Effect of hydrolysis time on the morphological, physical, chemical, and thermal behavior of sugar palm nanocrystalline cellulose (Arenga pinnata (Wurmb.) Merr)

Sugar palm nanocrystalline celluloses (SPNCCs) were isolated from sugar palm fiber (SPF). In this study, acid hydrolysis (60 wt. %) at different reaction times (30, 45, and 60 min) was carried out to investigate the optimum yield of NCC. The physical properties, degree of polymerization, chemical composition, structural analysis, crystallinity, surface area and charge, zeta potential, thermal analysis, and morphological characterization were also conducted to determine the outcome (efficiency) of the process. The results showed that a needle-like shape was observed under transmission electron microscopy (TEM) studies. TEM analysis showed optimum aspect ratios of 13.46, 14.44, and 13.13 for isolated SPNCC-I, SPNCC-II, and SPNCC-III, respectively. From thermogravimetric analysis (TGA), the degradation temperature of NCC decreased slightly from 335.15? to 278.50? as the reaction time increased. A shorter hydrolysis time tended to produce SPNCC with higher thermal stability, as proven in thermal analysis by TGA. The optimal isolation time was found to be around 45 min at 1200 rpm during hydrolysis at 45? with 60% sulfuric acid. Therefore, the extracted SPNCC from SPF has huge potential to be utilized in the bionanocomposite field for the production of biopackaging, biomedical products, etc

A review on natural fiber reinforced polymer composite for bullet proof and ballistic applications

Even though natural fiber reinforced polymer composites (NFRPCs) have been widely used in automotive and building industries, there is still a room to promote them to high-level structural applications such as primary structural component specifically for bullet proof and ballistic applications. The promising performance of Kevlar fabrics and aramid had widely implemented in numerous ballistic and bullet proof applications including for bullet proof helmets, vest, and other armor parts provides an acceptable range of protection to soldiers. However, disposal of used Kevlar products would affect the disruption of the ecosystem and pollutes the environment. Replacing the current Kevlar fabric and aramid in the protective equipment with natural fibers with enhanced kinetic energy absorption and dissipation has been significant effort to upgrade the ballistic performance of the composite structure with green and renewable resources. The vast availability, low cost and ease of manufacturing of natural fibers have grasped the attention of researchers around the globe in order to study them in heavy armory equipment and high durable products. The possibility in enhancement of natural fiber’s mechanical properties has led the extension of research studies toward the application of NFRPCs for structural and ballistic applications. Hence, this article established a state-of-the-art review on the influence of utilizing various natural fibers as an alternative material to Kevlar fabric for armor structure system. The article also focuses on the effect of layering and sequencing of natural fiber fabric in the composites to advance the current armor structure system

Mechanical performance and applications of cnts reinforced polymer composites—A review

Developments in the synthesis and scalable manufacturing of carbon nanomaterials like carbon nanotubes (CNTs) have been widely used in the polymer material industry over the last few decades, resulting in a series of fascinating multifunctional composites used in fields ranging from portable electronic devices, entertainment and sports to the military, aerospace, and automotive sectors. CNTs offer good thermal and electrical properties, as well as a low density and a high Young’s modulus, making them suitable nanofillers for polymer composites. As mechanical reinforcements for structural applications CNTs are unique due to their nano-dimensions and size, as well as their incredible strength. Although a large number of studies have been conducted on these novel materials, there have only been a few reviews published on their mechanical performance in polymer composites. As a result, in this review we have covered some of the key application factors as well as the mechanical properties of CNTs-reinforced polymer composites. Finally, the potential uses of CNTs hybridised with polymer composites reinforced with natural fibres such as kenaf fibre, oil palm empty fruit bunch (OPEFB) fibre, bamboo fibre, and sugar palm fibre have been highlighted

Thermogravimetric analysis properties of cellulosic natural fiber polymer composites: a review on influence of chemical treatmentst

