Surface tension and vapor-liquid phase coexistence of confined square-well fluid

Phase equilibria of a square-well fluid in planar slit pores with varying slit width are investigated by applying the grand-canonical transition-matrix Monte Carlo (GC-TMMC) with the histogram-reweighting method. The wall-fluid interaction strength was varied from repulsive to attractive such that it is greater than the fluid-fluid interaction strength. The nature of the phase coexistence envelope is in agreement with that given in literature. The surface tension of the vapor-liquid interface is calculated via molecular dynamics simulations. GC-TMMC with finite size scaling is also used to calculate the surface tension. The results from molecular dynamics and GC-TMMC methods are in very good mutual agreement. The vapor-liquid surface tension, under confinement, was found to be lower than the bulk surface tension. However, with the increase of the slit width the surface tension increases. For the case of a square-well fluid in an attractive planar slit pore, the vapor-liquid surface tension exhibits a maximum with respect to wall-fluid interaction energy. We also report estimates of critical properties of confined fluids via the rectilinear diameter approach.open312

Thin-thick surface phase coexistence and boundary tension of the square-well fluid on a weak attractive surface

Prewetting transition is studied for the square-well fluid of attractive-well diameter ??ff ff =1.5 in the presence of a homogeneous surface modeled by the square-well potential of attractive well from 0.8 ff to 1.8 ff. We investigate surface phase coexistence of thin-thick film transition using grand-canonical transition matrix Monte Carlo (GC-TMMC) and histogram reweighting techniques. Molecular dynamics (MD) and GC-TMMC are utilized to predict the properties of the fluid for various surface fluid affinities. Occurrences of prewetting transition with the variation of surface affinity are observed for a domain of reduced temperature from T* =0.62 to 0.75. We have used MD and GC-TMMC+finite size scaling (FSS) simulations to calculate the boundary tension as a function of temperature as well as surface affinity. Boundary tensions via MD and GC-TMMC+FSS methods are in good agreement. The boundary tension increases with the decrease of wall-fluid affinity. Prewetting critical properties are calculated using rectilinear diameter approach and scaling analysis. We found that critical temperature and density increase with the decrease of wall-fluid affinity.open101

Elastic pp Scattering at LHC Energies

We consider the first LHC data for elastic pp scattering in the framework of Regge theory with multiple Pomeron exchanges. The simplest eikonal approach allows one to describe differential elastic cross sections at LHC, as well as pp and $\bar{p}p$ scattering at lower collider energies, on a reasonable level.Comment: 11 pages, 5 figures, and 1 tabl

Frame-like Geometry of Double Field Theory

We relate two formulations of the recently constructed double field theory to a frame-like geometrical formalism developed by Siegel. A self-contained presentation of this formalism is given, including a discussion of the constraints and its solutions, and of the resulting Riemann tensor, Ricci tensor and curvature scalar. This curvature scalar can be used to define an action, and it is shown that this action is equivalent to that of double field theory.Comment: 35 pages, v2: minor corrections, to appear in J. Phys.

Driven Diffusive Systems: How Steady States Depend on Dynamics

In contrast to equilibrium systems, non-equilibrium steady states depend explicitly on the underlying dynamics. Using Monte Carlo simulations with Metropolis, Glauber and heat bath rates, we illustrate this expectation for an Ising lattice gas, driven far from equilibrium by an `electric' field. While heat bath and Glauber rates generate essentially identical data for structure factors and two-point correlations, Metropolis rates give noticeably weaker correlations, as if the `effective' temperature were higher in the latter case. We also measure energy histograms and define a simple ratio which is exactly known and closely related to the Boltzmann factor for the equilibrium case. For the driven system, the ratio probes a thermodynamic derivative which is found to be dependent on dynamics

The technology transfer of non-ferrous alloys casting during the middle age

The article reports on the findings from the metallographic analysis of 13th c. archaeological objects from Chełm (eastern Poland). The group submitted for analysis includes jeweller’s dies used in the production of women’s ceremonial ornaments, crucibles and bronze ornaments. The Mongol invasion of 13th c. had caused craftsmen from central areas of East Europe to flee and seek shelter in the western parts of Rus. It may be safe to interpret the finds from Chełm as the remains of a jeweller’s workshop, the site of casting and working copper alloys and silver. The analysis of the technology used in casting copper alloys and silver in the jeweller’s workshop were made using optical microscopy, X-ray spectroscopy and X-ray radiography

Vapor-liquid critical and interfacial properties of square-well fluids in slit pores

Vapor-liquid phase equilibria of square-well (SW) fluids of variable interaction range: ??=1.25, 1.75, 2.0, and 3.0 in hard slit pores are studied by means of grand-canonical transition-matrix Monte Carlo (GC-TMMC) simulation. Critical density under confinement shows an oscillatory behavior as slit width, H, reduced from 12 to 1. Two linear regimes are found for the shift in the critical temperature with the inverse in the slit width. The first regime is seen for H>2.0 with linear increase in the slope of shift in the critical temperature against inverse slit width with increasing interaction range. Subsequent decrease in H has little consequence on the critical temperature and it remains almost constant. Vapor-liquid surface tensions of SW fluids of variable well extent in a planar slit pore of variable slit width are also reported. GC-TMMC results are compared with that from slab based canonical Monte Carlo and molecular dynamics techniques and found to be in good agreement. Although, vapor-liquid surface tension under confinement is found to be lower than the bulk surface tension, the behavior of surface tension as a function of temperature is invariant with the variable pore size. Interfacial width, , calculated using a hyperbolic function increases with decreasing slit width at a given temperature, which is contrary to what is being observed recently for cylindrical pores. Inverse scaled interfacial width (/H), however, linearly increases with increase in the scaled temperature (Tc,bulk -T) / Tc,bulk.open121