Quantum Griffiths phase in CePd(1-x)Rh(x) with x ~ 0.8

The magnetic field dependence of the magnetisation ($M$) and the temperature dependence of the ac susceptibility ($\chi' = dM/dH$) of CePd(1-x)Rh(x) single crystals with $0.80 \leq x \leq 0.86$ are analysed within the frame of the quantum Griffiths phase scenario, which predicts $M \propto H^{\lambda}$ and $\chi' \propto T^{\lambda-1}$ with $0 \leq \lambda \leq 1$. All $M$ vs $H$ and $\chi'$ vs $T$ data follow the predicted power-law behaviour. The parameter $\lambda$, extracted from $\chi'(T)$, is very sensitive to the Rh content $x$ and varies systematically with $x$ from -0.1 to 0.4. The value of $\lambda$, derived from $M(H)$ measurements on a \cpr single crystal, seems to be rather constant, $\lambda \approx 0.2$, in a broad range of temperatures between 0.05 and 2 K and fields up to about 10 T. All observed signatures and the $\lambda$ values are thus compatible with the quantum Griffiths scenario.Comment: 4 pages, 3 figure

Universal low-temperature behavior of the CePd_{1-x}Rh_x ferromagnet

The heavy-fermion metal CePd_{1-x}Rh_x evolves from ferromagnetism at x=0 to a non-magnetic state at some critical concentration x_c. Utilizing the quasiparticle picture and the concept of fermion condensation quantum phase transition (FCQPT), we address the question about non-Fermi liquid (NFL) behavior of ferromagnet CePd_{1-x}Rh_x and show that it coincides with that of both antiferromagnet YbRh_2(Si_{0.95}Ge_{0.05})_2 and paramagnet CeRu_2Si_2 and CeNi_2Ge_2. We conclude that the NFL behavior being independent of the peculiarities of specific alloy, is universal, while numerous quantum critical points assumed to be responsible for the NFL behavior of different HF metals can be well reduced to the only quantum critical point related to FCQPT.Comment: 6 pages, 7 figure

Giant crystal-electric-field effect and complex magnetic behavior in single-crystalline CeRh3Si2

Single-crystalline CeRh3Si2 was investigated by means of x-ray diffraction, magnetic susceptibility, magnetization, electrical resistivity, and specific heat measurements carried out in wide temperature and magnetic field ranges. Moreover, the electronic structure of the compound was studied at room temperature by cerium core-level x-ray photoemission spectroscopy (XPS). The physical properties were analyzed in terms of crystalline electric field and compared with results of ab-initio band structure calculations performed within the density functional theory approach. The compound was found to crystallize in the orthorhombic unit cell of the ErRh3Si2 type (space group Imma -- No.74, Pearson symbol: oI24) with the lattice parameters: a = 7.1330(14) A, b = 9.7340(19) A, and c = 5.6040(11) A. Analysis of the magnetic and XPS data revealed the presence of well localized magnetic moments of trivalent cerium ions. All physical properties were found to be highly anisotropic over the whole temperature range studied, and influenced by exceptionally strong crystalline electric field with the overall splitting of the 4f1 ground multiplet exceeding 5700 K. Antiferromagnetic order of the cerium magnetic moments at TN = 4.70(1)K and their subsequent spin rearrangement at Tt = 4.48(1) K manifest themselves as distinct anomalies in the temperature characteristics of all investigated physical properties and exhibit complex evolution in an external magnetic field. A tentative magnetic B-T phase diagram, constructed for B parallel to the b-axis being the easy magnetization direction, shows very complex magnetic behavior of CeRh3Si2, similar to that recently reported for an isostructural compound CeIr3Si2. The electronic band structure calculations corroborated the antiferromagnetic ordering of the cerium magnetic moments and well reproduced the experimental XPS valence band spectrum.Comment: 32 pages, 12 figures, to appear in Physical Review

The effect of Camelina sativa cake diet supplementation on sensory and volatile profiles of ewe’s milk

