field treatments

The current work presents post-fabrication heat treatment and a combined external electric field-heat post-fabrication treatments for organic light emitting diodes (OLEDs). The devices were fabricated in the same run with a standard device without annealing for comparison, with an identical structure of ITO/PVK/Rhodamine B/Pb. After depositing the Rhodamine B layer on the PVK film, the samples were thermally annealed at different temperatures before depositing Pb. Some of the samples were thermally annealed without any external electric field while others were treated by an external electric field during heating. It is found that the annealing temperature of PVK/Rhodamine B layers increases the turn-on voltage of the device. On the other hand, in the electric field-heat treatment, the turn-on voltage is observed to decrease and the maximum current density of the device is dramatically enhanced

Dye-sensitized solar cells using dyes extracted from flowers, leaves, parks, and roots of three trees

In this paper, eleven natural dyes were collected from three trees and used as photosensitizers for dye sensitized solar cells (DSSCs). The cells were fabricated using TiO2 as a semiconducting layer deposited on transparent fluorine doped tin oxide (FTO) conductive glass using doctor blade method. The absorption spectra of the extracts were performed in the spectral range from 400 nm to 750 nm. The JV characteristic curves of all fabricated cells were measured and analyzed. The parameters related to the solar cell performance were determined. Moreover, the impedance spectroscopy of the cell with the best performance was investigated

A SIMPLE METHOD FOR DETERMINATION AND CHARACTERIZATION OF IMIDAZOLINONE HERBICIDE (IMAZAPYR/IMAZAPIC) RESIDUES IN CLEARFIELD® RICE SOIL

A study was conducted to evaluate residues of imidazolinone (IMI) in soil. Samples were taken from three Clearfield® rice fields as IMI which have been used for six years. IMI herbicides (imazapic/imazapyr) were widely used in Clearfield® rice soils. To date, few studies are available on the residues of these herbicides, especially in the context of Malaysian soil. Therefore, for this purpose, high performance liquid chromatography (HPLC) with UV detection was performed using a Zorbax stable bond C18 (4.6× 250 mm, 5 µm) column, with two mobile phases. The average percentage recovery for imazapyr and imazapic varied from 76%-107% and 71-77%, with 0.1-5 µg/ml fortification level, respectively. The limit of detection (LOD) and limit of quantification (LOQ) were found to be 1.05 and 4.09 for imazapic and 0.171 and 0.511 µg/ml for imazapyr respectively, in the top 15 cm. In the extracted soil sample, it was 0.19 µg/ml for imazapic and 0.04 µg/ml for imazapyr, respectively. Based on this study, a pre-harvest period of 40-60 day is suggested for rice crops after IMI application

Thermoelectricity Based on Cuo as a Semiconducting Material

In this paper, thermoelectricity based on copper(II) oxide CuO as semiconducting material is explored. The electrical properties of the samples were studied under different temperature gradients and pressures. Moreover, the effect of baking temperature was also investigated. CuO prepared using decomposition of Cu(NO3)2 as well as CuO nanopowder prepared using microwave-assisted synthesis technique were investigated and their results were compared. It was found that the current density can be enhanced with increasing the pressing pressure of the sample and when the sample undergoes a baking process. Moreover, it was found that the current density can be considerably enhanced with increasing the temperature gradient between the two ends of the sample. The CuO prepared using microwave-assisted synthesis technique was found to exhibit much better results over those of the CuO prepared using decomposition of Cu(NO3)2