Field-induced suppression of the pi-band superconductivity and magnetic hysteresis in the microwave surface resistance of MgB_2 at temperatures near T_c

We report on the magnetic-field-induced variations of the microwave surface resistance, R_s, in a polycrystalline MgB_2 sample, at different values of temperature. We have detected a magnetic hysteresis in R_s, which exhibits an unexpected plateau on decreasing the DC magnetic field below a certain value. In particular, at temperatures near T_c the hysteresis manifests itself only through the presence of the plateau. Although we do not quantitatively justify the anomalous shape of the magnetic hysteresis, we show that the results obtained in the reversible region of the R_s(H) curve can be quite well accounted for by supposing that, in this range of magnetic field, the pi-gap is almost suppressed by the applied field and, consequently, all the pi-band charge carriers are quasiparticles. On this hypothesis, we have calculated R_s(H) supposing that fluxons assume a conventional (single core) structure and the flux dynamics can be described in the framework of conventional models. From the fitting of the experimental results, we determine the values of H_{c2}^pi(T) at temperatures near T_c. In our opinion, the most important result of our investigation is that, at least at temperatures near T_c, the value of the applied field that separates the reversible and irreversible regions of the R_s(H) curves is just H_{c2}^pi(T); a qualitative discussion of the possible reason of this finding is given.Comment: 20 pages, 8 embedded figures, 2 Appendices, accepted for publication in Supercond. Sci. Techno

Critical-state effects on microwave losses in type-II superconductors

We discuss the microwave energy losses in superconductors in the critical state. The field-induced variations of the surface resistance are determined, in the framework of the Coffey and Clem model, by taking into account the distribution of the vortex magnetic field inside the sample. It is shown that the effects of the critical state cannot generally be disregarded to account for the experimental data. Results obtained in bulk niobium at low temperatures are quantitatively justified.Comment: 4 pages, 4 embedded figures, to be published on Eur. Phys. J.

Time relaxation of microwave second order response of superconductors in the critical state

Relaxation of the microwave second order response of YBa2Cu3O7 and Ba0.6K0.4BiO3 crystals in the critical state is studied. The samples are exposed to static and pulsed microwave magnetic fields. The second harmonic signals decay during the time in which the microwave pulse endures. The decay times depend on the supercon-ductor investigated and on the way the value of the static field has been reached.Comment: 2 pages, 1 figur

Fluxon dynamics in Li-Al codoped MgB2 by microwave surface resistance measurements

The magnetic-field-induced variations of the microwave surface resistance, R_s, have been investigated in ceramic Mg_{1-x}(LiAl)_xB_2, with x in the range 0.1 - 0.4. The measurements have been performed on increasing and decreasing the DC magnetic field, H_0, at fixed temperatures. At low temperatures, we have observed a magnetic hysteresis in the R_s(H_0) curves in all the investigated samples. On increasing the temperature, the range of H_0 in which the hysteretic behavior is visible shrinks; however, in the sample with x = 0.1 it is present up to temperatures close to T_c. We show that the field dependence of R_s can be quantitatively justified taking into account the critical-state effects on the fluxon lattice only in the sample with x = 0.4. On the contrary, in the samples with x < 0.4 the hysteresis exhibits an unusual shape, similar to that observed in others two-gap MgB_2 samples, which cannot be justified in the framework of the critical-state models.Comment: 8 pages, 3 embedded figures; proceedings of the Sixth International Conference on Vortex Matter in Nanostructured Superconductors (VORTEX VI) 17-24 September 2009, Rhodes, Greec

Microwave Harmonic Emission in MgB2 Superconductor: Comparison with YBaCuO

We report results of microwave second-harmonic generation in ceramic samples of MgB2, prepared by different methods. The SH signal has been investigated as a function of the temperature and the static magnetic field. The results are discussed in the framework of models reported in the literature. We show that the peculiarities of the SH signal are related to the specific properties of the sample. A comparison with the results obtained in ceramic and crystalline YBa(2)Cu(3)O(7) shows that the second-harmonic emission in MgB2 is weaker than that observed in ceramic YBa(2)Cu(3)O(7).Comment: 13 pages, 6 figures; Proceedings of Third Workshop on Metamaterials and Special Materials for Electromagnetic Applications and TLC (Rome, 30-31 March, 2006

