1,413 research outputs found
Classical dynamics on graphs
We consider the classical evolution of a particle on a graph by using a
time-continuous Frobenius-Perron operator which generalizes previous
propositions. In this way, the relaxation rates as well as the chaotic
properties can be defined for the time-continuous classical dynamics on graphs.
These properties are given as the zeros of some periodic-orbit zeta functions.
We consider in detail the case of infinite periodic graphs where the particle
undergoes a diffusion process. The infinite spatial extension is taken into
account by Fourier transforms which decompose the observables and probability
densities into sectors corresponding to different values of the wave number.
The hydrodynamic modes of diffusion are studied by an eigenvalue problem of a
Frobenius-Perron operator corresponding to a given sector. The diffusion
coefficient is obtained from the hydrodynamic modes of diffusion and has the
Green-Kubo form. Moreover, we study finite but large open graphs which converge
to the infinite periodic graph when their size goes to infinity. The lifetime
of the particle on the open graph is shown to correspond to the lifetime of a
system which undergoes a diffusion process before it escapes.Comment: 42 pages and 8 figure
A two-stage approach to relaxation in billiard systems of locally confined hard spheres
We consider the three-dimensional dynamics of systems of many interacting
hard spheres, each individually confined to a dispersive environment, and show
that the macroscopic limit of such systems is characterized by a coefficient of
heat conduction whose value reduces to a dimensional formula in the limit of
vanishingly small rate of interaction. It is argued that this limit arises from
an effective loss of memory. Similarities with the diffusion of a tagged
particle in binary mixtures are emphasized.Comment: Submitted to Chaos, special issue "Statistical Mechanics and
Billiard-Type Dynamical Systems
Chaos properties and localization in Lorentz lattice gases
The thermodynamic formalism of Ruelle, Sinai, and Bowen, in which chaotic
properties of dynamical systems are expressed in terms of a free energy-type
function - called the topological pressure - is applied to a Lorentz Lattice
Gas, as typical for diffusive systems with static disorder. In the limit of
large system sizes, the mechanism and effects of localization on large clusters
of scatterers in the calculation of the topological pressure are elucidated and
supported by strong numerical evidence. Moreover it clarifies and illustrates a
previous theoretical analysis [Appert et al. J. Stat. Phys. 87,
chao-dyn/9607019] of this localization phenomenon.Comment: 32 pages, 19 Postscript figures, submitted to PR
Transport and Helfand moments in the Lennard-Jones fluid. II. Thermal Conductivity
The thermal conductivity is calculated with the Helfand-moment method in the
Lennard-Jones fluid near the triple point. The Helfand moment of thermal
conductivity is here derived for molecular dynamics with periodic boundary
conditions. Thermal conductivity is given by a generalized Einstein relation
with this Helfand moment. We compute thermal conductivity by this new method
and compare it with our own values obtained by the standard Green-Kubo method.
The agreement is excellent.Comment: Submitted to the Journal of Chemical Physic
Kinetics and thermodynamics of first-order Markov chain copolymerization
We report a theoretical study of stochastic processes modeling the growth of
first-order Markov copolymers, as well as the reversed reaction of
depolymerization. These processes are ruled by kinetic equations describing
both the attachment and detachment of monomers. Exact solutions are obtained
for these kinetic equations in the steady regimes of multicomponent
copolymerization and depolymerization. Thermodynamic equilibrium is identified
as the state at which the growth velocity is vanishing on average and where
detailed balance is satisfied. Away from equilibrium, the analytical expression
of the thermodynamic entropy production is deduced in terms of the Shannon
disorder per monomer in the copolymer sequence. The Mayo-Lewis equation is
recovered in the fully irreversible growth regime. The theory also applies to
Bernoullian chains in the case where the attachment and detachment rates only
depend on the reacting monomer
Quantum fingerprints of classical Ruelle-Pollicot resonances
N-disk microwave billiards, which are representative of open quantum systems,
are studied experimentally. The transmission spectrum yields the quantum
resonances which are consistent with semiclassical calculations. The spectral
autocorrelation of the quantum spectrum is shown to be determined by the
classical Ruelle-Pollicot resonances, arising from the complex eigenvalues of
the Perron-Frobenius operator. This work establishes a fundamental connection
between quantum and classical correlations in open systems.Comment: 6 pages, 2 eps figures included, submitted to PR
Exactly solvable model of quantum diffusion
We study the transport property of diffusion in a finite translationally
invariant quantum subsystem described by a tight-binding Hamiltonian with a
single energy band and interacting with its environment by a coupling in terms
of correlation functions which are delta-correlated in space and time. For weak
coupling, the time evolution of the subsystem density matrix is ruled by a
quantum master equation of Lindblad type. Thanks to the invariance under
spatial translations, we can apply the Bloch theorem to the subsystem density
matrix and exactly diagonalize the time evolution superoperator to obtain the
complete spectrum of its eigenvalues, which fully describe the relaxation to
equilibrium. Above a critical coupling which is inversely proportional to the
size of the subsystem, the spectrum at given wavenumber contains an isolated
eigenvalue describing diffusion. The other eigenvalues rule the decay of the
populations and quantum coherences with decay rates which are proportional to
the intensity of the environmental noise. On the other hand, an analytical
expression is obtained for the dispersion relation of diffusion. The diffusion
coefficient is proportional to the square of the width of the energy band and
inversely proportional to the intensity of the environmental noise because
diffusion results from the perturbation of quantum tunneling by the
environmental fluctuations in this model. Diffusion disappears below the
critical coupling.Comment: Submitted to J. Stat. Phy
Rotational dynamics and friction in double-walled carbon nanotubes
We report a study of the rotational dynamics in double-walled nanotubes using
molecular dynamics simulations and a simple analytical model reproducing very
well the observations. We show that the dynamic friction is linear in the
angular velocity for a wide range of values. The molecular dynamics simulations
show that for large enough systems the relaxation time takes a constant value
depending only on the interlayer spacing and temperature. Moreover, the
friction force increases linearly with contact area, and the relaxation time
decreases with the temperature with a power law of exponent .Comment: submitted to PR
Methods of calculation of a friction coefficient: Application to the nanotubes
In this work we develop theoretical and numerical methods of calculation of a
dynamic friction coefficient. The theoretical method is based on an adiabatic
approximation which allows us to express the dynamic friction coefficient in
terms of the time integral of the autocorrelation function of the force between
both sliding objects. The motion of the objects and the autocorrelation
function can be numerically calculated by molecular-dynamics simulations. We
have successfully applied these methods to the evaluation of the dynamic
friction coefficient of the relative motion of two concentric carbon nanotubes.
The dynamic friction coefficient is shown to increase with the temperature.Comment: 4 pages, 6 figure
- …