5,907 research outputs found

    A New Approach toward Transition State Spectroscopy

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    Chirped-Pulse millimetre-Wave (CPmmW) rotational spectroscopy provides a new class of information about photolysis transition state(s). Measured intensities in rotational spectra determine species-isomer-vibrational populations, provided that rotational populations can be thermalized. The formation and detection of S0 vinylidene is discussed in the limits of low and high initial rotational excitation. CPmmW spectra of 193 nm photolysis of Vinyl Cyanide (Acrylonitrile) contain J=0-1 transitions in more than 20 vibrational levels of HCN, HNC, but no transitions in vinylidene or highly excited local-bender vibrational levels of acetylene. Reasons for the non-observation of the vinylidene co-product of HCN are discussed.Comment: Accepted by Faraday Discussion

    Reading with the Tongue: Individual Differences Affect the Perception of Ambiguous Stimuli with the BrainPort

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    There is an increasing interest in non-visual interfaces for HCI to take advantage of the information processing capability of the other sensory modalities. The BrainPort is a vision-to-tactile sensory substitution device that conveys information through electro-stimulation on the tongue. As the tongue is a horizontal surface, it makes for an interesting platform to study the brainā€™s representation of space. But which way is up on the tongue? We provided participants with perceptually ambiguous stimuli and measured how often different perspectives were adopted; furthermore, whether camera orientation and gender had an effect. Additionally, we examined whether personality (trait extraversion and openness) could predict the perspective taken. We found that self-centered perspectives were predominantly adopted, and that trait openness may predict perspective. This research demonstrates how individual differences can affect the usability of sensory substitution devices, and highlights the need for flexible and customisable interfaces

    NLO corrections in MC event generator for angular distribution of Drell-Yan lepton pair production

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    Using a subtraction method, we derive the formulae suitable for use in Monte-Carlo event generators to give the angular distribution for the gluon-quark induced NLO corrections in Drell-Yan lepton pair production. We also give the corresponding helicity density matrix for W and Z boson production.Comment: 14 pages, 2 figure

    Fetal Medial Habenula Transplants: Innervation of the Rat Interpeduncular Nucleus

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    The effects of donor age and site of placement on the survival of fetal medial habenula (MH) transplants into adult rats hosts were examined. The innervation of the interpeduncular nucleus (IPN) in such cases was also examined. Explants of MH consisting of the medial-dorsal lip of the third ventricle were held in vitro for 1ā€”2 days. Colloidal gold conjugated to wheat germ agglutinin was added for the last 18 hours to label the cells. Four of 16 cases with E19 derived transplants contained donor neurons. Markedly larger transplants were present in 95% of 20 cases with E16 derived transplants. Sites in the ventral midbrain were successful, while limited or no survival occurred at sites more remote from IPN. Retrograde labeling of transplant neurons was present in each case studied with HRP injection into host IPN. Colloidal gold-labeled macrophages, some oriented capillaries and GFAP-positive processes marked the donor-host interface. In EM the interface was evident only by the difference in tissue elements in the transplant versus host. Numerous synapses of Gray types I and II were present in the transplant. Excellent survival of MH neurons, donor/host interfaces, innervation of IPN by the transplant and fine structure in and around the transplants, all suggest that such preparations are suitable for further experimental analysis of the habenulo-interpeduncular system

    The impact of tensioning device mal-positioning on strand tension during Anterior Cruciate Ligament reconstruction

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    <p>Abstract</p> <p>Background</p> <p>In order to confer optimal strength and stiffness to the graft in Anterior Cruciate Ligament (ACL) reconstruction, the maintenance of equal strand tension prior to fixation, is desired; positioning of the tensioning device can significantly affect strand tension This study aimed to determine the effect of tensioning device mal-positioning on individual strand tension in simulated cadaveric ACL reconstructions.</p> <p>Methods</p> <p>Twenty cadaveric specimens, comprising bovine tibia and tendon harvested from sheep, were used to simulate ACL reconstruction with a looped four-strand tendon graft. A proprietary tensioning device was used to tension the graft during tibial component fixation with graft tension recorded using load cells. The effects of the tensioning device at extreme angles, and in various locking states, was evaluated.</p> <p>Results</p> <p>Strand tension varied significantly when the tensioning device was held at extreme angles (p < 0.001) or in 'locked' configurations of the tensioning device (p < 0.046). Tendon position also produced significant effects (p < 0.016) on the resultant strand tension.</p> <p>Conclusion</p> <p>An even distribution of tension among individual graft strands is obtained by maintaining the tensioning device in an unlocked state, aligned with the longitudinal axis of the tibial tunnel. If the maintenance of equal strand tension during tibial fixation of grafts is important, close attention must be paid to positioning of the tensioning device in order to optimize the resultant graft tension and, by implication, the strength and stiffness of the graft and ultimately, surgical outcome.</p

    Predicting market squid (Doryteuthis opalescens) landings from pre-recruit abundance

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    The fishery for market squid (Doryteuthis opalescens) in California is typical of many of the worldā€™s cephalopod fisheries, in that a very short life span and the effect of environmental forcing on recruitment result in enormous interannual variability in catches and population size. We evaluate the utility of a pre-recruit index of squid abundance that is based on midwater trawl sampling in the 3ā€“5 months preceding the onset of the fishery as a basis for predicting landings. Catches in the survey largely represent squid in the 30ā€“50 mm dorsal mantle length size range, representing individuals 30ā€“90 day old. Catch-per-unit-effort statistics are derived from simple twofactor Ī”-Generalized Linear Models, with year and station as main effects and numbers per tow as the dependent variable. Regional models for northern and southern squid populations are developed. Pre-recruit indices, as well as indices of squid prey (krill) abundance are compared with landings data, as well as estimates of squid spawning stock biomass derived from an egg escapement model. Our results show that the abundance of prerecruit market squid and krill sampled in the survey tracks both catches and overall population size, providing the potential to forecast landings. Our findings are consistent with a sparse but growing literature showing the potential utility of pre-recruit surveys to inform fisheries participants and managers

    Identifying procedural structure in Cobol programs

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