39,447 research outputs found
Preparation of microscopic cross sections of U235 for reactor calculations
Preparation of microscopic cross section of uranium 235 for high temperature reactor calculation
City and Countryside Revisited. Comparative rent movements in London and the South-East, 1580-1914
Economic historians have traditionally argued that urban growth in England was driven primarily by prior improvements in agricultural supply in the two centuries before the industrial revolution. Recent revisionist scholarship by writers such as Jan Luiten van Zanden and Robert Allen has suggested that 'the city drove the countryside, not the reverse'. This paper assembles new serial data on urban and agricultural rent movements in Kent, Essex and London, from 1580-1914, which enables us to provide a tentative estimate of the strength of the urban variable and the productivity of land across the rural-urban continuum. Our initial findings support the revisionist view, and throw new light on London's position within the wider metropolitan region. Comparative rent movements suggests a greater continuity between town and countryside than has often been assumed, with sharp increases in rental values occurring on the rural-urban fringes of London and the lower Medway valley
Single-level resonance parameters fit nuclear cross-sections
Least squares analyses of experimental differential cross-section data for the U-235 nucleus have yielded single level Breit-Wigner resonance parameters that fit, simultaneously, three nuclear cross sections of capture, fission, and total
Assembly and force measurement with SPM-like probes in holographic optical tweezers
We report a high fidelity tomographic reconstruction of the quantum state of photon pairs generated by parametric down-conversion with orbital angular momentum (OAM) entanglement. Our tomography method allows us to estimate an upper and lower bound for the entanglement between the down-converted photons. We investigate the two-dimensional state subspace defined by the OAM states ±â and superpositions thereof, with â=1, 2, ..., 30. We find that the reconstructed density matrix, even for OAMs up to around â=20, is close to that of a maximally entangled Bell state with a fidelity in the range between F=0.979 and F=0.814. This demonstrates that, although the single count-rate diminishes with increasing â, entanglement persists in a large dimensional state space
Increasing trap stiffness with position clamping in holographic optical tweezers
We present a holographic optical tweezers system capable of position clamping multiple particles. Moving an optical trap in response to the trapped object's motion is a powerful technique for optical control and force measurement. We have now realised this experimentally using a Boulder Nonlinear Systems Spatial Light Modulator (SLM) with a refresh rate of 203Hz. We obtain a reduction of 44% in the variance of the bead's position, corresponding to an increase in effective trap stiffness of 77%. This reduction relies on the generation of holograms at high speed. We present software capable of calculating holograms in under 1ms using a graphics processor unit. © 2009 Optical Society of America
Understanding the role of promoters in catalysis: operando XAFS/DRIFTS study of CeO<sub>x</sub>/Pt/Al<sub>2</sub>O<sub>3</sub> during CO oxidation
A combined operando XAFS/DRIFTS study on CeOx/Pt/Al2O3 catalysts has been performed during CO oxidation and provides insights into the changes in nanoparticle structure and adsorbed species during the reaction profile. The onset of CO2 formation is shown to be concurrent with a rapid re-oxidation of the Pt nanoparticles, evidenced by XAFS spectroscopy, and the loss of bridge bonded CO adsorbed on Pt, as shown by simultaneous DRIFTS acquisition. The continued appearance of linear bound CO on the catalyst surface is shown to remain long after catalytic light off. The interaction of Pt and CeOx is evidenced by the improved performance towards CO oxidation, compared to the non-CeOx modified Pt/Al2O3, and changes in the CO adsorption properties on Pt previously linked to Pt-CeO2 interfaces
Crystal Structure and Chemistry of Topological Insulators
Topological surface states, a new kind of electronic state of matter, have
recently been observed on the cleaved surfaces of crystals of a handful of
small band gap semiconductors. The underlying chemical factors that enable
these states are crystal symmetry, the presence of strong spin orbit coupling,
and an inversion of the energies of the bulk electronic states that normally
contribute to the valence and conduction bands. The goals of this review are to
briefly introduce the physics of topological insulators to a chemical audience
and to describe the chemistry, defect chemistry, and crystal structures of the
compounds in this emergent field.Comment: Submitted to Journal of Materials Chemistry, 47 double spaced pages,
9 figure
On the Physical Origin of OVI Absorption-Line Systems
We present a unified analysis of the O{\sc vi} absorption-lines seen in the
disk and halo of the Milky Way, high velocity clouds, the Magellanic Clouds,
starburst galaxies, and the intergalactic medium. We show that these disparate
systems define a simple relationship between the O{\sc vi} column density and
absorption-line width that is independent of the Oxygen abundance over the
range O/H 10% to twice solar. We show that this relation is exactly that
predicted theoretically as a radiatively cooling flow of hot gas passes through
the coronal temperature regime - independent of its density or metallicity (for
O/H 0.1 solar). Since most of the intregalactic O{\sc vi} clouds obey
this relation, we infer that they can not have metallicities less than a few
percent solar. In order to be able to cool radiatively in less than a Hubble
time, the intergalactic clouds must be smaller than 1 Mpc in size. We
show that the cooling column densities for the O{\sc iv}, O{\sc v}, Ne{\sc v},
and Ne{\sc vi} ions are comparable to those seen in O{\sc vi}. This is also
true for the Li-like ions Ne{\sc viii}, Mg{\sc x}, and Si{\sc xii} (if the gas
is cooling from K). All these ions have strong resonance lines
in the extreme-ultraviolet spectral range, and would be accessible to at
0.2 to 0.8. We also show that the Li-like ions can be used to probe
radiatively cooling gas at temperatures an order-of-magnitude higher than where
their ionic fraction peaks. We calculate that the H-like (He-like) O, Ne, Mg,
Si, and S ions have cooling columns of cm. The O{\sc vii},
O{\sc viii}, and Ne{\sc ix} X-ray absorption-lines towards PKS 2155-304 may
arise in radiatively cooling gas in the Galactic disk or halo.Comment: 25 pages, 5 figure
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