Congener specific analysis of polychlorinated terphenyls

In order to identify and to quantify polychlorinated terphenyls (PCT) in environmental matrices, the chro- matographic behavior of coplanar and non-coplanar congeners was evaluated. A mixture of 16 single PCT congeners was used for method development. Four of these compounds were synthesized for the first time by SUZUKI-coupling reaction. These were p-PCT (2,200 ,6,600 -tetrachloro-, 20 ,3,300 ,4,400 ,50 ,-hexachloro-, 20 ,3,300 ,5,50 ,500 -hexachloro-) and m-PCT (2,200 ,3,300 ,5,500 -hexachloro-). They were characterized by NMR ( 1 H, 13 C) spectroscopy. By means of the new column chromatographic clean-up reported here, a good matrix removal and the separation of the coplanar PCT congeners from the non-coplanar ones was obtained. The recovery rates for all congeners were good for the PCT in different test matrices like fat, charcoal, and soil. The quality of the clean-up, the separation and the recovery rates were determined by GC/MS analysis. The method was applied for the first time to a real sample from a fire accident, where different PCT, obviously formed during the combustion process, were found. The conclusion is drawn that this method is suitable for the analysis of PCT in different environmental samples

Impingement of Water Droplets on NACA 65A004 Airfoil at 8 deg Angle of Attack

The trajectories of droplets in the air flowing past an NACA 65AO04 airfoil at an angle of attack of 8 deg were determined.. The amount of water in droplet form impinging on the airfoil, the area of droplet impingement, and the rate of droplet impingement per unit area on the airfoil surface were calculated from the trajectories and presented to cover a large range of flight and atmospheric conditions. These impingement characteristics are compared briefly with those previously reported for the same airfoil at an angle of attack of 4 deg

Breaking time-reversal symmetry with a superconducting flux capacitor

We present the design of a passive, on-chip microwave circulator based on a ring of superconducting tunnel junctions. We investigate two distinct physical realisations, based on either Josephson junctions (JJ) or quantum phase slip elements (QPS), with microwave ports coupled either capacitively (JJ) or inductively (QPS) to the ring structure. A constant bias applied to the center of the ring provides the symmetry breaking (effective) magnetic field, and no microwave or rf bias is required. We find that this design offers high isolation even when taking into account fabrication imperfections and environmentally induced bias perturbations and find a bandwidth in excess of 500 MHz for realistic device parameters.Comment: 10 pages, 11 figures, including supplementary material - published as "Passive on-chip, superconducting circulator using rings of tunnel junctions

The physics and kinematics of the evolved, interacting planetary nebula PN G342.0-01.7

Here we aim to study the physical and kinematical characteristics of the unstudied old planetary nebula (PN) PN G342.0-01.7, which shows evidence of interaction with its surrounding interstellar medium. We used Integral Field Spectra from the Wide Field Spectrograph on the ANU 2.3 m telescope to provide spectroscopy across the whole object covering the spectral range 3400-7000 {\AA}. We formed narrow-band images to investigate the excitation structure. The spectral analysis shows that the object is a distant Peimbert Type I PN of low excitation, formally of excitation class of 0.5. The low electron density, high dynamical age, and low surface brightness of the object confirm that it is observed fairly late in its evolution. It shows clear evidence for dredge-up of CN-processed material characteristic of its class. In addition, the low peculiar velocity of 7 km s$^{-1}$ shows it to be a member of the young disk component of our Galaxy. We built a self-consistent photoionisation model for the PNe matching the observed spectrum, the H$\beta$ luminosity, and the diameter. On the basis of this we derive an effective temperature $\log T_{\rm eff} \sim 5.05$ and luminosity $1.85 < \log L < 2.25$. The temperature is much higher than might have been expected using the excitation class, proving that this can be misleading in classifying evolved PNe. PN G342.0-01.7 is in interaction with its surrounding interstellar medium through which the object is moving in the south-west direction. This interaction drives a slow shock into the outer PN ejecta. A shock model suggests that it only accounts for about 10\% of the total luminosity, but has an important effect on the global spectrum of the PN.Comment: 15 pages, 6 figures, A&A accepted 201

Hamiltonian approach to QCD in Coulomb gauge - a survey of recent results

I report on recent results obtained within the Hamiltonian approach to QCD in Coulomb gauge. Furthermore this approach is compared to recent lattice data, which were obtained by an alternative gauge fixing method and which show an improved agreement with the continuum results. By relating the Gribov confinement scenario to the center vortex picture of confinement it is shown that the Coulomb string tension is tied to the spatial string tension. For the quark sector a vacuum wave functional is used which explicitly contains the coupling of the quarks to the transverse gluons and which results in variational equations which are free of ultraviolet divergences. The variational approach is extended to finite temperatures by compactifying a spatial dimension. The effective potential of the Polyakov loop is evaluated from the zero-temperature variational solution. For pure Yang--Mills theory, the deconfinement phase transition is found to be second order for SU(2) and first order for SU(3), in agreement with the lattice results. The corresponding critical temperatures are found to be $275 \, \mathrm{MeV}$ and $280 \, \mathrm{MeV}$, respectively. When quarks are included, the deconfinement transition turns into a cross-over. From the dual and chiral quark condensate one finds pseudo-critical temperatures of $198 \, \mathrm{MeV}$ and $170 \, \mathrm{MeV}$, respectively, for the deconfinement and chiral transition.Comment: Talk given by H. Reinhardt at "5th Winter Workshop on Non-Perturbative Quantum Field Theory", 22-24 March 2017, Sophia-Antipolis, France. arXiv admin note: text overlap with arXiv:1609.09370, arXiv:1510.03286, arXiv:1607.0814

Open Charm Production at STAR

We present the open charm spectra at mid-rapidity from direct reconstruction of D0, D* and D+/- in d+Au collisions at sqrt(sNN)=200 GeV using the STAR detector at RHIC. The indirect electron/positron measurements via charm semileptonic decays in p+p and d+Au collisions are also reported. The total c\bar(c) cross section per nucleon-nucleon collision is extracted from both direct and indirect measurements and are consistent with each other. By combining the D0 and semileptonic measurements together, the cross section of 1.4+/-0.2+/-0.4 mb is higher than expectations from PYTHIA and other pQCD calculations. The open charm pT distribution from direct measurements covers the pT range up to ~10 GeV/c and follows a power-law distribution.Comment: 7 pages, 4 figures, proceedings for Hot Quark 04 Conference. submitted to J. Phys. G: Nucl. Phy