Photocatalytic reactions of a nickel(II) annulene complex incorporated in polymeric structures

The photochemical reactions of the Ni(II) annulene complex, [NiII([5,7,12,14]-tetra methyl dibenzo[2,3- b:2,3-b,i][1,4,8,11]tetraaza[14]annulenate)], grafted into a poly(isobutylene-alt-maleate) backbone were investigated in aqueous media. The grafted Ni(II) complex becomes soluble in aqueous and organic solvents where the strands form aggregates with medium-dependent shapes. Irradiation of the polymer at 532 or 351 nm produce charge-separated macrocyclic pendants, CS, with a lifetime s 30 ns. CS reacts with electron donors and acceptors before it decays with a lifetime s 1 ms. In parallel to the decay of CS, an excited state-excited state annihilation process gives rise to luminescence whose spectrum spans wavelengths shorter than the wavelength of the irradiation, lex > 500 nm. Theoretical calculations were carried out with the aim of understanding the morphology and structures of strand aggregates, to confirm the nature of reaction products and to account for the spectroscopic and photochemical properties of the Ni(II) pendants. The endothermic reduction of CO2 to CO by S(IV) species was used as a test of the Ni(II) complex´s ability to photocatalyze the reaction. In the photoprocess, the Ni(II) complex fulfills the double role of antenna and catalyst.Fil: Estiu, G.. University Of Notre Dame-indiana; Estados UnidosFil: Ferraudi, G.. University Of Notre Dame-indiana; Estados UnidosFil: Lappin, A. G.. University Of Notre Dame-indiana; Estados UnidosFil: Ruiz, Gustavo Teodosio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Vericat, Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Costamagna, J.. Universidad de Santiago de Chile; ChileFil: Villagrán, M.. Universidad de Santiago de Chile; Chil

Evaluation of the microclimate in a traditional Colombian greenhouse used for cut flower production

This is the final version. Available from MDPI via the DOI in this record. Cut flower production in the Bogotá savanna is one of Colombia’s main export products. Flower production is mainly carried out in greenhouses, as this type of production system has substantial advantages over crops grown in open fields. Protected agriculture provides timely climate management that improves crop yields. The objective of this work was to build and validate a 3D CFD numerical model to understand the spatial distribution of temperatures because of the air flow dynamics inside a typical greenhouse in the Bogotá savanna. Root mean square error (RMSE) and mean absolute percentage error (MAPE) were the statistical indicators used between experimental and simulated wind speed and temperature data. The simulations considered twelve evaluation scenarios that were established based on the climatic conditions characteristic of the study region. The results indicate that under regional conditions of temperature and wind for this type of passive greenhouse, there is a deficient ventilation rate. This rate does not exceed 35 exchanges h−1 compared to the recommended rates for crops, which is between 45 and 60 air exchanges h−1. This renewal rate contributes to the heterogeneity of the microclimatic dynamics of the greenhouse, presenting hot spots with temperature values above 32 °C in all examined scenarios. For the lower air speed scenarios (<1 ms−1), these areas of high temperature can reach up to 50% of the cultivated area. Therefore, it is suggested that future studies should seek technical solutions to optimize the microclimatic conditions of the greenhouse design used in the Colombian floriculture sector.Sistema General de Regalías and the Gobernacion de Cundinamarc

Influence of the Height in a Colombian Multi-Tunnel Greenhouse on Natural Ventilation and Thermal Behavior: Modeling Approach