Natural fiber such as bamboo fiber, oil palm empty fruit bunch (OPEFB) fiber, kenaf fiber, and sugar palm fiber-reinforced polymer composites are being increasingly developed for lightweight structures with high specific strength in the automotive, marine, aerospace, and construction indus-tries with significant economic benefits, sustainability, and environmental benefits. The plant-based natural fibers are hydrophilic, which is incompatible with hydrophobic polymer matrices. This leads to a reduction of their interfacial bonding and to the poor thermal stability performance of the resulting fiber-reinforced polymer composite. Based on the literature, the effect of chemical treatment of natural fiber-reinforced polymer composites had significantly influenced the thermogravimetric analysis (TGA) together with the thermal stability performance of the composite structure. In this review, the effect of chemical treatments used on cellulose natural fiber-reinforced thermoplastic and thermosetting polymer composites has been reviewed. From the present review, the TGA data are useful as guidance in determining the purity and composition of the composites’ structures, drying, and the ignition temperatures of materials. Knowing the stability temperatures of compounds based on their weight, changes in the temperature dependence is another factor to consider regarding the effectiveness of chemical treatments for the purpose of synergizing the chemical bonding between the natural fiber with polymer matrix or with the synthetic fibers

Thermogravimetric analysis properties of cellulosic natural fiber polymer composites: a review on influence of chemical treatments

Natural fiber such as bamboo fiber, oil palm empty fruit bunch (OPEFB) fiber, kenaf fiber, and sugar palm fiber-reinforced polymer composites are being increasingly developed for lightweight structures with high specific strength in the automotive, marine, aerospace, and construction industries with significant economic benefits, sustainability, and environmental benefits. The plant-based natural fibers are hydrophilic, which is incompatible with hydrophobic polymer matrices. This leads to a reduction of their interfacial bonding and to the poor thermal stability performance of the resulting fiber-reinforced polymer composite. Based on the literature, the effect of chemical treatment of natural fiber-reinforced polymer composites had significantly influenced the thermogravimetric analysis (TGA) together with the thermal stability performance of the composite structure. In this review, the effect of chemical treatments used on cellulose natural fiber-reinforced thermoplastic and thermosetting polymer composites has been reviewed. From the present review, the TGA data are useful as guidance in determining the purity and composition of the composites’ structures, drying, and the ignition temperatures of materials. Knowing the stability temperatures of compounds based on their weight, changes in the temperature dependence is another factor to consider regarding the effectiveness of chemical treatments for the purpose of synergizing the chemical bonding between the natural fiber with polymer matrix or with the synthetic fibers

Fiber-Reinforced Polymer Nanocomposites

“Fiber-Reinforced Polymer Nanocomposites” is a newly open Special Issue of Nanomaterials, which aims to publish original and review papers on new scientific and applied research and make boundless contributions to the finding and understanding of the reinforcing effects of various nanomaterials on the performance of polymer nanocomposites [...

Treatments of natural fiber as reinforcement in polymer composites-a short review

The demand for environmental awareness, preserving nature and being beneficial for societal economics has attracted the attention of many researchers and industries to examine the potential usage of natural fibers. There are a lot of beneficial natural fiber sources in a wide range of applications in the composites industry. It is worth mentioning that the performance of natural fiber-reinforced composites can be tailored through a certain natural fiber treatment, and hybridization by employing an appropriate number of synthetic fibers or with other natural fibers. In addition to cost-effectiveness balance, a balance between environmental impacts and desired performance can be achieved by designing the composite based on the product requirements. Yet, certain drawbacks such as incompatibility with the hydrophobic polymer matrix, hydrophilic nature and the tendency to absorb moisture during processing greatly reduce the potential of natural fibers to be used as reinforcements in polymer composites. In this short review, the main results presented in the literature are summarized, focusing on the properties and challenges of natural fibers, the processing behavior of natural fiber treatments, and paying attention to the use of physical and chemical treatments for the improvement of fiber-matrix interaction as reinforcement for polymeric matrices (thermoplastics, thermosets and biodegradables)

Advancement in fiber reinforced polymer, metal alloys and multi-layered armour systems for ballistic applications – a review

