Synthesis and spectroscopic characterization of Ru(II) and Sn(IV)-porphyrins supramolecular complexes

Copyright © 2014 Published by Elsevier B.V. All rights reserved. Synthesis and NMR studies of Ru(II) and Sn(IV) tetraphenylporphyrins supramolecular complexes were carried out. The diffusion coefficients of the complexes, porphyrinates, and solvents were determined by DOSY NMR spectroscopy. By the method of spectrophotometric titration a binding ability of Ru(II) tetraphenylporphyrin towards 4-(imidazol-1-yl)-phenol was investigated, stability constant of resulting complexes and concentration intervals of their existence were defined. Crow

Symmetrical and difunctional substituted cobalt phthalocyanines with benzoic acids fragments: Synthesis and catalytic activity

© 2017 World Scientific Publishing Company Difunctional and symmetric phthalonitriles were synthesized by nucleophilic substitution of brome and nitro-group in 4-bromo-5-nitro-phthalonitrile for residues 4-amino-, 4-hydroxyl- and 4-sulfanyl benzoic acid. Symmetrical and difunctional substituted cobalt phthalocyanines were obtained by template synthesis based on mentioned phthalonitriles. Their spectral properties and catalytic activity in aerobic oxidation of sodium (Formula presented.),(Formula presented.)-carbomoditiolate were investigated

Symmetrical and difunctional substituted cobalt phthalocyanines with benzoic acids fragments: Synthesis and catalytic activity

© 2017 World Scientific Publishing Company.Difunctional and symmetric phthalonitriles were synthesized by nucleophilic substitution of brome and nitro-group in 4-bromo-5-nitro-phthalonitrile for residues 4-amino-, 4-hydroxyl- and 4-sulfanyl benzoic acid. Symmetrical and difunctional substituted cobalt phthalocyanines were obtained by template synthesis based on mentioned phthalonitriles. Their spectral properties and catalytic activity in aerobic oxidation of sodium N,N-carbomoditiolate were investigated

Aza-substitution, benzo-annulation effects and catalytic activity of β-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis

© 2016, Springer Science+Business Media Dordrecht.The influence of the size of conjugated π-system on catalytic activity of cobalt complex with β-octaphenylporphyrin and its tetraaza-, tetrabenzo and tetrabenzotetraaza derivatives was studied in present work. It is found that catalytic activity for oxidation of sulfur-containing compounds increases under extension of conjugated macrocycle system according to the following series CoP < CoBP ≤ CoPz < CoPPz ≪ CoPc

Parental Tobacco Smoking and the Risk of Acute Myeloid Leukemia in Children: the Childhood Leukemia International Consortium (CLIC).

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