Impact of intrinsic localized modes of atomic motion on materials properties

Recent neutron and x-ray scattering measurements show intrinsic localized modes (ILMs) in metallic uranium and ionic sodium iodide. Here, the role ILMs play in the behavior of these materials is examined. With the thermal activation of ILMs, thermal expansion is enhanced, made more anisotropic, and, at a microscopic level, becomes inhomogeneous. Interstitial diffusion, ionic conductivity, the annealing rate of radiation damage, and void growth are all influenced by ILMs. The lattice thermal conductivity is suppressed above the ILM activation temperature while no impact is observed in the electrical conductivity. This complement of transport properties suggests that ILMs could improve thermoelectric performance. Ramifications also include thermal ratcheting, a transition from brittle to ductile fracture, and possibly a phase transformation in uranium.Comment: 34 pages, 11 figure

Multichannel parametrization of \pi N scattering amplitudes and extraction of resonance parameters

We present results of a new multichannel partial-wave analysis for \pi N scattering in the c.m. energy range 1080 to 2100 MeV. This work explicitly includes \eta N and K \Lambda channels and the single pion photoproduction channel. Resonance parameters were extracted by fitting partial-wave amplitudes from all considered channels using a multichannel parametrization that is consistent with S-matrix unitarity. The resonance parameters so obtained are compared to predictions of quark models

Exploratory Models in a time of Big Data

This paper aims to trigger discourse about the emergence of a new type of social scientific model — Exploratory Models — which draw on Big Data, computer modeling and interdisciplinary research to tackle complex social scientific processes. First, we define Exploratory Models referring to Batty and Morgan and Morrison. We then present changes to the traditional modeling paradigm. We show how Exploratory Models circumvent challenges related to the idiosyncracy, self-reflexivity and acceleration of social phenomena, which limit predictive effectiveness of traditional models. We show that Exploratory Models are better equipped to tackle complex problems due to their capacity to process heterogeneous datasets. Having established that Exploratory Models are predominantly problem- and data-driven, we emphasize that scientific theory is indispensable to their progress. Finally, the development of an integrative platform is suggested as a way of maximizing the benefits of this approach. Discussion concludes by flagging areas for further research

On the Strain-Rate Sensitivity of Columnar Ice

A power law relation between stress and strain rate of the form σ ∝ ε̇1/n was used to describe the response to strain rate of S1 ice loaded across the columns at -10°C. The rate exponent, n, decreased with increasing strain from about 4.6 at an observed peak on the load displacement curve to approximately 2.6 at a shortening of 2%. Analysis of these results and of the results of other authors on different forms of ice deformed at the same temperature suggests that the power law exponent, n, is proportional to Fc/Fg. The parameter Fc/Fg is the far-field basal dislocation climb force divided by the glide force

Household visitation during the COVID-19 pandemic

The COVID-19 pandemic has posed novel risks related to the indoor mixing of individuals from different households and challenged policymakers to adequately regulate this behaviour. While in many cases household visits are necessary for the purpose of social care, they have been linked to broadening community transmission of the virus. In this study we propose a novel, privacy-preserving framework for the measurement of household visitation at national and regional scales, making use of passively collected mobility data. We implement this approach in England from January 2020 to May 2021. The measures expose significant spatial and temporal variation in household visitation patterns, impacted by both national and regional lockdown policies, and the rollout of the vaccination programme. The findings point to complex social processes unfolding differently over space and time, likely informed by variations in policy adherence, vaccine relaxation, and regional interventions

Improving Monolithic Perovskite Silicon Tandem Solar Cells From an Optical Viewpoint

Perovskite silicon tandem solar cells are the most promising concept for a future photovoltaic technology. We report on recent progress from an optical viewpoint and disucss how we achieved more than 25 device efficienc

Maceration Before and During Fermentation: Effect on Pinotage Wine Phenolic Composition, Total Antioxidant Capacity and Objective Colour Parameters

Low-temperature maceration treatments (1, 2 and 4 days at 10 and 15°C) before fermentation and juice/skin mixing treatments (punching-down, pumping-over and rotor action every hour and every 3 hours) duringfermentation were investigated in terms of their effects on Pinotage wine phenolic composition, total antioxidant capacity (TAC) and colour over three vintages (2000 to 2002). Results for pre-fermentation maceration were notconsistent between vintages. Very few significant differences in the phenolic content, TAC and objective colour parameters were observed between the control wines and wines subjected to different pre-fermentation macerationtreatments. Pre-fermentation maceration, especially at 15°C, resulted in wines with increased vitisin A content.  Improvement of wine quality when using pre-fermentation maceration treatments at 10°C was noted previously, while no detrimental effect on the wine TAC was observed. The pumping-over treatment yielded wines with lower TAC and phenol content, as well as less favourable objective colour values, indicating that the punching-down or rotor treatment would be preferred. Although mixing at hourly intervals yielded a higher content of some phenolic compounds compared to the 3-hour interval mixing, mixing frequency did not affect the TAC of the wine. The objective colour parameters, h* and b*, were slightly lower at the higher mixing frequency in 2002 indicating a shift in the direction of a magenta hue

Changes in the Phenolic Composition and Antioxidant Activity of Pinotage, Cabernet Sauvignon, Chardonnay and Chenin blanc Wines During Bottle Ageing

The effect of bottle ageing on the antioxidant activity of Pinotage, Cabernet Sauvignon, Chardonnay and Chenin blanc wines, using the 2,2'-azino-di-(3-ethylbenzothialozine-sulphonic acid) radical cation (ABTS•+) and 2,2-diphenyl-1-picrylhydrazyl radical (DPPH0) scavenging assays, was determined. Storage at 0°C, 15°C or 30°C for a period of 12 months resulted in a significant (p ≤ 0.05) decrease in both the total antioxidant activity (TAAAnTs and TAAoPPH) and the total phenol content of the wines. The antioxidant potency of the total phenols of most of the wines, which is a ratio of antioxidant activity to the total phenol content, also decreased. The total anthocyanins in the red wines decreased significantly (p ≤ 0.05) over 12 months except for storage at 0°C, while the flavanol content of the Pinotage, Cabernet Sauvignon and Chardonnay wines increased up to nine months storage with a subsequent decrease to 12 months. The flavonol content of all the wines decreased, while only minor changes in their hydroxycinnamate content were observed during the storage period. Understanding the complexity of these reactions may provide clues for stabilising especially red wines to preserve the antioxidant activity without losing the beneficial effects of colouring and flavour development during bottle ageing