Study of formation of high aspect GaAs structures based on the method of focused ion beams

This work was supported by the Russian Science Foundation Grant No. 15-19-10006. The results were obtained using the equipment of the Research and Education Center and Center for Collective Use "Nanotechnologies" of Southern Federal University

Photoluminescence of tetrahedral quantum-dot quantum wells

Taking into account the tetrahedral shape of a quantum dot quantum well (QDQW) when describing excitonic states, phonon modes and the exciton-phonon interaction in the structure, we obtain within a non-adiabatic approach a quantitative interpretation of the photoluminescence spectrum of a single CdS/HgS/CdS QDQW. We find that the exciton ground state in a tetrahedral QDQW is bright, in contrast to the dark ground state for a spherical QDQW. The position of the phonon peaks in the photoluminescence spectrum is attributed to interface optical phonons. We also show that the experimental value of the Huang-Rhys parameter can be obtained only within the nonadiabatic theory of phonon-assisted transitions.Comment: 4 pages, 4 figures, E-mail addresses: [email protected], [email protected], [email protected], [email protected], to be published in Phys. Rev. Letter

Evidence for differentiation in the iron-helicoidal-chain in GdFe3_{3}(BO3_{3})4_{4}

We report on a single-crystal X-ray structure study of $GdFe_{3}(BO_{3})_{4}$ at room temperature and at T=90 K. At room temperature $GdFe_{3}(BO_{3})_{4}$ crystallizes in a trigonal space group R32 (No. 155), the same as found for other members of iron-borate family $RFe_{3}(BO_{3})_{4}$. At 90 K the structure of $GdFe_{3}(BO_{3})_{4}$ has transformed to the space group $P3_{1}2_{1}$ (No. 152). The low-temperature structure determination gives new insight into the weakly first-order structural phase transition at 156 K and into the related Raman phonon anomalies. The discovery of two inequivalent iron chains in the low temperature structure provide new point of view on the low-temperature magnetic properties.Comment: Subm. to Acta Cryst.

Infrared study of lattice dynamics and spin-phonon and electron-phonon interactions in multiferroic TbFe3(BO3)4 and GdFe3(BO3)4

We present a comparative far-infrared reflection spectroscopy study of phonons, phase transitions, spin-phonon and electron-phonon interactions in isostructural multiferroic iron borates of gadolinium and terbium. The behavior of phonon modes registered in a wide temperature range is consistent with a weak first-order structural phase transition (Ts = 143 for GdFe3(BO3)4 and 200 K for TbFe3(BO3)4) from high-symmetry high-temperature R32 structure into low-symmetry low-temperature P3121 one. The temperature dependences of frequencies, oscillator strengths, and damping constants of some low-frequency modes reveal an appreciable lattice anharmonicity. Peculiarities in the phonon mode behavior in both compounds at the temperature of an antiferromagnetic ordering (TN = 32 K for GdFe3(BO3)4 and 40 K for TbFe3(BO3)4) evidence the spin-phonon interaction. In the energy range of phonons, GdFe3(BO3)4 has no electronic levels but TbFe3(BO3)4 possesses several ones. We observe an onset of new bands in the excitation spectrum of TbFe3(BO3)4, due to a resonance interaction between a lattice phonon and 4f electronic crystal-field excitations of Tb3+. This interaction causes delocalization of the CF excitations, their Davydov splitting, and formation of coupled electron-phonon modes.Comment: 26 pages, 4 tables, 8 firgure

Imbalanced d-wave superfluids in the BCS-BEC crossover regime at finite temperatures

Singlet pairing in a Fermi superfluid is frustrated when the amounts of fermions of each pairing partner are unequal. The resulting `imbalanced superfluid' has been realized experimentally for ultracold atomic gases with s-wave interactions. Inspired by high-temperature superconductivity, we investigate the case of d-wave interactions, and find marked differences from the s-wave superfluid. Whereas s-wave imbalanced Fermi gases tend to phase separate in real space, in a balanced condensate and an imbalanced normal halo, we show that the d-wave gas can phase separate in reciprocal space so that imbalance and superfluidity can coexist spatially. We show that the mechanism explaining this property is the creation of polarized excitations in the nodes of the gap. The Sarma mechanism, present only at nonzero temperatures for the s-wave case, is still applicable in the temperature zero limit for the d-wave case. As a result, the d-wave BCS superfluid is more robust with respect to imbalance, and a region of the phase diagram can be identified where the s-wave BCS superfluidity is suppressed whereas the d-wave superfluidity is not. When these results are extended into the BEC limit of strongly bound molecules, the symmetry of the order parameter matters less. The effects of fluctuations beyond mean field is taken into account in the calculation of the structure factor and the critical temperature. The poles of the structure factor (corresponding to bound molecular states) are less damped in the d-wave case as compared to s-wave. On the BCS side of the unitarity limit, the critical temperature follows the temperature corresponding to the pair binding energy and as such will also be more robust against imbalance. Possible routes for the experimental observation of the d-wave superfluidity have been discussed.Comment: 22 pages, 7 figure

