Design of LTCC-based Ceramic Structure for Chemical Microreactor

The design of ceramic chemical microreactor for the production of hydrogen needed in portable polymer-electrolyte membrane (PEM) fuel cells is presented. The microreactor was developed for the steam reforming of liquid fuels with water into hydrogen. The complex three-dimensional ceramic structure of the microreactor includes evaporator(s), mixer(s), reformer and combustor. Low-temperature co-fired ceramic (LTCC) technology was used to fabricate the ceramic structures with buried cavities and channels, and thick-film technology was used to make electrical heaters, temperature sensors and pressure sensors. The final 3D ceramic structure consists of 45 LTCC tapes. The dimensions of the structure are 75 × 41 × 9 mm3 and the weight is about 73 g

Formation of 1,2,3-Thiadiazole Derivatives from Isothiocyanates and Aliphatic Diazo Compounds

Among different methods for the preparation of 1,2,3-thiodiazole derivatives1• 2 a relatively simple one consists in the reaction of a n is.othi:ocyalilate and a diazoalkane. However, this reaction, first reported by Pechmann and Nold3 and later checked by Sheehan an Izzo was successfully performed only with phenyl isoithi·ocya\u27ll!ate and diaz·omethane a:s representatives o.f both classes of reactants

Formation of 1,2,3-Thiadiazole Derivatives from Isothiocyanates and Aliphatic Diazo Compounds

Among different methods for the preparation of 1,2,3-thiodiazole derivatives1• 2 a relatively simple one consists in the reaction of a n is.othi:ocyalilate and a diazoalkane. However, this reaction, first reported by Pechmann and Nold3 and later checked by Sheehan an Izzo was successfully performed only with phenyl isoithi·ocya\u27ll!ate and diaz·omethane a:s representatives o.f both classes of reactants

Comparison Tools for Assessing the Microgravity Environment of Orbital Missions, Carriers and Conditions

The Principal Component Spectral Analysis and the Quasi-steady Three-dimensional Histogram techniques provide the means to describe, on a single plot, the microgravity acceleration environment of a long period of time, such as a day, week, or month. This allows a straight forward comparison of the microgravity environment between microgravity increments on the International Space Station, locations within the International Space Station, and/or different operating conditions. Traditional data display methods (e.g. acceleration versus time), while adequate for shorter time periods, would utilize more plots for an extensive period of time, often making interpretation more difficult. These new techniques provide a single page representation of a large set of microgravity acceleration data. These techniques, in conjunction with other techniques, may be employed to derive useful information from acceleration data to characterize or compare the microgravity environment

Comparison Tools for Assessing the Microgravity Environment of Space Missions, Carriers and Conditions

The microgravity environment of the NASA Shuttles and Russia's Mir space station have been measured by specially designed accelerometer systems. The need for comparisons between different missions, vehicles, conditions, etc. has been addressed by the two new processes described in this paper. The Principal Component Spectral Analysis (PCSA) and Quasi-steady Three-dimensional Histogram QTH techniques provide the means to describe the microgravity acceleration environment of a long time span of data on a single plot. As described in this paper, the PCSA and QTH techniques allow both the range and the median of the microgravity environment to be represented graphically on a single page. A variety of operating conditions may be made evident by using PCSA or QTH plots. The PCSA plot can help to distinguish between equipment operating full time or part time, as well as show the variability of the magnitude and/or frequency of an acceleration source. A QTH plot summarizes the magnitude and orientation of the low-frequency acceleration vector. This type of plot can show the microgravity effects of attitude, altitude, venting, etc

Anisotropic random resistor networks: a model for piezoresistive response of thick-film resistors

A number of evidences suggests that thick-film resistors are close to a metal-insulator transition and that tunneling processes between metallic grains are the main source of resistance. We consider as a minimal model for description of transport properties in thick-film resistors a percolative resistor network, with conducting elements governed by tunneling. For both oriented and randomly oriented networks, we show that the piezoresistive response to an applied strain is model dependent when the system is far away from the percolation thresold, while in the critical region it acquires universal properties. In particular close to the metal-insulator transition, the piezoresistive anisotropy show a power law behavior. Within this region, there exists a simple and universal relation between the conductance and the piezoresistive anisotropy, which could be experimentally tested by common cantilever bar measurements of thick-film resistors.Comment: 7 pages, 2 eps figure

Motion of Air Bubbles in Water Subjected to Microgravity Accelerations

The International Space Station (ISS) serves as a platform for microgravity research for the foreseeable future. A microgravity environment is one in which the effects of gravity are drastically reduced which then allows physical experiments to be conducted without the over powering effects of gravity. During his 6-month stay on the ISS, astronaut Donald R. Pettit performed many informal/impromptu science experiments with available equipment. One such experiment focused on the motion of air bubbles in a rectangular container nearly filled with de-ionized water. Bubbles were introduced by shaking and then the container was secured in place for several hours while motion of the bubbles was recorded using time-lapse photography. This paper shows correlation between bubble motion and quasi-steady acceleration levels during one such experiment operation. The quasi-steady acceleration vectors were measured by the Microgravity Acceleration Measurement System (MAMS). Essentially linear motion was observed in the condition considered here. Dr. Pettit also created other conditions which produced linear and circulating motion, which are the subjects of further study. Initial observations of this bubble motion agree with calculations from many microgravity physical science experiments conducted on shuttle microgravity science missions. Many crystal-growth furnaces involve heavy metals and high temperatures in which undesired acceleration-driven convection during solidification can adversely affect the crystal. Presented in this paper will be results showing correlation between bubble motion and the quasi-steady acceleration vector