Formation and fate of methyltin compounds in the Great Bay Estuary (New Hampshire)

Methyltin compounds (MeSn), which are not of anthropogenic origin, are common in estuaries, particularly in the marsh grass Spartina alterniflora. During the 1989 growing season, S. alterniflora leaves collected from three locations in the Great Bay Estuary were analyzed for MeSn and inorganic tin by hydride generation/atomic absorption spectrophotometry (HG-AAS). Total MeSn concentrations showed a sharp increase early in the season, reaching a maximum on May 23, then gradually decreased. Statistical calculations verified that date was a significant contributor to the observed variance, while location was not. Two years later the seasonal study was expanded to include below ground portions of the plant and the surrounding porewater. HG-AAS analyses on samples collected weekly at Chapman\u27s Landing detected monomethyltin and Sn in all plant parts, with no apparent temporal trend. Concentrations of Sn and monomethyltin were generally higher in roots than in other plant parts. Additionally, there was no increase in MeSn concentration either concurrent with or following an increase in Sn concentration, indicating that Sn and MeSn are absorbed from the surrounding sediment/porewater and poorly translocated to the remainder of the plant. Further studies examining the methylation of Sn by decaying S. alterniflora and by estuarine water were conducted to ascertain the contribution to MeSn concentrations found in the estuary. Samples of estuarine water spiked with Sn and MeSn were analyzed for Sn and MeSn periodically for four days. Overall Sn concentration decreased while total MeSn concentration increased, indicating methylation. Samples of S. alterniflora leaves in estuarine water spiked with Sn were sampled periodically for 120 h. While some conversion of MeSn species could be detected, no net methylation occurred during the time frame studied. To further elucidate formation of MeSn in the estuary, a hydride generator was coupled to a gas chromatographic mass spectrometry (GC/MS) via cryogenic trapping and thermal desorption. Both sensitivity and precision were improved by cryogenically focusing the analytes at the head of the GC column. This method enabled sensitive and selective speciation of MeSn, and also yielded positive compound identification and the opportunity to use isotopically labeled compounds to trace methylation experiments

A transportable strontium optical lattice clock

We report on a transportable optical clock, based on laser-cooled strontium atoms trapped in an optical lattice. The experimental apparatus is composed of a compact source of ultra-cold strontium atoms including a compact cooling laser set-up and a transportable ultra-stable laser for interrogating the optical clock transition. The whole setup (excluding electronics) fits within a volume of less than 2 m$^3$. The high degree of operation reliability of both systems allowed the spectroscopy of the clock transition to be performed with 10 Hz resolution. We estimate an uncertainty of the clock of $7\times10^{-15}$.Comment: 12 pages, 9 figures, to be published in Appl. Phys.

A compact and efficient strontium oven for laser-cooling experiments

Here we describe a compact and efficient strontium oven well suited for laser-cooling experiments. Novel design solutions allowed us to produce a collimated strontium atomic beam with a flux of 1.0\times10^13 s^-1 cm^-2 at the oven temperature of 450 {\deg}C, reached with an electrical power consumption of 36 W. The oven is based on a stainless-steel reservoir, filled with 6 g of metallic strontium, electrically heated in a vacuum environment by a tantalum wire threaded through an alumina multi-bore tube. The oven can be hosted in a standard DN40CF cube and has an estimated continuous operation lifetime of 10 years. This oven can be used for other alkali and alkaline earth metals with essentially no modifications.Comment: 6 pages, 6 figures, Review of Scientific Instruments, in pres

Solitons in the one-dimensional forest fire model

Fires in the one-dimensional Bak-Chen-Tang forest fire model propagate as solitons, resembling shocks in Burgers turbulence. The branching of solitons, creating new fires, is balanced by the pair-wise annihilation of oppositely moving solitons. Two distinct, diverging length scales appear in the limit where the growth rate of trees, $p$, vanishes. The width of the solitons, $w$, diverges as a power law, $1/p$, while the average distance between solitons diverges much faster as $d \sim \exp({\pi}^2/12p)$.Comment: 4 pages with 2 figures include

Analyzing runtime and size complexity of integer programs

We present a modular approach to automatic complexity analysis of integer programs. Based on a novel alternation between finding symbolic time bounds for program parts and using these to infer bounds on the absolute values of program variables, we can restrict each analysis step to a small part of the program while maintaining a high level of precision. The bounds computed by our method are polynomial or exponential expressions that depend on the absolute values of input parameters. We show how to extend our approach to arbitrary cost measures, allowing to use our technique to find upper bounds for other expended resources, such as network requests or memory consumption. Our contributions are implemented in the open source tool KoAT, and extensive experiments show the performance and power of our implementation in comparison with other tools