The recent research and development performed for armour systems for material selection and analysis has helped discover new and significant material properties suited for ballistic applications. The realm of ballistic studies has employed advanced materials to provide the desired performance, considering the strict requirement of perfect material selection for armour systems. Energy absorption, ballistic limit, and depth of indentation are the most important parameters to be analyzed for an efficient armour system. The importance of utilizing appropriate materials for armour system is necessary, to achieve higher energy absorption, ballistic limit, and low blunt trauma (<44 mm), while simultaneously ensuring the armour has low weight. The aim of this review is to analyze the different armour systems such as fiber reinforced polymeric composites, metallic and multilayer armour systems (MAS) to understand their response on ballistic impact. Also, the importance of advanced fabrication techniques such as bio-inspired fabrication and additive manufacturing for armour applications has been addressed in detail. Moreover, this review critically analyzed the possible ways to enhance the ballistic performance of fiber reinforced polymeric composites, metallic materials, and MAS

Mechanical performance evaluation of bamboo fibre reinforced polymer composites and its applications: a review

This paper reviews the mechanical performance of bamboo fibre reinforced polymer composites (BFRPs) for structural applications. Bamboo fibres are very promising reinforcements for polymer composites production due to their high aspect ratio, renewability, environmentally friendly, non-toxicity, cheap cost, non-abrasives, full biodegradability, and strong mechanical performances. Besides, bamboo has its own prospects and good potential to be used in biopolymer composites as an alternative for petroleum-based materials to be used in several advanced applications in the building and construction industry. For bamboo fibre to be reinforced with polymer, they must have good interfacial bond between the polymer, as better fibre and matrix interaction results in good interfacial adhesion between fibre/matrix and fewer voids in the composite. Several important factors to improve matrix-fibre bonding and enhance the mechanical properties of BFRP are by fibre treatment, hybridisation, lamination, and using coupling agent. Moreover, mechanical properties of BFRP are greatly influenced by few factors, such as type of fibre and matrix used, fibre-matrix adhesion, fibre dispersion, fibre orientation, composite manufacturing technique used, void content in composites, and porosity of composite. In order to better understand their reinforcing potential, the mechanical properties of this material is critically discussed in this review paper. In addition, the advantages of bamboo fibres as the reinforcing phase in polymer composites is highlighted in this review paper. Besides that, the bamboo-based products such as laminated bamboo lumber, glued-laminated bamboo, hybrid bamboo polymer composites, parallel bamboo strand lumber, parallel strand bamboo, bamboo-oriented strand board, and bamboo-scrimber have lately been developed and used in structural applications

Effect of Wood Dust Fibre Treatments Reinforcement on the Properties of Recycled Polypropylene Composite (r-WoPPC) Filament for Fused Deposition Modelling (FDM)

The efficacy of wood dust fibre treatment on the property of wood dust reinforced recycled polypropylene composite (r-WoPPC) filament was investigated. The wood dust fibre was treated using alkali, silane, and NaOH-silane. The treated wood fibre was incorporated with r-PP using a twin-screw extruder to produce filament. The silane treatment on wood dust fibre enhances interfacial bonding between wood fibre and recycled PP; hence, a filament has the highest wire pull strength, which is 35.2% higher compared to untreated and alkaline-treated wood dust filament. It is because silanol in silane forms a siloxane bond that acts as a coupling agent that improves interfacial bonding between wood dust fibre and recycled PP. The SEM micrograph of the fracture structure reveals that treated silane has strong interfacial bonding between wood dust fibre and recycled PP, having minimal void, gap, and good fibre adhesion. The water absorption test results indicate that filament with treated wood dust absorbs less water than filament with untreated wood because the treatment minimizes the gap between wood fibres and recycled PP. The FTIR analysis identified the presence of silane on the wood dust surface for silane-treated wood dust. The DSC studies suggest that the temperature range 167–170 °C be used in the extrusion machine to produce r-WoPPC filament. As a result, r-WoPPc filaments containing silane-treated wood dust have better mechanical properties and have a greater potential for usage in FDM applications