This is the final version. Available on open access from MDPI via the DOI in this recordfirst_pagesettings Open AccessArticle Influence of the Height in a Colombian Multi-Tunnel Greenhouse on Natural Ventilation and Thermal Behavior: Modeling Approach by Edwin Villagrán 1,Jorge Flores-Velazquez 2,*ORCID,Mohammad Akrami 3,*ORCID andCarlos Bojacá 1ORCID 1 Department of Biological and Environmental Sciences, Faculty of Natural Sciences and Engineering, Jorge Tadeo Lozano University, Bogotá 111321, Colombia 2 Coordination of Hydrosciences, Postgraduate Collage, Carr Mex Tex km 36.5, Montecillo Edo de Mexico 62550, Mexico 3 Department of Engineering, University of Exeter, Exeter EX4 4QF, UK * Authors to whom correspondence should be addressed. Academic Editors: Muhammad Sultan, Yuguang Zhou, Walter Den and Uzair Sajjad Sustainability 2021, 13(24), 13631; https://doi.org/10.3390/su132413631 Received: 25 October 2021 / Revised: 25 November 2021 / Accepted: 6 December 2021 / Published: 9 December 2021 (This article belongs to the Special Issue Sustainable Agricultural Engineering Technologies and Applications) Download PDF Browse Figures Citation Export Abstract The dimensions of a passive greenhouse are one of the decisions made by producers or builders based on characteristics of the available land and the economic cost of building the structure per unit of covered area. In few cases, the design criteria are reviewed and the dimensions are established based on the type of crop and local climate conditions. One of the dimensions that is generally exposed to greater manipulation is the height above the gutter and the general height of the structure, since a greenhouse with a lower height has a lower economic cost. This has led some countries in the tropical region to build greenhouses that, due to their architectural characteristics, have inadequate microclimatic conditions for agricultural production. The objective of this study was to analyze the effect on air flows and thermal distribution generated by the increase of the height over gutter of a Colombian multi-tunnel greenhouse using a successfully two-dimensional computational fluid dynamics (CFD) model. The simulated numerical results showed that increasing the height of the greenhouse allows obtaining temperature reductions from 0.1 to 11.7 °C depending on the ventilation configuration used and the external wind speed. Likewise, it was identified that the combined side and roof ventilation configuration (RS) allows obtaining higher renovation indexes (RI) in values between 144 and 449% with respect to the side ventilation (S) and roof ventilation (R) configurations. Finally, the numerical results were successfully fitted within the surface regression models responses.Servicio Nacional de Aprendizaje (SENA)Asociación Colombiana de Exportadores de Flores (Asocolflores)Centro de Innovación de la Floricultura Colombiana (Ceniflores

Microclimatic Evaluation of Five Types of Colombian Greenhouses Using Geostatistical Techniques

This is the final version. Available on open access from MDPI via the DOI in this recordn Colombia, the second-largest exporter of cut flowers worldwide and one of the South American countries with the largest area of crops under cover, passive or naturally ventilated greenhouses predominate. Locally, there are several types of greenhouses that differ in architecture, size, height, shape of roof and ventilation surfaces, of which many characteristics of the microclimate generated in their interior environment are unknown. This generates productive limitations that in some way may be limiting the yield, quality and health of the final products harvested; in addition, Colombian producers do not have the ability to monitor the microclimate of their farms, much less to correlate microclimate data with data on crop production and yield. Therefore, there is a need for the Colombian grower to know the most relevant microclimate characteristics generated in the main greenhouses used locally. The objective of this work was to carry out a microclimatic characterization of the five most used types of greenhouses in Colombia. The main results allowed determining that in these structures, there are conditions of high humidity and low vapor pressure for several hours of the day, which affects the physiological processes of growth and development of the plants. It was also identified that for each type of greenhouse, depending on the level of radiation, there is a significant microclimatic heterogeneity that may be the cause of the heterogeneity in plant growth, which is a common characteristic observed by the technical cultivation personnel. Therefore, it can be concluded that it is urgent to propose microclimatic optimization strategies to help ensure the sustainability of the most important production systems in the country.Servicio Nacional de Aprendizaje (SENA)Asociación Colombiana de Exportadores de Flores (Asocolflores)Centro de Innovación de la Floricultura Colombiana (Ceniflores

