518 research outputs found
Photoelasticity of sodium silicate glass from first principles
Based on density-functional perturbation theory we have computed the
photoelastic tensor of a model of sodium silicate glass of composition
(NaO)(SiO) (NS3). The model (containig 84 atoms) is
obtained by quenching from the melt in combined classical and Car-Parrinello
molecular dynamics simulations. The calculated photoelastic coefficients are in
good agreement with experimental data. In particular, the calculation
reproduces quantitatively the decrease of the photoelastic response induced by
the insertion of Na, as measured experimentally.
The extension to NS3 of a phenomenological model developed in a previous work
for pure a-SiO indicates that the modulation upon strain of other
structural parameters besides the SiOSi angles must be invoked to explain the
change in the photoelstic response induced by Na
Crystal structure of LaTiO_3.41 under pressure
The crystal structure of the layered, perovskite-related LaTiO_3.41
(La_5Ti_5O_{17+\delta}) has been studied by synchrotron powder x-ray
diffraction under hydrostatic pressure up to 27 GPa (T = 295 K). The
ambient-pressure phase was found to remain stable up to 18 GPa. A sluggish, but
reversible phase transition occurs in the range 18--24 GPa. The structural
changes of the low-pressure phase are characterized by a pronounced anisotropy
in the axis compressibilities, which are at a ratio of approximately 1:2:3 for
the a, b, and c axes. Possible effects of pressure on the electronic properties
of LaTiO_3.41 are discussed.Comment: 5 pages, 6 figure
Structural, elastic and thermal properties of cementite (FeC) calculated using Modified Embedded Atom Method
Structural, elastic and thermal properties of cementite (FeC) were
studied using a Modified Embedded Atom Method (MEAM) potential for iron-carbon
(Fe-C) alloys. Previously developed Fe and C single element potentials were
used to develop an Fe-C alloy MEAM potential, using a statistically-based
optimization scheme to reproduce structural and elastic properties of
cementite, the interstitial energies of C in bcc Fe as well as heat of
formation of Fe-C alloys in L and B structures. The stability of
cementite was investigated by molecular dynamics simulations at high
temperatures. The nine single crystal elastic constants for cementite were
obtained by computing total energies for strained cells. Polycrystalline
elastic moduli for cementite were calculated from the single crystal elastic
constants of cementite. The formation energies of (001), (010), and (100)
surfaces of cementite were also calculated. The melting temperature and the
variation of specific heat and volume with respect to temperature were
investigated by performing a two-phase (solid/liquid) molecular dynamics
simulation of cementite. The predictions of the potential are in good agreement
with first-principles calculations and experiments.Comment: 12 pages, 9 figure
Quorum of observables for universal quantum estimation
Any method for estimating the ensemble average of arbitrary operator
(observables or not, including the density matrix) relates the quantity of
interest to a complete set of observables, i.e. a quorum}. This corresponds to
an expansion on an irreducible set of operators in the Liouville space. We give
two general characterizations of these sets. All the known unbiased
reconstruction techniques, i.e. ``quantum tomographies'', can be described in
this framework. New operatorial resolutions are given that can be used to
implement novel reconstruction schemes.Comment: Latex, no figure
Compositional disorder and its influence on the structural, electronic and magnetic properties of MgC(Ni_{1-x}Co_{x})_{3} alloys using first-principles
First-principles, density-functional based electronic structure calculations
are carried out for MgC(Ni_{1-x}Co_{x})_{3} alloys over the concentration range
0\leq x\leq1, using Korringa-Kohn-Rostoker coherent-potential approximation
(KKR CPA) method in the atomic sphere approximation (ASA). The self-consistent
calculations are used to study the changes as a function of x in the equation
of state parameters, total and partial densities of states, magnetic moment and
the on-site exchange interaction parameter. To study the magnetic properties as
well as its volume dependence, fixed-spin moment calculations in conjunction
with the phenomenological Landau theory are employed. The salient features that
emerge from these calculations are (i) a concentration independent variation in
the lattice parameter and bulk modulus at x~0.75 with an anomaly in the
variation of the pressure derivative of bulk modulus, (ii) the fixed-spin
moment based corrections to the overestimated magnetic ground state for 0.0\leq
x\leq0.3 alloys, making the results consistent with the experiments, and (iii)
the possibility of multiple magnetic states at x~0.75, which, however, requires
further improvements in the calculations
Eutactic quantum codes
We consider sets of quantum observables corresponding to eutactic stars.
