Evaluation of Selected Chemical Processes for Production of Low-cost Silicon, Phase 3

Refinements of the design of the 50 MT/year Experimental Process System Development Unit were made and competitive bids were received from mechanical, electrical, and structural contractors. Bids on most of the equipment were received and cataloged. Emergency procedures were defined to counter a variety of contingencies disclosed in operations and safety reviews. Experimental work with an electrolytic cell for zinc chloride disclosed no significant increase in power efficiency by steps taken to increase electrolyte circulation. On the basis of materials compatibility and permeability tests, 310 stainless steel was chosen for the shell of the fluidized-bed reactor and SiC-coated graphite for the liner

Evaluation of selected chemical processes for production of low-cost silicon, phases 1 and 2

A miniplant, consisting of a 5 cm-diameter fluidized-bed reactor and associated equipment was used to study the deposition parameters, temperature, reactant composition, seed particle size, bed depth, reactant throughput, and methods of reactant introduction. It was confirmed that the permissible range of fluidized-bed temperature was limited at the lower end by zinc condensation (918 C) and at higher temperatures by rapidly decreasing conversion efficiency. Use of a graded bed temperature was shown to increase the conversion efficiency over that obtained in an isothermal bed. Other aspects of the process such as the condensation and fused-salt electrolysis of the ZnCl2 by-product for recycle of zinc and chlorine were studied to provide information required for design of a 50 MT/year experimental facility. In view of the favorable technical and economic indications obtained, it was recommended that construction and operation of the 50 MT/year experimental facility be implemented

Evaluation of Selected Chemical Processes for Production of Low-cost Silicon, Phase 3

The construction of the 50 MT Si/year experimental process system development unit was deferred until FY 1980, and the fluidized bed, zinc vaporizer, by-product condenser, and electrolytic cell were combined with auxiliary units, capable of supporting 8-hour batchwise operation, to form the process development unit (PDU), which is scheduled to be in operation by October 1, 1979. The design of the PDU and objectives of its operation are discussed. Experimental program support activities described relate to: (1) a wetted-wall condensor; (2) fluidized-bed modeling; (3) zinc chloride electrolysis; and (4) zinc vaporizer

Evaluation of selected chemical processes for production of low-cost silicon, phase 3

A Process Development Unit (PDU), which consisted of the four major units of the process, was designed, installed, and experimentally operated. The PDU was sized to 50MT/Yr. The deposition took place in a fluidized bed reactor. As a consequences of the experiments, improvements in the design an operation of these units were undertaken and their experimental limitations were partially established. A parallel program of experimental work demonstrated that Zinc can be vaporized for introduction into the fluidized bed reactor, by direct induction-coupled r.f. energy. Residual zinc in the product can be removed by heat treatment below the melting point of silicon. Current efficiencies of 94 percent and above, and power efficiencies around 40 percent are achievable in the laboratory-scale electrolysis of ZnCl2

Evaluation of selected chemical processes for production of low-cost silicon, phase 2

Potential designs for an integrated fluidized-bed reactor/zinc vaporizer/SiCl4 preheater unit are being considered and heat-transfer calculations have been initiated on versions of the zinc vaporizer section. Estimates of the cost of the silicon prepared in the experimental facility have been made for projected capacities of 25, 50, 75, and 100 metric ton of silicon. A 35 percent saving is obtained in going from 25 metric ton/year to the 50 metric ton/year level. This analysis, coupled with the recognition that use of two reactors in the 50 metric ton/year version allows for continued operation (at reduced capacity) with one reactor shut down, has resulted in a recommendation for adoption of an experimental facility capacity of 50 metric ton/year or greater. At this stage, the change to a larger size facility would not increase the design costs appreciably. In the experimental support program, the effects of seed bed particle size and depth were studied, and operation of the miniplant with a new zinc vaporizer was initiated, revealing the need for modification of the latter

