533 research outputs found
Photoionization of tungsten ions: experiment and theory for W
Experimental and theoretical results are reported for single-photon single
ionization of the tungsten ion W. Absolute cross sections have been
measured employing the photon-ion merged-beams setup at the Advanced Light
Source in Berkeley. Detailed photon-energy scans were performed at 200~meV
bandwidth in the 40 -- 105~eV range. Theoretical results have been obtained
from a Dirac-Coulomb R-matrix approach employing basis sets of 730 levels for
the photoionization of W. Calculations were carried out for the
, =2, ground level and the
associated fine-structure levels with =3 and 4 for the W ions. In
addition, cross sections have been calculated for the metastable levels
. Very satisfying agreement of theory and experiment is
found for the photoionization cross section of W which is remarkable
given the complexity of the electronic structure of tungsten ions in low charge
states.Comment: 15 pages, 3 figures, to appear in the Journal of Physics B: Atomic,
Molecular and Optical Physic
Three Dimensional Mapping of Texture in Dental Enamel
We have used synchrotron x-ray diffraction to study the crystal orientation in human dental enamel as a function of position within intact tooth sections. Keeping tooth sections intact has allowed us to construct 2D and 3D spatial distribution maps of the magnitude and orientation of texture in dental enamel. We have found that the enamel crystallites are most highly aligned at the expected occlusal points for a maxillary first premolar, and that the texture direction varies spatially in a three dimensional curling arrangement. Our results provide a model for texture in enamel which can aid researchers in developing dental composite materials for fillings and crowns with optimal characteristics for longevity, and will guide clinicians to the best method for drilling into enamel, in order to minimize weakening of remaining tooth structure, during dental restoration procedure
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Absolute single photoionization cross-sections of Br3+: Experiment and theory
Absolute single photoionization cross section measurements for Br3+ ions are reported in the photon energy range 44.79-59.54 eV at a photon energy resolution of 21 ±3 meV. Measurements were performed at the Advanced Light Source at Lawrence Berkeley National Laboratory using the merged-beams technique. Numerous resonance features in the experimental spectrum are assigned and their energies and quantum defect values are tabulated. The cross-section measurements are also compared with Breit-Pauli R-matrix calculations with suitable agreement over the photon energy range investigated. Analysis of the measured spectrum including Rydberg resonance series identifications produced a new emperical determination of the ionizational potential of Br3+ of 46.977 ± 0.050 eV, which is 805 meV lower than the most recently published value of 47.782 eV. This disparity between our determination and the earlier published value is similar to an 843 meV shift in the accepted ionization potential published for iso-electronic Se2+ as part of this same research program
Exploitation of SPR to Investigate the Importance of Glycan Chains in the Interaction between Lactoferrin and Bacteria
peer-reviewedBovine lactoferrin (LF) has been shown to prevent adhesion to and invasion of mammalian cell lines by pathogenic bacteria, with evidence for direct bacterial binding by the milk glycoprotein. However, the glycosylation pattern of LF changes over the lactation cycle. In this study, we aim to investigate the effect that this variation has on the milk glycoprotein’s ability to interact with pathogens. Surface plasmon resonance technology was employed to compare the binding of LF from colostrum (early lactation) and mature milk (late lactation) to a panel of pathogenic bacteria (Staphylococcus aureus, Escherichia coli, Cronobacter sakazakii, Streptococcus pneumoniae, Pseudomonas aeruginosa, Listeria monocytogenes and Salmonella typhimurium). Novel interactions with LF were identified for C. sakazakii, S. pneumoniae and P. aeruginosa with the highest binding ability observed for mature milk LF in all cases, with the exception of S. typhimurium. The difference in bacterial binding observed may be as a result of the varying glycosylation profiles. This work demonstrates the potential of LF as a functional food ingredient to prevent bacterial infectio
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Secondary ion mass spectrometry and x-ray absorption near-edge structure spectroscopy of isotopically anomalous organic matter from CR1 chondrites GRO 95577
We located interstellar organics from a CR1 chondrite with NanoSIMS and analyzed FIB-extracted sections with XANES. D-rich material appears not associated with a functional group, whereas 15N-rich matter shows some affinity to nitrile functionality
Single-photon single ionization of W ions: experiment and theory
Experimental and theoretical results are reported for photoionization of
Ta-like (W) tungsten ions. Absolute cross sections were measured in the
energy range 16 to 245 eV employing the photon-ion merged-beam setup at the
Advanced Light Source in Berkeley. Detailed photon-energy scans at 100 meV
bandwidth were performed in the 16 to 108 eV range. In addition, the cross
section was scanned at 50 meV resolution in regions where fine resonance
structures could be observed. Theoretical results were obtained from a
Dirac-Coulomb R-matrix approach. Photoionization cross section calculations
were performed for singly ionized atomic tungsten ions in their , =1/2, ground level and the associated
excited metastable levels with =3/2, 5/2, 7/2 and 9/2. Since the ion beams
used in the experiments must be expected to contain long-lived excited states
also from excited configurations, additional cross-section calculations were
performed for the second-lowest term, 5d^5 \; ^6{\rm S}_{J}, =5/2, and for
the F term, 5d^3 6s^2 \; ^4{\rm F}_{J}, with = 3/2, 5/2, 7/2 and 9/2.
Given the complexity of the electronic structure of W the calculations
reproduce the main features of the experimental cross section quite well.Comment: 23 pages, 7 figures, 1 table: Accepted for publication in J. Phys. B:
At. Mol. & Opt. Phy
Fossil biomass preserved as graphitic carbon in a late paleoproterozoic banded iron formation metamorphosed at more than 550°C
Metamorphism is thought to destroy microfossils, partly through devolatilization and graphitization of biogenic organic matter. However, the extent to which there is a loss of molecular, elemental and isotope signatures from biomass during high-temperature metamorphism is not clearly established. We report on graphitic structures inside and coating apatite grains from the c. 1850 Ma Michigamme silicate banded iron formation from Michigan, metamorphosed above 550°C. Traces of N, S, O, H, Ca and Fe are preserved in this graphitic carbon and X-ray spectra show traces of aliphatic groups. Graphitic carbon has an expanded lattice around 3.6 Å, forms microscopic concentrically-layered and radiating polygonal flakes and has homogeneous δ13C values around −22‰, identical to bulk analyses. Graphitic carbon inside apatite is associated with nanometre-size ammoniated phyllosilicate. Precursors of these metamorphic minerals and graphitic carbon originated from ferruginous clayrich sediments with biomass. We conclude that graphite coatings and inclusions in apatite grains indicate fluid remobilization during amphibolite-facies metamorphism of precursor biomass. This new evidence fills in observational gaps of metamorphosed biomass into graphite and supports the existence of biosignatures in the highly metamorphosed iron formation from the Eoarchean Akilia Association, which dates from the beginning of the sedimentary rock record
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