SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL STUDIES OF SOME LANTHANIDE (III) COMPLEXES WITH A TRIDENTATE ONO DONOR SCHIFF BASE LIGAND

Some new lanthanide(III) complexes- La(III), Ce(III), Pr(III) and Nd(III) have been synthesised from Schiff base ligand 4-{[(2-hydroxyphenyl)imino]methyl}-1,5-dimethyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one (L1) whose precursors are 4-antipyrine carboxaldehyde and 2-aminophenol. The metal to ligand ratio (1:2) and the general formula [Ln(L1)2(NO3)2]NO3 were established by elemental analysis, conductivity measurements, spectral techniques such as IR, UV-Visible, 1H NMR as well as magnetic susceptibility measurements. L1 behave as a neutral tridentate (ONO) ligand and Ln(III) ion display coordination number eight in all complexes. The Schiff base and complexes were screened for their in vitro antimicrobial activities against selected human pathogenic bacteria by agar disc diffusion method. Most of the synthesized complexes were found to be more potent bactericides than the corresponding free ligand

Thermodynamic structure of the Atmospheric Boundary Layer over the Arabian Sea and the Indian Ocean during pre-INDOEX and INDOEX-FFP campaigns

Spatial and temporal variability of the Marine Atmospheric Boundary Layer (MABL) height for the Indian Ocean Experiment (INDOEX) study period are examined using the data collected through Cross-chained LORAN (Long-Range Aid to Navigation) Atmospheric Sounding System (CLASS) launchings during the Northern Hemispheric winter monsoon period. This paper reports the results of the analyses of the data collected during the pre-INDOEX (1997) and the INDOEX-First Field Phase (FFP; 1998) in the latitude range 14°N to 20°S over the Arabian Sea and the Indian Ocean. Mixed layer heights are derived from thermodynamic profiles and they indicated the variability of heights ranging from 400m to 1100m during daytime depending upon the location. Mixed layer heights over the Indian Ocean are slightly higher during the INDOEX-FFP than the pre-INDOEX due to anomalous conditions prevailing during the INDOEX-FFP. The trade wind inversion height varied from 2.3km to 4.5km during the pre-INDOEX and from 0.4km to 2.5km during the INDOEX-FFP. Elevated plumes of polluted air (lofted aerosol plumes) above the marine boundary layer are observed from thermodynamic profiles of the lower troposphere during the INDOEX-FFP. These elevated plumes are examined using 5-day back trajectory analysis and show that one group of air mass travelled a long way from Saudi Arabia and Iran/Iraq through India before reaching the location of measurement, while the other air mass originates from India and the Bay of Bengal

Toxic Metals Enrichment in the Surficial Sediments of a Eutrophic Tropical Estuary (Cochin Backwaters, Southwest Coast of India)

Concentrations and distributions of trace metals (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) in surficial sediments of the Cochin backwaters were studied during both monsoon and pre-monsoon periods. Spatial variations were in accordance with textural charaterstics and organic matter content. A principal component analysis distinguished three zones with different metal accumulation capacity: (i) highest levels in north estuary, (ii) moderate levels in central zone, and (iii) lowest levels in southern part. Trace metal enrichments are mainly due to anthropogenic contribution of industrial, domestic, and agricultural effluents, whose effect is enhanced by settling of metals due to organic flocculation and inorganic precipitation associated with salinity changes. Enrichments factors using Fe as a normalizer showed that metal contamination was the product of anthropogenic activities. An assessment of degree of pollution-categorized sediments as moderately polluted with Cu and Pb, moderately-to-heavily polluted with Zn, and heavily-to-extremely polluted with Cd. Concentrations at many sites largely exceed NOAA ERL (e.g., Cu, Cr, and Pb) or ERM (e.g., Cd, Ni, and Zn). This means that adverse effects for benthic organisms are possible or even highly probable

Constraints on the χ_(c1) versus χ_(c2) polarizations in proton-proton collisions at √s = 8 TeV

The polarizations of promptly produced χ_(c1) and χ_(c2) mesons are studied using data collected by the CMS experiment at the LHC, in proton-proton collisions at √s=8  TeV. The χ_c states are reconstructed via their radiative decays χ_c → J/ψγ, with the photons being measured through conversions to e⁺e⁻, which allows the two states to be well resolved. The polarizations are measured in the helicity frame, through the analysis of the χ_(c2) to χ_(c1) yield ratio as a function of the polar or azimuthal angle of the positive muon emitted in the J/ψ → μ⁺μ⁻ decay, in three bins of J/ψ transverse momentum. While no differences are seen between the two states in terms of azimuthal decay angle distributions, they are observed to have significantly different polar anisotropies. The measurement favors a scenario where at least one of the two states is strongly polarized along the helicity quantization axis, in agreement with nonrelativistic quantum chromodynamics predictions. This is the first measurement of significantly polarized quarkonia produced at high transverse momentum