Probing the reactivity of a 2,2′-bipyridyl-3,3′-bis-imine ligand by X-ray crystallography

The reactivity of a Schiff-base bis-imine ligand 3 is probed by X-ray diffraction studies. Its susceptibility to hydrolysis, oxidation and nucleophilic addition reactions is demonstrated by the isolation of the methanol adduct 4 and two diazapene heterocycles 5 and 6. This reactivity is also reflected in the molecular structures of two coordination complexes isolated by the reaction of 3 with MIJhfac)2 salts, to afford [Cu(5)-(hfac)(tfa)] (8) and [Zn(6)(hfac)2] (9)

A Taxonomy of Knowledge Spillovers for High-Tech Start-ups Development

Entrepreneurship is considered of utmost importance for national economic and industrial growth. A leading theory related to economic development is the Knowledge Spillover Theory of Entrepreneurship (KSTE), which aims to uncover the effects that economic agents have on the creation of new companies. By following the KSTE process, companies can commercialize and implement newly acquired knowledge in the market more quickly. Typically, economic growth evaluation is conducted at the country or regional level through global monitoring indexes, assessment on the generation of patents, and identification of the number of companies created. However, since knowledge is sometimes unattached to a physical document or item, it remains necessary to clarify a taxonomy and flow of knowledge spillovers at the individual level for start-ups in their first three to five years of development from the time that the company is funded. The purpose of this paper is to identify and discuss possible strategies for evaluating the effects of knowledge spillovers on start-ups in high-tech sections which, in turn, will aid the decision-making process of Chief Executive Officers (CEOs)

A Taxonomy of Knowledge Spillovers for High-Tech Start-ups Development

Entrepreneurship is considered of utmost importance for national economic and industrial growth. A leading theory related to economic development is the Knowledge Spillover Theory of Entrepreneurship (KSTE), which aims to uncover the effects that economic agents have on the creation of new companies. By following the KSTE process, companies can commercialize and implement newly acquired knowledge in the market more quickly. Typically, economic growth evaluation is conducted at the country or regional level through global monitoring indexes, assessment on the generation of patents, and identification of the number of companies created. However, since knowledge is sometimes unattached to a physical document or item, it remains necessary to clarify a taxonomy and flow of knowledge spillovers at the individual level for start-ups in their first three to five years of development from the time that the company is funded. The purpose of this paper is to identify and discuss possible strategies for evaluating the effects of knowledge spillovers on start-ups in high-tech sections which, in turn, will aid the decision-making process of Chief Executive Officers (CEOs)

The Effects of Knowledge Spillovers and Accelerator Programs on the Product Innovation of High-Tech Start-Ups: A Multiple Case Study

The Knowledge Spillover Theory of Entrepreneurship (KSTE) explores the effects that new knowledge and proximity have on the exploitation of entrepreneurial opportunities and the resultant creation of start-ups. This paper aims to identify the types of knowledge spillovers that affect entrepreneurs in the early stages of start-up development. A conceptual model is proposed, using a multi-case study approach involving High-Tech start-ups that have attended accelerator and incubator programmes in Greater London, United Kingdom (UK). The research involved 32 semistructured interviews with Chief Executive Officers (CEOs) and co-founders of start-up companies. Our findings suggest that entrepreneurs are influenced by various forms of knowledge spillover which assist in determining the strategic decision of the company, in terms of formation, including partnerships or alliances, allocation of Research and Development (R&D) budgets, and engagement in product innovation. Further observations confirm that High-tech start-ups focus on a fast pace of constant product innovation to cover identified gaps in the market. One significant finding is that start-ups use various technological platforms to access knowledge spillovers which challenges the ideas of geographical proximity present in existing KSTE understanding

Experiences and perceptions of Spring Lane Sure Start Children's Centre

Spring Lane Sure Start Children’s Centre was designated in September 2007, and ‘officially opened’ in February 2009. The Centre is housed in refurbished premises within a nursery/school complex in the heart of Northampton and offers diverse health, childcare, early education and support services delivered by a multi-professional team. These services and activities are available to children aged 0-5 years old, and their parents/carers, residing within a catchment area comprising eight ‘Super Output Areas’ in the Castle and St. James ward of Northampton. In April 2009, the Centre for Children and Youth (CCY) – a research centre based at The University of Northampton – was commissioned by Spring Lane Sure Start Children’s Centre to collate and gather evaluative data regarding experiences and perceptions of the Children’s Centre during its first year of activitie