Eutactic stars are systems of vectors which are the lower dimensional
``shadow'' image, the orthogonal view, of higher dimensional orthonormal bases.
Although these vector systems are not comeasurable, they represent redundant
coordinate bases with remarkable properties. One application is quantum secret
sharing.Comment: 6 page
Structural stability of Fe5Si3 and Ni2Si studied by high-pressure x-ray diffraction and ab initio total-energy calculations
We performed high-pressure angle dispersive x-ray diffraction measurements on
Fe5Si3 and Ni2Si up to 75 GPa. Both materials were synthesized in bulk
quantities via a solid-state reaction. In the pressure range covered by the
experiments, no evidence of the occurrence of phase transitions was observed.
On top of that, Fe5Si3 was found to compress isotropically, whereas an
anisotropic compression was observed in Ni2Si. The linear incompressibility of
Ni2Si along the c-axis is similar in magnitude to the linear incompressibility
of diamond. This fact is related to the higher valence-electron charge density
of Ni2Si along the c-axis. The observed anisotropic compression of Ni2Si is
also related to the layered structure of Ni2Si where hexagonal layers of Ni2+
cations alternate with graphite-like layers formed by (NiSi)2- entities. The
experimental results are supported by ab initio total-energy calculations
carried out using density functional theory and the pseudopotential method. For
Fe5Si3, the calculations also predicted a phase transition at 283 GPa from the
hexagonal P63/mcm phase to the cubic structure adopted by Fe and Si in the
garnet Fe5Si3O12. The room-temperature equations of state for Fe5Si3 and Ni2Si
are also reported and a possible correlation between the bulk modulus of iron
silicides and the coordination number of their minority element is discussed.
Finally, we report novel descriptions of these structures, in particular of the
predicted high-pressure phase of Fe5Si3 (the cation subarray in the garnet
Fe5Si3O12), which can be derived from spinel Fe2SiO4 (Fe6Si3O12).Comment: 44 pages, 13 figures, 3 Table
Ab initio study of the vibrational properties of crystalline TeO2: The alpha, beta, and gamma phases
Based on density functional perturbation theory, we have studied the
vibrational properties of three crystalline phases of tellurium dioxide:
paratellurite alpha-TeO2, tellurite beta-TeO2, and the new phase gamma-TeO2,
recently identified experimentally. Calculated Raman and IR spectra are in good
agreement with available experimental data. The vibrational spectra of alpha-
and beta-TeO2 can be interpreted in terms of vibrations of TeO2 molecular
units
A first-principles comparison of the electronic properties of MgC_{y}Ni_{3} and ZnC_{y}Ni_{3} alloys
First-principles, density-functional-based electronic structure calculations
are employed to study the changes in the electronic properties of ZnC_{y}Ni_{3}
and MgC_{y}Ni_{3} using the Korringa-Kohn-Rostoker coherent-potential
approximation method in the atomic sphere approximation (KKR-ASA CPA). As a
function of decreasing C at%, we find a steady decrease in the lattice constant
and bulk modulus in either alloys. However, the pressure derivative of the bulk
modulus displays an opposite trend. Following the Debye model, which relates
the pressure derivative of the bulk modulus with the average phonon frequency
of the crystal, it can thus be argued that ZnCNi_{3} and its disordered alloys
posses a different phonon spectra in comparison to its MgCNi_{3} counterparts.
This is further justified by the marked similarity we find in the electronic
structure properties such as the variation in the density of states and the
Hopfield parameters calculated for these alloys. The effects on the equation of
state parameters and the density of states at the Fermi energy, for partial
replacement of Mg by Zn are also discussed.Comment: 19 pages, 15 figure
Generalized Euler Angle Paramterization for SU(N)
In a previous paper (math-ph/0202002) an Euler angle parameterization for
SU(4) was given. Here we present the derivation of a generalized Euler angle
parameterization for SU(N). The formula for the calculation of the Haar measure
for SU(N) as well as its relation to Marinov's volume formula for SU(N) will
also be derived. As an example of this parameterization's usefulness, the
density matrix parameterization and invariant volume element for a
qubit/qutrit, three qubit and two three-state systems, also known as two qutrit
systems, will also be given.Comment: 36 pages, no figures; added qubit/qutrit work, corrected minor
definition problems and clarified Haar measure derivation. To be published in
J. Phys. A: Math. and Ge
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