The two-dimensional disordered Mott metal-insulator transition

We studied several aspects of the Mott metal-insulator transition in the disordered case. The model on which we based our analysis is the disordered Hubbard model, which is the simplest model capable of capturing the Mott metal-insulator transition. We investigated this model through the Statistical Dynamical Mean-Field Theory (statDMFT). This theory is a natural extension of the Dynamical Mean-Field Theory (DMFT), which has been used with relative success in the last several years with the purpose of describing the Mott transition in the clean case. As is the case for the latter theory, the statDMFT incorporates the electronic correlation effects only in their local manifestations. Disorder, on the other hand, is treated in such a way as to incorporate Anderson localization effects. With this technique, we analyzed the disordered two-dimensional Mott transition, using Quantum Monte Carlo to solve the associated single-impurity problems. We found spinodal lines at which the metal and insulator cease to be meta-stable. We also studied spatial fluctuations of local quantities, such as the self-energy and the local Green's function, and showed the appearance of metallic regions within the insulator and vice-versa. We carried out an analysis of finite-size effects and showed that, in agreement with the theorems of Imry and Ma, the first-order transition is smeared in the thermodynamic limit. We analyzed transport properties by means of a mapping to a random classical resistor network and calculated both the average current and its distribution across the metal-insulator transition

Prioritized Sweeping Neural DynaQ with Multiple Predecessors, and Hippocampal Replays

During sleep and awake rest, the hippocampus replays sequences of place cells that have been activated during prior experiences. These have been interpreted as a memory consolidation process, but recent results suggest a possible interpretation in terms of reinforcement learning. The Dyna reinforcement learning algorithms use off-line replays to improve learning. Under limited replay budget, a prioritized sweeping approach, which requires a model of the transitions to the predecessors, can be used to improve performance. We investigate whether such algorithms can explain the experimentally observed replays. We propose a neural network version of prioritized sweeping Q-learning, for which we developed a growing multiple expert algorithm, able to cope with multiple predecessors. The resulting architecture is able to improve the learning of simulated agents confronted to a navigation task. We predict that, in animals, learning the world model should occur during rest periods, and that the corresponding replays should be shuffled.Comment: Living Machines 2018 (Paris, France

P28 85. Análisis de la supervivencia a corto y medio plazo de la cirugía de aorta ascendente

ObjetivosEvaluar la mortalidad hospitalaria y la supervivencia a medio plazo de los pacientes sometidos a una cirugía de aorta ascendente y determinar cuáles son sus factores de riesgo.Material y métodosSe analizó de forma retrospectiva toda la población de pacientes sometidos a un procedimiento quirúrgico de aorta ascendente (sustitución con o sin cirugía valvular o de raíz asociada) entre enero de 2003 y diciembre de 2008. Se evaluó la mortalidad hospitalaria y la supervivencia absoluta en el seguimiento, y mediante análisis uni y multivariante se determinaron las correspondientes variables predictoras.ResultadosTrescientos sesenta y cinco pacientes fueron sometidos de forma consecutiva a algún procedimiento quirúrgico de la aorta ascendente. Edad media: 63,1 años (desviación estándar [DE] 13); n = 99 (27,1%) fueron mujeres; n = 58 (15,9%) habían sido sometidos a una cirugía previa. En 32 pacientes se sustituyó total o parcialmente el arco aórtico. EuroSCORE mediano de 11,72% (interquartile range [IQR]: 6,78-20,43). La mortalidad hospitalaria fue 7,7% (n = 28). Los predictores de mortalidad en análisis multivariante fueron: cirugía cardíaca previa (odds ratio [OR]: 3,18; p = 0,045), tabaquismo activo (OR: 5,7; p = 0,021), insuficiencia renal (OR: 3,03; p = 0,043), estado crítico preoperatorio (OR: 5,63; p = 0,005), edad (OR: 1,06; p = 0,018) y cirugía coronaria asociada (OR: 3,17; p = 0,35). La supervivencia a 1, 3 y 5 años fue 96, 94 y 92%. Sólo edad (hazard ratio [HR]: 1,08; p = 0,022) e hipertensión pulmonar grave (HR: 3,5; p = 0,026) fueron predictores independientes de mortalidad en el seguimiento.ConclusionesEn nuestra experiencia, la sustitución de la aorta ascendente demuestra una baja mortalidad hospitalaria y una adecuada supervivencia a medio plazo

Analycity and smoothing effect for the coupled system of equations of Korteweg - de Vries type with a single point singularity

We study that a solution of the initial value problem associated for the coupled system of equations of Korteweg - de Vries type which appears as a model to describe the strong interaction of weakly nonlinear long waves, has analyticity in time and smoothing effect up to real analyticity if the initial data only has a single point singularity at $x=0.