Infrared study of lattice and magnetic dynamics in a spin-chain compound Gd2 BaNiO5

We present infrared spectra of Gd2 BaNiO5, which is isostructural to a prototype S=1 Haldane compound Y2 BaNiO 5 containing Ni2⊃+ chains, in the spectral range 2 meV-0.55 eV. Unlike Y2 BaNiO5, the studied compound contains magnetic rare-earth sublattices and orders antiferromagnetically at TN =58 K. Detailed information on optical phonons is given. Temperature dependences of frequencies and half widths for the two lowest-frequency phonons polarized along the Ni-chain direction evidence the interaction of these lattice vibrations with magnetic excitations. With the help of lattice-dynamics calculations, we find relative displacement vectors of ions for all the phonon modes and use them to discuss the mechanism of phonon-magnon interaction. The optical spectra exhibit a broad absorption continuum for radiation polarized along the chains, probably of magnetic origin, gradually decreasing with lowering temperature. A new mode at about 30 cm⊃-1 polarized along the chains (a axis) emerges below ∼150 K. A midinfrared absorption peak at 1306 cm⊃-1 (0.16 eV) is observed and found to sharpen and shift significantly at TN. We argue that it can be attributed to a phonon-assisted magnetic absorption and discuss its nature in the framework of the Lorenzana-Sawatzky-Eder model. © 2010 The American Physical Society

Raman scattering from phonons and magnons in RFe3)BO3)4

Inelastic light scattering spectra of several members of the RFe3(BO3)4 family reveal a cascade of phase transitions as a function of temperature, starting with a structural, weakly first order, phase transition followed by two magnetic phase transitions. Those consist of the ordering of the Fe-spin sublattice revealed by all the compound, and a subsequent spin-reorientational transition for GdFe3(BO3)4. The Raman data evidence a strong coupling between the lattice and magnetic degrees of freedom in these borates. The Fe-sublattice ordering leads to a strong suppression of the low energy magnetic scattering, and a multiple peaked two-magnon scattering continuum is observed. Evidence for short-range correlations is found in the `paramagnetic' phase by the observation of a broad magnetic continuum in the Raman data, which persists up to surprisingly high temperatures.Comment: 17 pages, 13 figure

Many-body large polaron optical conductivity in SrTi1−x_{1-x}Nbx_xO3_3

Recent experimental data on the optical conductivity of niobium doped SrTiO$_{3}$ are interpreted in terms of a gas of large polarons with effective coupling constant $\alpha_{eff}\approx2$. The {theoretical approach takes into account} many-body effects, the electron-phonon interaction with multiple LO-phonon branches, and the degeneracy and the anisotropy of the Ti t$_{2g}$ conduction band. {Based on the Fr\"{o}hlich interaction, the many-body large-polaron theory} provides an interpretation for the essential characteristics, except -- interestingly -- for the unexpectedly large intensity of a peak at $\sim130$ meV, of the observed optical conductivity spectra of SrTi$_{1-x}$Nb$_{x}$O$_{3}$ \textit{without} any adjustment of material parameters.Comment: to appear in Phys. Rev.

Polar optical phonons in wurtzite spheroidal quantum dots: Theory and application to ZnO and ZnO/MgZnO nanostructures

Polar optical-phonon modes are derived analytically for spheroidal quantum dots with wurtzite crystal structure. The developed theory is applied to a freestanding spheroidal ZnO quantum dot and to a spheroidal ZnO quantum dot embedded into a MgZnO crystal. The wurtzite (anisotropic) quantum dots are shown to have strongly different polar optical-phonon modes in comparison with zincblende (isotropic) quantum dots. The obtained results allow one to explain and accurately predict phonon peaks in the Raman spectra of wurtzite nanocrystals, nanorods (prolate spheroids), and epitaxial quantum dots (oblate spheroids).Comment: 11 page

Multi-phonon Raman scattering in semiconductor nanocrystals: importance of non-adiabatic transitions

Multi-phonon Raman scattering in semiconductor nanocrystals is treated taking into account both adiabatic and non-adiabatic phonon-assisted optical transitions. Because phonons of various symmetries are involved in scattering processes, there is a considerable enhancement of intensities of multi-phonon peaks in nanocrystal Raman spectra. Cases of strong and weak band mixing are considered in detail. In the first case, fundamental scattering takes place via internal electron-hole states and is participated by s- and d-phonons, while in the second case, when the intensity of the one-phonon Raman peak is strongly influenced by the interaction of an electron and of a hole with interface imperfections (e. g., with trapped charge), p-phonons are most active. Calculations of Raman scattering spectra for CdSe and PbS nanocrystals give a good quantitative agreement with recent experimental results.Comment: 16 pages, 2 figures, E-mail addresses: [email protected], [email protected], [email protected], accepted for publication in Physical Review