Ab initio studies of structural instabilities in magnesium silicate perovskite

Density-functional simulations are used to calculate structural properties and high-symmetry phonons of the hypothetical cubic phase, the stable orthorhombic phase and an intermediate tetragonal phase of magnesium silicate perovskite. We show that the structure of the stable phase is well described by freezing in a small number of unstable phonons into the cubic phase. We use the frequencies of these unstable modes to estimate transition temperatures for cubic--tetragonal and tetragonal--orthorhombic phase transitions. These are investigated further to find that the coupling with the strain suggests that phonons give a better representation than rigid unit modes. The phonons of an intermediate tetragonal phase were found to be stable except for two rotational modes. The eigenvectors of the most unstable mode of each of the cubic and tetragonal phases account for all the positional parameters of the orthorhombic phase. The phase boundary for the orthorhombic--tetragonal transition intersects possible mantle geotherms, suggesting that the tetragonal phase may be present in the lower mantle.Comment: 16 pages, REVTEX, 7 postscript figures (Fig 1 very large, contact Authors if required); submitted to Physics and Chemistry of Mineral

Retracts of vertex sets of trees and the almost stability theorem

Let G be a group, let T be an (oriented) G-tree with finite edge stabilizers, and let VT denote the vertex set of T. We show that, for each G-retract V' of the G-set VT, there exists a G-tree whose edge stabilizers are finite and whose vertex set is V'. This fact leads to various new consequences of the almost stability theorem. We also give an example of a group G, a G-tree T and a G-retract V' of VT such that no G-tree has vertex set V'.Comment: 15 pages, 0 figures. Formerly titled "Some refinements of the almost stability theorem". Version

Managing professional identity within a changing market environment: New Zealand optometrists’ responses to the growth of corporate optometry

This research investigated the effects of changes in the market environment for optometry services and products on the professional identity of New Zealand optometrists. It explored three issues. First, ways participants’ location within either the independent or corporate sectors shaped their professional identities. Second, ways potential ethical conflicts between participants’ healthcare and retailing identities were resolved. Last, participants’ opinions concerning the future of their profession. Twelve male and fourteen female optometrists were interviewed. Nineteen participants worked within independent optometry practices. Seven worked within practices that were part of international optometry chains. Six participants were recent graduates, the rest experienced optometrists. All participants identified primarily as healthcare professionals. All recognised that practising optometry within a commercial market created the possibility of ethical conflicts between healthcare and business imperatives. There were differences in the ways participants managed this boundary, with participants working within corporate optometry seeming more comfortable with the business aspects of their profession. All participants thought the profession was changing and several suggested that the future of independent optometry was limited. The article concludes that recent changes within the market environment of optometry have heightened tensions between optometrists’ medical and entrepreneurial identities and contributed to changing work patterns within the profession.fals

Beta measurements

The second year's results of the BETA project research are presented. The program is divided into two areas, aerosol modification and climatology in the trade wind region and the climatology of BETA (CO2) on remote mountain top locations. Limited data is available on the aerosol climatology of the marine free troposphere (MFT) in the trade wind region. In order to study the effects of cumulus convection on the MFT values of BETA, a cloud model was developed to simulate the evolution of a typical Pacific trade wind cumulus cloud. The stages involved in this development are outlined. The assembly of the major optical components of the lidar was made. Tests were run of the spectral bandwidth of the Synrad laser when a portion of the beam is mixed with a component which has traveled 450 meters corresponding to a delay of 1.5 microsecs. The bandwidth of the beat signal was measured to be 3 KHz. The data processing system based on a parallel processing filter bank analyzer using true time squaring detectors at each filter was completed

Mechanical properties of several nickel alloys in hydrogen at elevated temperatures

Tests were performed to determine low cycle fatigue and crack growth rate properties of one iron-base and two forms of one cast nickel-base alloy. The alloys were tested in various forms and/or heat-treat conditions that are proposed for use in a high-pressure hydrogen or a hydrogen-water vapor environment. Some general conclusions can be made comparing the results of tests in a hydrogen environment with those in a hydrogen-water vapor environment. The hydrogen-water vapor environment caused a 50 percent average reduction in fatigue life, indicating extreme degradation when compared with tests conducted in air, for Incoloy 903 at 1033 K (1400 F). Crack growth rates increased significantly for all materials with increasing test temperature. A very significant increase (three orders of magnitude) in crack growth rate occurred for Incoloy 903 tested in the hydrogen-water vapor environment when compared with testing done in hydrogen along at 922 K (1200 F)

Plate tectonics: When ancient continents collide

The geological record preserves scant evidence for early plate tectonics. Analysis of eclogites — metamorphic rocks formed in subduction zones — in the Trans-Hudson mountain belt suggests modern-style subduction may have operated 1,800 million years ago

A proposed DAQ system for a calorimeter at the International Linear Collider

This note describes R&D to be carried out on the data acquisition system for a calorimeter at the future International Linear Collider. A generic calorimeter and data acquisition system is described. Within this framework modified designs and potential bottlenecks within the current system are described. Solutions leading up to a technical design report will to be carried out within CALICE-UK groups.Comment: 13 pages, 4 figure