Long range transport of ultra cold atoms in a far-detuned 1D optical lattice

We present a novel method to transport ultra cold atoms in a focused optical lattice over macroscopic distances of many Rayleigh ranges. With this method ultra cold atoms were transported over 5 cm in 250 ms without significant atom loss or heating. By translating the interference pattern together with the beam geometry the trap parameters are maintained over the full transport range. Thus, the presented method is well suited for tightly focused optical lattices that have sufficient trap depth only close to the focus. Tight focusing is usually required for far-detuned optical traps or traps that require high laser intensity for other reasons. The transport time is short and thus compatible with the operation of an optical lattice clock in which atoms are probed in a well designed environment spatially separated from the preparation and detection region.Comment: 14 pages, 6 figure

Determinants of Gray Wolf (Canis lupus) Sightings in Denali National Park

Wildlife viewing within protected areas is an increasingly popular recreational activity. Management agencies are often tasked with providing these opportunities, yet quantitative analyses of factors influencing wildlife sightings are lacking. We analyzed locations of GPS-collared wolves and wolf sightings from 2945 trips in Denali National Park and Preserve, Alaska, USA, to provide a mechanistic understanding of how viewing opportunities are influenced by attributes of wolves and physical, biological, and harvest characteristics. We found that the presence of masking vegetation, den site proximity to the road, pack size, and presence of a wolf harvest closure adjacent to the park affected wolf sightings, and the influence of den proximity on sightings depended on harvest management. Wolf sightings increased with den site proximity to the road in years with a harvest closure adjacent to the park but not in the absence of the closure. The effect of the harvest closure on sightings was similar in magnitude to an increase in pack size by two wolves or a more than a two-fold decrease in masking vegetation. These findings were consistent across a 10-fold change in spatial resolution. Quantitative analysis of the factors influencing wildlife sightings provides valuable insight for agencies tasked with managing viewing opportunities. L’observation de la faune dans les aires protégées est un loisir qui prend de plus en plus d’ampleur. Souvent, les organismes de gestion ont le mandat d’offrir de telles activités et pourtant, il n’y a toujours pas d’analyses quantitatives des facteurs qui exercent une influence sur les observations fauniques. Nous avons analysé les emplacements de loups munis de colliers GPS et les observations de loups découlant de 2 945 déplacements au parc national et à la réserve de Denali, en Alaska, aux États-Unis afin d’obtenir une compréhension mécaniste de la manière dont les activités d’observation sont influencées par les attributs des loups ainsi que par les caractéristiques physiques, biologiques et de récolte. Nous avons remarqué que la présence de végétation masquante, la proximité des tanières de la route, la taille des meutes et la présence d’une interdiction de récolte de loups dans le secteur adjacent au parc ont eu un effet sur les observations de loups, et que l’influence de la proximité des tanières par rapport aux observations dépendait de la gestion des récoltes. Les observations de loups augmentaient en fonction de la proximité des tanières par rapport à la route au cours des années pendant lesquelles il y avait interdiction de récolte de loups dans le secteur adjacent au parc, mais ce n’était pas le cas en l’absence d’interdiction. L’ampleur de l’effet de l’interdiction de récolte sur les observations était semblable à une augmentation de la taille de la meute correspondant à deux loups ou plus, ou à la diminution de plus du double de la végétation masquante. Ces constatations se recoupaient dans un changement correspondant au décuple dans la résolution spatiale. L’analyse quantitative des facteurs influençant les observations fauniques offre une importante perspective aux organismes dont le mandat consiste à gérer les activités d’observation.&nbsp

NEOShield kinetic impactor demonstration mission

This paper outlines a near-term mission concept developed under the NEOShield Project, for the demonstration of deflection capability of Potentially Hazardous Objects (PHOs). Potentially Hazardous Objects are a subclass of NEOs consisting mostly of asteroids (Potentially Hazardous Asteroids) that have the potential to make close approaches to the Earth whilst featuring a size large enough to cause significant regional damage in the event of an impact. It is currently (as of 2012) expected that only 20 - 30 percent of all existing PHOs are already known. This gives an indication that NEOs, in particular PHOs, are likely to pose a real threat to earth on a long time scale. Among the possible mitigation and deflection options, the mission outlined here seeks to demonstrate NEO deflection by means of a kinetic impactor. The main objectives of the mission are technology demonstration, deflection validation and beta-factor determination. This requires a mission that impacts a NEO in a representative velocity regime, allows measurement of the deflection sufficiently accurately to clearly demonstrate the momentum transfer by the impactor. The beta-factor quantifies the additional momentum transfer achieved through ejecta from the asteroid, which can be achieved both through accurate deflection measurement or ejecta observation, ideally through both. For the development of a fitting mission concept the NEOShield project performed a wide range of trade-offs while taking into consideration a variety of previously developed mission concepts such as Don Quijote