Preliminary Assessment of Parmigiano Reggiano Authenticity by Handheld Raman Spectroscopy

Raman spectroscopy, and handheld spectrometers in particular, are gaining increasing attention in food quality control as a fast, portable, non-destructive technique. Furthermore, this technology also allows for measuring the intact sample through the packaging and, with respect to near infrared spectroscopy, it is not affected by the water content of the samples. In this work, we evaluate the potential of the methodology to model, by multivariate data analysis, the authenticity of Parmigiano Reggiano cheese, which is one of the most well-known and appreciated hard cheeses worldwide, with protected denomination of origin (PDO). On the other hand, it is also highly subject to counterfeiting. In particular, it is critical to assess the authenticity of grated cheese, to which, under strictly specified conditions, the PDO is extended. To this aim, it would be highly valuable to develop an authenticity model based on a fast, non-destructive technique. In this work, we present preliminary results obtained by a handheld Raman spectrometer and class-modeling (Soft Independent Modeling of Class Analogy, SIMCA), which are extremely promising, showing sensitivity and specificity of 100% for the test set. Moreover, another salient issue, namely the percentage of rind in grated cheese, was addressed by developing a multivariate calibration model based on Raman spectra. It was possible to obtain a prediction error around 5%, with 18% being the maximum content allowed by the production protocol

Time evolution of the microwave second-order response of YBaCuO powder

Transient effects in the microwave second-order response of YBaCuO powder are investigated. The time evolution of the second harmonic signal has been measured for about 300 s after the sample had been exposed to variations of the DC magnetic field. We show that in different time scales the transient response has different origin. In the time scale of milliseconds the transient response of samples in the critical state is ascribable to processes of flux redistribution induced by the switching on/off of the microwave field. At longer times, the time evolution of the second harmonic signal can be ascribed to motion of fluxons induced by the variation of the DC magnetic field. In particular, diffusive motion of fluxons determines the response in the first 10 seconds after the stop of the magnetic field variation; magnetic relaxation over the surface barrier determines the response in the time scale of minutes.Comment: 16 pages, 7 figures, submited to Physica

Superconducting Microwave Cavity Made of Bulk MgB2

We report the successful manufacture and characterization of a microwave resonant cylindrical cavity made of bulk MgB2 superconductor (Tc = 38.5 K), which has been produced by the Reactive Liquid Mg Infiltration technique. The quality factor of the cavity for the TE011 mode, resonating at 9.79 GHz, has been measured as a function of the temperature. At T = 4.2 K, the unloaded quality factor is 2.2x10^5; it remains of the order of 10^5 up to T ~ 30 K. We discuss the potential performance improvements of microwave cavities built from bulk MgB2 materials produced by reactive liquid Mg infiltration.Comment: 7 pages, 2 embedded figures, accepted for publication in Supercond. Sci. Techno

Electromagnetic response of LaO_0.94F_0.06FeAs: AC susceptibility and microwave surface resistance

We discuss on the electromagnetic response of a polycrystalline sample of LaO_0.94F_0.06FeAs exposed to DC magnetic fields up to 10 kOe. The low- and high-frequency responses have been investigated by measuring the AC susceptibility at 100 kHz and the microwave surface resistance at 9.6 GHz. At low as well as high DC magnetic fields, the susceptibility strongly depends on the amplitude of the AC driving field, highlighting enhanced nonlinear effects. The field dependence of the AC susceptibility exhibits a magnetic hysteresis that can be justified considering the intragrain-field-penetration effects on the intergrain critical current density. The microwave surface resistance exhibits a clockwise magnetic hysteresis, which cannot be justified in the framework of the critical-state models of the Abrikosov-fluxon lattice; it may have the same origin as that detected in the susceptibility.Comment: 8 pages, 4 embedded eps figures; Proceedings of the 9th EUCAS Conference (Dresden, Germany, September 13-17, 2009