A Tight-Binding Investigation of the NaxCoO2 Fermi Surface

We perform an orthogonal basis tight binding fit to an LAPW calculation of paramagnetic Na$_x$CoO$_2$ for several dopings. The optimal position of the apical oxygen at each doping is resolved, revealing a non-trivial dependence of the band structure and Fermi surface on oxygen height. We find that the small e$_{g'}$ hole pockets are preserved throughout all investigated dopings and discuss some possible reasons for the lack of experimental evidence for these Fermi sheets

Precise Tight-binding Description of the Band Structure of MgB2

We present a careful recasting of first-principles band structure calculations for MgB2 in a non-orthogonal sp-tight-binding (TB) basis. Our TB results almost exactly reproduce our full potential linearized augmented plane wave results for the energy bands, the densities of states and the total energies. Our procedure generates transferable Slater-Koster parameters which should be useful for other studies of this important material.Comment: REVTEX, 2 Encapsulated PostScript Figure

Late Glacial–Holocene climatic transition record at the Argentinian Andean piedmont between 33 and 34° S

The Arroyo La Estacada (~ 33°28' S, 69°02' W), eastern Andean piedmont of Argentina, cuts through an extensive piedmont aggradational unit composed of a dominant Late Pleistocene–early Holocene (LP–EH) alluvial sequence that includes several paleosols. <br><br> One of these paleosols developed affecting the topmost part of likely Late Glacial aeolian deposits aggraded into a floodplain environment by the end of the Late Pleistocene. The paleosol shows variable grade of development along the arroyo outcrops. Organic matter humification, carbonate accumulation and redox processes were the dominant processes associated with paleosol formation. By the early Holocene, when the formation of the paleosol ended, renewed alluvial aggradation and high magnitude flooding events affected the arroyo's floodplain environment. Accordignly, a period of relative landscape stability in the Arroyo La Estacada basin is inferred from the paleosol developed by the LP–EH transition in response to the climatic conditions in the Andes cordillera piedmont after the Late Glacial arid conditions. The analyzed Late Glacial–Holocene alluvial record of the Andean piedmont constitutes a suitable record of the LP–EH climatic transition in the extra-Andean region of Argentina. It is in agreement with regional paleoclimatic evidence along the southern tip of the South American continent, where other pedosedimentary sequences record similar late Quaternary paleoenvironmental changes over both fluvial and interfluvial areas