64 research outputs found
Single step process for the synthesis of carbon nanotubes and metal/alloy-filled multiwalled carbon nanotubes
A single-step approach for the synthesis of multi-walled nanotubes (MWNT) filled with nanowires of Ni/ternary Zr based hydrogen storage alloy has been illustrated. We also demonstrate the generation of CO-free hydrogen by methane decomposition over alloy hydride catalyst. The present work also highlights the formation of single-walled nanotubes (SWNT) and MWNTs at varying process conditions. These carbon nanostructures have been characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution TEM (HRTEM), Energy dispersive X-ray analysis (EDX) and Raman spectroscopy. This new approach overcomes the existing multi-step process limitation, with possible impact on the development of future fuel cell, nano-battery and hydrogen sensor technologies
Nanoarchitectured 3D cathodes for Li-Ion microbatteries
Microbatteries with large area capacity and no power limitation can be obtained by designing 3D structured batteries. 3D electrodes composed of 30 nm-thick films of LiCoO2 coating free-standing columns of Al current collector were achieved. By comparison with a planar electrode presenting an equivalent nominal capacity, a 3D electrode exhibits improved capacity retention: 68% of the nominal capacity at 8C instead of 11%
3D lithium ion batteries—from fundamentals to fabrication
3D microbatteries are proposed as a step change in the energy and power per footprint of surface mountable rechargeable batteries for microelectromechanical systems (MEMS) and other small electronic devices. Within a battery electrode, a 3D nanoarchitecture gives mesoporosity, increasing power by reducing the length of the diffusion path; in the separator region it can form the basis of a robust but porous solid, isolating the electrodes and immobilising an otherwise fluid electrolyte. 3D microarchitecture of the whole cell allows fabrication of interdigitated or interpenetrating networks that minimise the ionic path length between the electrodes in a thick cell. This article outlines the design principles for 3D microbatteries and estimates the geometrical and physical requirements of the materials. It then gives selected examples of recent progress in the techniques available for fabrication of 3D battery structures by successive deposition of electrodes, electrolytes and current collectors onto microstructured substrates by self-assembly methods
Effect of Purity and Substrate on Field Emission Properties of Multi-walled Carbon Nanotubes
Multi-walled carbon nanotubes (MWNT) have been synthesized by chemical vapour decomposition (CVD) of acetylene over Rare Earth (RE) based AB2(DyNi2) alloy hydride catalyst. The as-grown carbon nanotubes were purified by acid and heat treatments and characterized using powder X-ray diffraction, Scanning Electron Microscopy, Transmission Electron Microscopy, Thermo Gravimetric Analysis and Raman Spectroscopy. Fully carbon based field emitters have been fabricated by spin coating a solutions of both as-grown and purified MWNT and dichloro ethane (DCE) over carbon paper with and without graphitized layer. The use of graphitized carbon paper as substrate opens several new possibilities for carbon nanotube (CNT) field emitters, as the presence of the graphitic layer provides strong adhesion between the nanotubes and carbon paper and reduces contact resistance. The field emission characteristics have been studied using an indigenously fabricated set up and the results are discussed. CNT field emitter prepared by spin coating of the purified MWNT–DCE solution over graphitized carbon paper shows excellent emission properties with a fairly stable emission current over a period of 4 h. Analysis of the field emission characteristics based on the Fowler–Nordheim (FN) theory reveals current saturation effects at high applied fields for all the samples
On the growth mechanism of nickel and cobalt nanowires and comparison of their magnetic properties
Synthesis of High Coercivity Cobalt Nanotubes with Acetate Precursors and Elucidation of the Mechanism of Growth
Cobalt nanotubes (CoNTs) with very high longitudinal coercivity were prepared by electrodeposition of cobalt
acetate for the first time by using anodized alumina (AAO) template. They were then characterized with
X-ray diffraction (XRD), a field emission scanning electron microscope (FESEM), and a transmission electron
microscope (TEM). Formation of a highly ordered hexagonal cobalt phase is observed. Room temperature
SQUID (superconducting quantum interference device) magnetometer measurements indicate that the easy
axis of magnetization is parallel to the nanotube axis. These CoNTs exhibit very high longitudinal coercivity
of ∼820 Oe. A very high intertubular interaction resulting from magnetostatic dipolar interaction between
nanotubes is observed. Thick-walled nanotubes were also fabricated by using cobalt acetate tetrahydrate
precursors. A plausible mechanism for the formation of CoNTs based on mobility assisted growth is proposed.
The role of the hydration layer and the mobility of metal ions are elucidated in the case of the growth mechanism
of one-dimensional geometryCochin UniVersity of Science & TechnologyJ. Phys. Chem. C 2008, 112, 14281–1428
On the Growth Mechanism of Nickel and Cobalt Nanowires and Comparison of Their Magnetic Properties
Magnetic nanowires (NWs) are ideal materials for the fabrication of various multifunctional nanostructures
which can be manipulated by an external magnetic fi eld. Highly crystalline and textured nanowires of nickel
(Ni NWs) and cobalt (Co NWs) with high aspect ratio (~330) and high coercivity have been synthesized
by electrodeposition using nickel sulphate hexahydrate (NiSO4·6H2O) and cobalt sulphate heptahydrate
(CoSO4·7H2O) respectively on nanoporous alumina membranes. They exhibit a preferential growth along〈110〉.
A general mobility assisted growth mechanism for the formation of Ni and Co NWs is proposed. The role of
the hydration layer on the resulting one-dimensional geometry in the case of potentiostatic electrodeposition
is verified. A very high interwire interaction resulting from magnetostatic dipolar interactions between the
nanowires is observed. An unusual low-temperature magnetisation switching for fi eld parallel to the wire axis
is evident from the peculiar high fi eld M(T) curveCochin University of Science & TechnologyNano Res (2008) 1: 465 47
Direct deposition of MoSe2 nanocrystals onto conducting substrates: towards ultra-efficient electrocatalysts for hydrogen evolution
There is an urgent need to develop efficient and cost-effective catalysts for the hydrogen evolution reaction (HER) in order to realize a hydrogen economy with clean and renewable energy. Nanostructures of layered transition metal dichalcogenides show promising electrocatalytic activity towards the hydrogen evolution reaction, however, the majority of the exposed surfaces (basal planes) are inactive, and engineering their catalytically active edge sites still remains a challenge. Here we show that monodisperse single/fewlayered MoSe2 nanocrystals can be directly deposited onto any conducting substrate, through electrochemical exfoliation of bulk MoSe2, which exhibit remarkable electrocatalytic activity for the HER with ultra-high efficiency showing a very low on-set potential (70.9 mV vs. the RHE) and Tafel slope (31.8 mV dec (1)). The exceptional electrocatalytic activity of the MoSe2 nanocrystals results from the synergistic advantages emerging from improved edge sites, enhanced electronic conductivity and the presence of new and active sites arising upon in situ lithiation, all in one step, which is facile, economic and environmentally benign
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