The aim of this study was to evaluate the sensory profile based on the principal component analysis (PCA) and cluster analysis of Euclidean distances as well as evaluate a volatile profile in ewes’ milk. The analysis was conducted using SPME GC/TOFMS. Tested milk came from ewes fed concentrate supplemented with 10 and 20% Camelina sativa (L.) Crantz cake (CSC). This plant containing unsaturated fatty acids as well as natural antioxidants (for example, tocopherol), may constitute an excellent source of energy in the feed ratio for animals, at the same time improving the composition of fatty acids in milk fats. Milk of ewes fed CSC had a distinct animal, grainy and processed aroma. After pasteurization, the cooked and dairy fat aroma intensified. At the same time the overall dairy aroma, highly characteristic of the control milk, was considerably reduced. An addition of CSC to the diet of ewes resulted in an increase in the content of volatiles, primarily fatty acids. The applied milk pasteurization had a significant effect on a further increase in the contents of volatiles. First of all furans, furanones and furfural, being the Maillard reaction products, were accumulated.Key words: Sheep milk, sensory analysis, flavor analysis, volatiles in milk

Shape anisotropy effect on magnetic domain wall dynamics in nanowires under thermal gradient

We investigate the magnetic-domain wall (DW) dynamics in uniaxial/biaxial-nanowires under a thermal gradient (TG). The findings reveal that the DW propagates toward the hotter region in both nanowires. In uniaxial-nanowire, the DW propagates accompanying a rotation of the DW-plane. In biaxial nanowire, DW propagates in the hotter region, and the so-called Walker breakdown phenomenon is observed. The main physics of such DW dynamics is the magnonic angular momentum transfer to the DW. The hard (shape) anisotropy exists in biaxial-nanowire, which contributes an additional torque; hence DW speed is larger than that in uniaxial-nanowire. But rotational speed is lower initially as hard anisotropy suppresses the DW-rotation. After certain TG, DW-plane overcomes the hard anisotropy; thus, the rotational speed increases again. DW dynamics show a decreasing trend with the damping since the magnon propagation length decreases. Therefore, the above findings might be useful to realize the spintronics (i.e., fast racetrack memory) devices

Universal behavior of CePd1−xRhx\rm CePd_{1-x}Rh_x Ferromagnet at Quantum Critical Point

The heavy-fermion metal $\rm CePd_{1-x}Rh_x$ can be tuned from ferromagnetism at $x=0$ to non-magnetic state at some critical concentration $x_c$. The non-Fermi liquid behavior (NFL) at $x\simeq x_c$ is recognized by power low dependence of the specific heat $C(T)$ given by the electronic contribution, magnetic susceptibility $\chi(T)$ and volume expansion coefficient $\alpha(T)$ at low temperatures: $C/T\propto\chi(T)\propto\alpha(T)/T\propto1/\sqrt{T}$. We also demonstrate that the behavior of normalized effective mass $M^*_N$ observed in $\rm CePd_{1-x}Rh_x$ at $x\simeq 0.8$ agrees with that of $M^*_N$ observed in paramagnetic $\rm CeRu_2Si_2$ and conclude that these alloys exhibit the universal NFL thermodynamic behavior at their quantum critical points. We show that the NFL behavior of $\rm CePd_{1-x}Rh_x$ can be accounted for within frameworks of quasiparticle picture and fermion condensation quantum phase transition, while this alloy exhibits a universal thermodynamic NFL behavior which is independent of the characteristic features of the given alloy such as its lattice structure, magnetic ground state, dimension etc.Comment: 5 pages, 3 figure

Kondo-Cluster-Glass State near a Ferromagnetic Quantum Phase Transition

We report on a comprehensive study of CePd$_{1-x}$Rh$_x$ $(0.6 \leq x \leq 0.95)$ poly- and single crystals close to the ferromagnetic instability by means of low-temperature ac susceptibility, magnetization and volume thermal expansion. The signature of ferromagnetism in this heavy-fermion system can be traced from 6.6 K in CePd down to 25 mK for $x=0.87$. Despite pronounced non-Fermi-liquid (NFL) effects in both, specific heat and thermal expansion, the Gr\"uneisen ratio {\it does not} diverge as $T\to 0$, providing evidence for the absence of a quantum critical point. Instead, a peculiar "Kondo-cluster-glass" state is found for $x\geq 0.65$, and the NFL effects in the specific heat, ac susceptibility and magnetization are compatible with the quantum Griffiths phase scenario.Comment: 4 pages, 4 figure