Enhancement of in vitro production of volatile organic compounds by shoot differentiation in Artemisia spicigera

Callus initiation, shoot formation and plant regeneration were established for Artemisia spicigera, a traditional medicinal plant growing in Armenia, Middle-Anatolia and Iran, and pro- ducing valuable volatile organic compounds (VOCs) that are mostly represented by monoterpe- noids. Optimal callus initiation and shoot production were obtained by culture of hypocotyl and cotyledon explants on MS medium comprising 0.5 mg L−1 naphthalene acetic acid (NAA) and 0.5 mg L−1 6-benzyladenine (BA). Consequently, the shoots were transferred onto the MS media sup- plemented with 1 mg L−1 of indole-3-butyric acid (IBA) or 1 mg L−1 of NAA. Both types of auxin induced root formation on the shoots and the resulting plantlets were successfully grown in pots. The production of VOCs in callus tissues and regenerated plantlets was studied by gas chroma- tography–mass spectrometry (GC-MS) analysis. Although the potential of undifferentiated callus to produce VOCs was very low, an increased content of bioactive volatile components was ob- served at the beginning of shoot primordia differentiation. Intriguingly, the volatiles obtained from in vitro plantlets showed quantitative and qualitative variation depending on the type of auxins used for the rooting process. The acquired quantities based on total ion current (TIC) showed that the regenerated plantlets using 1 mg L−1 NAA produced higher amounts of oxygenated monoter- penes such as camphor (30.29%), cis-thujone (7.07%), and 1,8-cineole (6.71%) and sesquiterpene derivatives, namely germacrene D (8.75%), bicyclogermacrene (4.0%) and spathulenol (1.49%) compared with the intact plant. According to these findings, in vitro generation of volatile organic compounds in A. spicigera depends on the developmental stages of tissues and may enhance with the formation of shoot primordia and regeneration of plantlets

Controlled growth of carbon nanotubes on electrodes under different bias polarity

Carbon nanotubes (CNTs) of different alignments, such as surface-bounded and vertically aligned arrays, enable applications in different fields. In this study, controlled growth of CNTs with different alignments was achieved by electrically biasing catalyzed electrodes with different polarities in a laser-assisted chemical vapor deposition process. CNT growth was suggested to be guided by the movement of electrically charged catalyst-nanoparticles under the influence of an external electric field. This discovery provides a convenient approach to control the alignment of CNT arrays for different applications

Transparent interconnections formed by rapid single-step fabrication of graphene patterns

We developed a process to form transparent interconnections using graphene patterns that were synthesized by laser chemical vapor deposition. The number of graphene layers was tightly controlled by laser scan speed. Graphene patterns were fabricated at a high scan speed of up to 200 µm/s with a single-step process. The process time is about a million times faster than the conventional chemical vapor deposition method. The fabricated graphene patterns on nickel foils were directly transferred to desired positions on patterned electrodes. The position-controlled transfer with rapid single-step fabrication of graphene patterns provides an innovative pathway for graphene-based interconnections

Diameter Modulation by Fast Temperature Control in Laser-Assisted Chemical Vapor Deposition of Single-Walled Carbon Nanotubes

Diameter modulation by fast temperature control in laser-assisted chemical vapor deposition (LCVD) was successfully achieved to tune the diameters of single-walled carbon nanotubes (SWNTs) in different segments. Due to the inverse relationship between the SWNT diameter and the growth temperature, SWNTs with ascending diameters were obtained by reducing the LCVD temperature from high to low. The diameter-modulated SWNTs were integrated in electrodes to form field-effect transistors (FETs) and to investigate their electronic transport properties. The SWNTs in the FET structures have electronic properties similar to Schottky diodes, indicating clear evidence of different bandgap structures at the two ends of the SWNTs. Raman spectroscopy, transmission electron microscopy, and electronic transport characteristics were studied to investigate the influence of temperature variation on the structural and electronic characteristics of the SWNTs

Towards Carbon-Nanotube Integrated Devices: Optically Controlled Parallel Integration of Single-Walled Carbon Nanotubes

Where it starts and where it goes? Controlled integration of single-walled carbon nanotubes (SWNTs) into pre-designed nano-architectures is one of the major challenges to be overcome for extensive scientific research and technological applications. Various serial assembly techniques have been proposed and developed. However, they are still a long way from practical applications due to the drawbacks on reliability, yield and cost. Here we demonstrate a laser-based strategy to achieve parallel integration of SWNTs into pre-designed nano-architectures through an optically controlled in situ growth process. Optical driving forces originated from tip-induced optical near-field enhancement and laser beam polarization were applied in this study to realize the controlled placement of SWNTs at designated sites following wanted orientations on the nanometer scale. Parallel integration of SWNT arrays was achieved by adjusting laser beam diameter to cover interested nano-architectures. The laser-based process suggests an efficient and cost-effective approach for fabricating and integrating SWNT-based devices and circuits

Transparent, flexible, and solid-state supercapacitors based on graphene electrodes

In this study, graphene-based supercapacitors with optical transparency and mechanical flexibility have been achieved using a combination of poly(vinyl alcohol)/phosphoric acid gel electrolyte and graphene electrodes. An optical transmittance of ∼67% in a wavelength range of 500-800 nm and a 92.4% remnant capacitance under a bending angle of 80° have been achieved for the supercapacitors. The decrease in capacitance under bending is ascribed to the buckling of the graphene electrode in compression. The supercapacitors with high optical transparency, electrochemical stability, and mechanical flexibility hold promises for transparent and flexible electronics