Evaluation of selected chemical processes for production of low-cost silicon

Plant construction costs and manufacturing costs were estimated for the production of solar-grade silicon by the reduction of silicon tetrachloride in a fluidized bed of seed particles, and several modifications of the iodide process using either thermal decomposition on heated filaments (rods) or hydrogen reduction in a fluidized bed of seed particles. Energy consumption data for the zinc reduction process and each of the iodide process options are given and all appear to be acceptable from the standpoint of energy pay back. Information is presented on the experimental zinc reduction of SiCl4 and electrolytic recovery of zinc from ZnCl2. All of the experimental work performed thus far has supported the initial assumption as to technical feasibility of producing semiconductor silicon by the zinc reduction or iodide processes proposed. The results of a more thorough thermodynamic evaluation of the iodination of silicon oxide/carbon mixtures are presented which explain apparent inconsistencies in an earlier cursory examination of the system

Three-Dimensional Simulations of Solar and Stellar Dynamos: The Influence of a Tachocline

We review recent advances in modeling global-scale convection and dynamo processes with the Anelastic Spherical Harmonic (ASH) code. In particular, we have recently achieved the first global-scale solar convection simulations that exhibit turbulent pumping of magnetic flux into a simulated tachocline and the subsequent organization and amplification of toroidal field structures by rotational shear. The presence of a tachocline not only promotes the generation of mean toroidal flux, but it also enhances and stabilizes the mean poloidal field throughout the convection zone, promoting dipolar structure with less frequent polarity reversals. The magnetic field generated by a convective dynamo with a tachocline and overshoot region is also more helical overall, with a sign reversal in the northern and southern hemispheres. Toroidal tachocline fields exhibit little indication of magnetic buoyancy instabilities but may be undergoing magneto-shear instabilities.Comment: 14 pages, 5 color figures, to appear in Proc. GONG 2008/SOHO XXI Meeting on Solar-Stellar Dynamos as Revealed by Helio and Asteroseismology, held August 15-18, 2008, Boulder, CO, Astronomical Soc. Pac. Conf. Series, volume TB

X-ray photoemission characterization of La_{0.67}(Ca_{x}Sr_{1-x})_{0.33}MnO_{3} films

The Curie temperature and x-ray photoemission spectra of thin films of La_{0.67}(Ca_{x}Sr_{1-x})_{0.33}MnO_{3} (LCSMO) have been studied as a function of the Ca/Sr ratio. The films were grown by off-axis cosputtering from individual targets of La_{0.67}Ca_{0.33}MnO_{3} (LCMO) and La_{0.67}Sr_{0.33}MnO_{3} (LSMO) onto (100) oriented NdGaO_{3} substrates. The films grow with a (100) orientation, with no other orientations observed by x-ray diffraction. For the alloy mixtures, the Curie temperature, T_C, varies slowly as the Ca/Sr is decreased, remaining $\approx$ 300 K, while for the LCMO and LSMO films T_C is 260 and 330 K, respectively. The Mn-O valence structure is composed of two dominant peaks, whose positions undergo a change as the Ca fraction is decreased. The core lines behave as linear combinations of lines from pure LCMO and LSMO.Comment: 3 pages, 5 eps figures. To be published in Journal of Applied Physics (Proceedings of MMM'98

The promise of layer-specific neuroimaging for testing predictive coding theories of psychosis

Predictive coding potentially provides an explanatory model for understanding the neurocognitive mechanisms of psychosis. It proposes that cognitive processes, such as perception and inference, are implemented by a hierarchical system, with the influence of each level being a function of the estimated precision of beliefs at that level. However, predictive coding models of psychosis are insufficiently constrained—any phenomenon can be explained in multiple ways by postulating different changes to precision at different levels of processing. One reason for the lack of constraint in these models is that the core processes are thought to be implemented by the function of specific cortical layers, and the technology to measure layer specific neural activity in humans has until recently been lacking. As a result, our ability to constrain the models with empirical data has been limited. In this review we provide a brief overview of predictive processing models of psychosis and then describe the potential for newly developed, layer specific neuroimaging techniques to test and thus constrain these models. We conclude by discussing the most promising avenues for this research as well as the technical and conceptual challenges which may limit its application