673 research outputs found
Direct experimental observation of nonclassicality in ensembles of single photon emitters
In this work we experimentally demonstrate for the first time a recently
proposed criterion adressed to detect nonclassical behavior in the fluorescence
emission of ensembles of single-photon emitters. In particular, we apply the
method to study clusters of NV centres in diamond observed via
single-photon-sensitive confocal microscopy. Theoretical considerations on the
behavior of the parameter at any arbitrary order in presence of poissonian
noise are presented and, finally, the opportunity of detecting manifold
coincidences is discussed
Native NIR-emitting single colour centres in CVD diamond
Single-photon sources are a fundamental element for developing quantum
technologies, and sources based on colour centres in diamonds are among the
most promising candidates. The well-known NV centres are characterized by
several limitations, thus few other defects have recently been considered. In
the present work, we characterize in detail native efficient single colour
centres emitting in the near infra-red in both standard IIa single-crystal and
electronic-grade polycrystalline commercial CVD diamond samples. In the former
case, a high-temperature annealing process in vacuum is necessary to induce the
formation/activation of luminescent centres with good emission properties,
while in the latter case the annealing process has marginal beneficial effects
on the number and performances of native centres in commercially available
samples. Although displaying significant variability in several photo physical
properties (emission wavelength, emission rate instabilities, saturation
behaviours), these centres generally display appealing photophysical properties
for applications as single photon sources: short lifetimes, high emission rates
and strongly polarized light. The native centres are tentatively attributed to
impurities incorporated in the diamond crystal during the CVD growth of
high-quality type IIa samples, and offer promising perspectives in
diamond-based photonics.Comment: 27 pages, 10 figures. Submitted to "New Journal of Phsyics",
NJP-100003.R
Polarized micro-Raman studies of femtosecond laser written stress-induced optical waveguides in diamond
Understanding the physical mechanisms of the refractive index modulation
induced by femtosecond laser writing is crucial for tailoring the properties of
the resulting optical waveguides. In this work we apply polarized Raman
spectroscopy to study the origin of stress-induced waveguides in diamond,
produced by femtosecond laser writing. The change in the refractive index
induced by the femtosecond laser in the crystal is derived from the measured
stress in the waveguides. The results help to explain the waveguide
polarization sensitive guiding mechanism, as well as providing a technique for
their optimization.Comment: 5 pages, 4 figure
Single-photon-emitting optical centers in diamond fabricated upon Sn implantation
The fabrication of luminescent defects in single-crystal diamond upon Sn
implantation and annealing is reported. The relevant spectral features of the
optical centers (emission peaks at 593.5 nm, 620.3 nm, 630.7 nm and 646.7 nm)
are attributed to Sn-related defects through the correlation of their
photoluminescence (PL) intensity with the implantation fluence. Single
Sn-related defects were identified and characterized through the acquisition of
their second-order auto-correlation emission functions, by means of
Hanbury-Brown-Twiss interferometry. The investigation of their single-photon
emission regime as a function of excitation laser power revealed that
Sn-related defects are based on three-level systems with a 6 ns radiative decay
lifetime. In a fraction of the studied centers, the observation of a blinking
PL emission is indicative of the existence of a dark state. Furthermore,
absorption dependence from the polarization of the excitation radiation with
about 45 percent contrast was measured. This work shed light on the existence
of a new optical center associated with a group-IV impurity in diamond, with
similar photo-physical properties to the already well-known Si-V and Ge-V
emitters, thus providing results of interest from both the fundamental and
applicative points of view.Comment: 10 pages, 4 figure
All-carbon multi-electrode array for real-time in vitro measurements of oxidizable neurotransmitters
We report on the ion beam fabrication of all-carbon multi electrode arrays
(MEAs) based on 16 graphitic micro-channels embedded in single-crystal diamond
(SCD) substrates. The fabricated SCD-MEAs are systematically employed for the
in vitro simultaneous amperometric detection of the secretory activity from
populations of chromaffin cells, demonstrating a new sensing approach with
respect to standard techniques. The biochemical stability and biocompatibility
of the SCD-based device combined with the parallel recording of
multi-electrodes array allow: i) a significant time saving in data collection
during drug screening and/or pharmacological tests over a large number of
cells, ii) the possibility of comparing altered cell functionality among cell
populations, and iii) the repeatition of acquisition runs over many cycles with
a fully non-toxic and chemically robust bio-sensitive substrate.Comment: 24 pages, 5 figure
Photo-physical properties of He-related color centers in diamond
Diamond is a promising platform for the development of technological
applications in quantum optics and photonics. The quest for color centers with
optimal photo-physical properties has led in recent years to the search for
novel impurity-related defects in this material. Here, we report on a
systematic investigation of the photo-physical properties of two He-related
(HR) emission lines at 535 nm and 560 nm created in three different diamond
substrates upon implantation with 1.3 MeV He+ ions and subsequent annealing.
The spectral features of the HR centers were studied in an "optical grade"
diamond substrate as a function of several physical parameters, namely the
measurement temperature, the excitation wavelength and the intensity of
external electric fields. The emission lifetimes of the 535 nm and 560 nm lines
were also measured by means of time-gated photoluminescence measurements,
yielding characteristic decay times of (29 +- 5) ns and (106 +- 10) ns,
respectively. The Stark shifting of the HR centers under the application of an
external electrical field was observed in a CVD diamond film equipped with
buried graphitic electrodes, suggesting a lack of inversion symmetry in the
defects' structure. Furthermore, the photoluminescence mapping under 405 nm
excitation of a "detector grade" diamond sample implanted at a 1x1010 cm-2 He+
ion fluence enabled to identify the spectral features of both the HR emission
lines from the same localized optical spots. The reported results provide a
first insight towards the understanding of the structure of He-related defects
in diamond and their possible utilization in practical applicationsComment: 9 pages, 3 figure
Nanodiamonds-induced effects on neuronal firing of mouse hippocampal microcircuits
Fluorescent nanodiamonds (FND) are carbon-based nanomaterials that can
efficiently incorporate optically active photoluminescent centers such as the
nitrogen-vacancy complex, thus making them promising candidates as optical
biolabels and drug-delivery agents. FNDs exhibit bright fluorescence without
photobleaching combined with high uptake rate and low cytotoxicity. Focusing on
FNDs interference with neuronal function, here we examined their effect on
cultured hippocampal neurons, monitoring the whole network development as well
as the electrophysiological properties of single neurons. We observed that FNDs
drastically decreased the frequency of inhibitory (from 1.81 Hz to 0.86 Hz) and
excitatory (from 1.61 Hz to 0.68 Hz) miniature postsynaptic currents, and
consistently reduced action potential (AP) firing frequency (by 36%), as
measured by microelectrode arrays. On the contrary, bursts synchronization was
preserved, as well as the amplitude of spontaneous inhibitory and excitatory
events. Current-clamp recordings revealed that the ratio of neurons responding
with AP trains of high-frequency (fast-spiking) versus neurons responding with
trains of low-frequency (slow-spiking) was unaltered, suggesting that FNDs
exerted a comparable action on neuronal subpopulations. At the single cell
level, rapid onset of the somatic AP ("kink") was drastically reduced in
FND-treated neurons, suggesting a reduced contribution of axonal and dendritic
components while preserving neuronal excitability.Comment: 34 pages, 9 figure
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