Complexation of Am with size-fractionated soil humic acids

[研究報告

Cavity approach to the first eigenvalue problem in a family of symmetric random sparse matrices

A methodology to analyze the properties of the first (largest) eigenvalue and its eigenvector is developed for large symmetric random sparse matrices utilizing the cavity method of statistical mechanics. Under a tree approximation, which is plausible for infinitely large systems, in conjunction with the introduction of a Lagrange multiplier for constraining the length of the eigenvector, the eigenvalue problem is reduced to a bunch of optimization problems of a quadratic function of a single variable, and the coefficients of the first and the second order terms of the functions act as cavity fields that are handled in cavity analysis. We show that the first eigenvalue is determined in such a way that the distribution of the cavity fields has a finite value for the second order moment with respect to the cavity fields of the first order coefficient. The validity and utility of the developed methodology are examined by applying it to two analytically solvable and one simple but non-trivial examples in conjunction with numerical justification.Comment: 11 pages, 4 figures, to be presented at IW-SMI2010, Kyoto, March 7-10, 201

Electrical properties of boron-doped MWNTs synthesized by hot-filament chemical vapor deposition

We have synthesized a large amount of boron-doped multiwalled carbon nanotubes (MWNTs) by hot-filament chemical vapor deposition. The synthesis was carried out in a flask using a methanol solution of boric acid as a source material. The scanning electron microscopy, transmission electron microscopy, and micro-Raman spectroscopy were performed to evaluate the structural properties of the obtained MWNTs. In order to evaluate the electrical properties, temperature dependence of resistivity was measured in an individual MWNTs with four metal electrodes. The Ramman shifts suggest carrier injection into the boron-doped MWNTs, but the resistivity of the MWNTs was high and increased strongly with decreasing temperature. Defects induced by the plasma may cause this enhanced resistivity.Comment: 16 pages, 5 figures; submitted to the Proceedings of 21st International Symposium on Superconductivity, Tsukuba, Japan, October 27-29, 200

In-situ epitaxial growth of superconducting La-based bilayer cuprate thin films

We investigate the epitaxial growth of bilayer cuprate La2CaCu2O6+\delta using pure ozone as an oxidant, and find that even the crystal with parent composition without cation substitution can show metallic behavior with the aid of epitaxial strain effect. The hole concentration is controlled simply by excess-oxygen doping, and the films grown under the optimum conditions exhibit superconductivity below 30 K. This is the first result on the superconductivity of bilayer La2CaCu2O6+\delta induced purely by the excess oxygen.Comment: 5 pages, 3 figures, To appear in Phys. Rev. B, Rapid Communication

Observation of a superconducting gap in boron-doped diamond by laser-excited photoemission spectroscopy

&lt;p&gt;We investigate the temperature (T)-dependent low-energy electronic structure of a boron-doped diamond thin film using ultrahigh resolution laser-excited photoemission spectroscopy. We observe a clear shift of the leading edge below T=11 K, indicative of a superconducting gap opening (Delta~0.78 meV at T=4.5 K). The gap feature is significantly broad and a well-defined quasiparticle peak is lacking even at the lowest temperature of measurement (=4.5 K). We discuss our results in terms of disorder effects on the normal state transport and superconductivity in this system.&lt;/p&gt;</p

Role of defects and disorder in the half-metallic full-Heusler compounds

Half-metallic ferromagnets and especially the full-Heusler alloys containing Co are at the center of scientific research due to their potential applications in spintronics. For realistic devices it is important to control accurately the creation of defects in these alloys. We review some of our late results on the role of defects and impurities in these compounds. More precisely we present results for the following cases (i) doping and disorder in Co$_2$Cr(Mn)Al(Si) alloys, (ii) half-metallic ferrimagnetism appeared due to the creation of Cr(Mn) antisites in these alloys, (iii) Co-doping in Mn$_2$VAl(Si) alloys leading to half-metallic antiferromagnetism, and finally (iv) the occurrence of vacancies in the full-Heusler alloys containing Co and Mn. These results are susceptible of encouraging further theoretical and experimental research in the properties of these compounds.Comment: Chapter intended for a book with contributions of the invited speakers of the International Conference on Nanoscale Magnetism 2007. Revised version contains new figure