© 2016, Springer Science+Business Media Dordrecht.The influence of the size of conjugated π-system on catalytic activity of cobalt complex with β-octaphenylporphyrin and its tetraaza-, tetrabenzo and tetrabenzotetraaza derivatives was studied in present work. It is found that catalytic activity for oxidation of sulfur-containing compounds increases under extension of conjugated macrocycle system according to the following series CoP < CoBP ≤ CoPz < CoPPz ≪ CoPc

Golubchikov O.

Koifman O.

Kuzmin I.

Maizlish V.

Petrov O.

Pukhovskaya S.

Razumov M.

Vashurin A.

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Kazan Federal University Digital Repository

Journal of Inclusion Phenomena and Macrocyclic Chemistry 2017 vol.87 N1-2, pages 37-43Aza-substitution, benzo-annulation effects and catalyticactivity of β-octaphenyl-substituted tetrapyrrolicmacroheterocyclic cobalt complexes. I. heterogeneouscatalysisVashurin A., Maizlish V., Kuzmin I., Petrov O., Razumov M., Pukhovskaya S., Golubchikov O.,Koifman O.Kazan Federal University, 420008, Kremlevskaya 18, Kazan, RussiaAbstract© 2016, Springer Science+Business Media Dordrecht.The influence of the size of conjugated π-system on catalytic activity of cobalt complex with β-octaphenylporphyrin and its tetraaza-,tetrabenzo and tetrabenzotetraaza derivatives was studied in present work. It is found thatcatalytic activity for oxidation of sulfur-containing compounds increases under extension ofc o n j u g a t e d  ma c r o c y c l e  s y s t em  a c c o r d i n g  t o  t h e  f o l l ow i n g  s e r i e sCoP  <  CoBP  ≤  CoPz  <  CoPPz  ≪  CoPc.http://dx.doi.org/10.1007/s10847-016-0674-4KeywordsAza-substitution, Benzo-annulation, Catalyst, Metal complex, Oxidation, Sodium N,N-carbomodithiolate, β-OctaphenylporphyrinReferences[1] Bricker,  J.S.,  Laricchia,  L.:  Advances in Merox™ process and catalysis  for  thiol  oxidation.  Top.  Catal.  55,1315–1323 (2012)[2] Khorshidifard, M., Rudbari, H.A., Askari, B., Sahihi, M., Farsani, M.R., Jalilian, F., Bruno, G.: Cobalt(II), copper(II),zinc(II)  and palladium(II)  schiff  base complexes:  synthesis,  characterization  and catalytic  performance inselective oxidation of sulfides using hydrogen peroxide under solvent-free conditions. 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Aza-substitution, benzo-annulation effects and catalytic activity of β-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis

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Aza-substitution, benzo-annulation effects and catalytic activity of β-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis

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