Nonlinear resonance reflection from and transmission through a dense glassy system built up of oriented linear Frenkel chains: two-level models

A theoretical study of the resonance optical response of assemblies of oriented short (as compared to an optical wavelength) linear Frenkel chains is carried out using a two-level model. We show that both transmittivity and reflectivity of the film may behave in a bistable fashion and analyze how the effects found depend on the film thickness and on the inhomogeneous width of the exciton optical transition.Comment: 26 pages, 9 figure

Statistics of low-energy levels of a one-dimensional weakly localized Frenkel exciton: A numerical study

Numerical study of the one-dimensional Frenkel Hamiltonian with on-site randomness is carried out. We focus on the statistics of the energy levels near the lower exciton band edge, i. e. those determining optical response. We found that the distribution of the energy spacing between the states that are well localized at the same segment is characterized by non-zero mean, i.e. these states undergo repulsion. This repulsion results in a local discrete energy structure of a localized Frenkel exciton. On the contrary, the energy spacing distribution for weakly overlapping local ground states (the states with no nodes within their localization segments) that are localized at different segments has zero mean and shows almost no repulsion. The typical width of the latter distribution is of the same order as the typical spacing in the local discrete energy structure, so that this local structure is hidden; it does not reveal itself neither in the density of states nor in the linear absorption spectra. However, this structure affects the two-exciton transitions involving the states of the same segment and can be observed by the pump-probe spectroscopy. We analyze also the disorder degree scaling of the first and second momenta of the distributions.Comment: 10 pages, 6 figure

Pauli-Villars Regularization in nonperturbative Hamiltonian approach on the Light Front

The advantage of Pauli-Villars regularization in quantum field theory quantized on the light front is explained. Simple examples of scalar $\lambda\varphi^4$ field theory and Yukawa-type model are used. We give also an example of nonperturbative calculation in the theory with Pauli-Villars fields, using for that a model of anharmonic oscillator modified by inclusion of ghost variables playing the role similar to Pauli-Villars fields.Comment: LaTeX, 10 pages, 2 figures. Article will be published in AIP Conference Proceedings, the final publication will be available at http://scitation.aip.org/content/aip/proceeding/aipc

Localization properties of a one-dimensional tight-binding model with non-random long-range inter-site interactions

We perform both analytical and numerical studies of the one-dimensional tight-binding Hamiltonian with stochastic uncorrelated on-site energies and non-fluctuating long-range hopping integrals . It was argued recently [A. Rodriguez at al., J. Phys. A: Math. Gen. 33, L161 (2000)] that this model reveals a localization-delocalization transition with respect to the disorder magnitude provided . The transition occurs at one of the band edges (the upper one for and the lower one for). The states at the other band edge are always localized, which hints on the existence of a single mobility edge. We analyze the mobility edge and show that, although the number of delocalized states tends to infinity, they form a set of null measure in the thermodynamic limit, i.e. the mobility edge tends to the band edge. The critical magnitude of disorder for the band edge states is computed versus the interaction exponent by making use of the conjecture on the universality of the normalized participation number distribution at transition.Comment: 7 pages, 6 postscript figures, uses revtex

Signature of Anomalous Exciton Localization in the Optical Response of Self-Assembled Organic Nanotubes

We show that the disorder scaling of the low-temperature optical absorption linewidth of tubular molecular assemblies sharply contrasts with that known for one-dimensional aggregates. The difference can be explained by an anomalous localization of excitons, which arises from the combination of long-range intermolecular interactions and the tube's higher-dimensional geometry. As a result, the exciton density of states near the band bottom drops to zero, leading to a strong suppression of exciton localization. Our results explain the strong linear dichroism and weak exciton-exciton scattering in tubular J aggregates observed in experiments and suggest that for nanoscale wirelike applications a tubular shape is to be preferred over a truly one-dimensional chain