209 research outputs found
Charge and Orbital Ordering in Pr_{0.5} Ca_{0.5} MnO_3 Studied by ^{17}O NMR
The charge and orbital ordering in Pr_{0.5} Ca_{0.5} MnO_3 is studied for the
first time by ^{17}O NMR. This local probe is sensitive to spin, charge and
orbital correlations. Two transitions exist in this system: the charge and
orbital ordering at T_{CO} = 225 K and the antiferromagnetic (AF) transition at
T_N = 170 K. Both are clearly seen in the NMR spectra measured in a magnetic
field of 7T. Above T_{CO} there exists only one NMR line with a large isotropic
shift, whose temperature dependence is in accordance with the presence of
ferromagnetic (FM) correlations. This line splits into two parts below T_{CO},
which are attributed to different types of oxygen in the charge/orbital ordered
state. The interplay of FM and AF spin correlations of Mn ions in the charge
ordered state of Pr_{0.5} Ca_{0.5} MnO_3 is considered in terms of the hole
hopping motion that is slowed down with decreasing temperature. The developing
fine structure of the spectra evidences, that there still exist
charge-disordered regions at T_{CO} > T > T_N and that the static (t >
10^{-6}s) orbital order is established only on approaching T_N. The CE-type
magnetic correlations develop gradually below T_{CO}, so that at first the AF
correlations between checkerboard ab-layers appear, and only at lower
temperature - CE correlations within the ab-planes
Specific heat and magnetocaloric effect in Pr1-xAgxMnO3 manganites
The magnetocaloric effect in alternating magnetic fields has been
investigated in Pr1-xAgxMnO3 manganites with x=0.05-0.25. The stepwise reversal
of the sign of the magnetocaloric effect has been revealed in a weakly doped
sample (x=0.05) at low temperatures (~80 K). This reversal is attributed to the
coexistence of the ferromagnetic and canted antiferromagnetic phases with
different critical temperatures.Comment: 4 pages, 4 figure
Thickness dependence of the stability of the charge-ordered state in PrCaMnO thin films
Thin films of the charge-ordered (CO) compound PrCaMnO
have been deposited onto (100)-oriented SrTiO substrates using the Pulsed
Laser Deposition technique. Magnetization and transport properties are measured
when the thickness of the film is varied. While the thinner films do not
exhibit any temperature induced insulator-metal transition under an applied
magnetic field up to 9T, for thickness larger than 1100\UNICODE{0xc5} a 5T
magnetic field is sufficient to melt the CO state. For this latest film, we
have measured the temperature-field phase diagram. Compared to the bulk
material, it indicates that the robustness of the CO state in thin films is
strongly depending on the strains and the thickness. We proposed an explanation
based on the distortion of the cell of the film.Comment: 9 pages, 6 figures, submitted to Phys. Rev.
Phase Separation and the Low-Field Bulk Magnetic Properties of Pr0.7Ca0.3MnO3
We present a detailed magnetic study of the perovskite manganite
Pr0.7Ca0.3MnO3 at low temperatures including magnetization and a.c.
susceptibility measurements. The data appear to exclude a conventional spin
glass phase at low fields, suggesting instead the presence of correlated
ferromagnetic clusters embedded in a charge-ordered matrix. We examine the
growth of the ferromagnetic clusters with increasing magnetic field as they
expand to occupy almost the entire sample at H ~ 0.5 T. Since this is well
below the field required to induce a metallic state, our results point to the
existence of a field-induced ferromagnetic insulating state in this material.Comment: 15 pages with figures, submitted to Physical Review
Formation of finite antiferromagnetic clusters and the effect of electronic phase separation in Pr{_0.5}Ca{_0.5}Mn{_0.975}Al{_0.025}O{_3}
We report the first experimental evidence of a magnetic phase arising due to
the thermal blocking of antiferromagnetic clusters in the weakened charge and
orbital ordered system Pr{_0.5}Ca{_0.5}Mn{_0.975}Al{_0.025}O{_3}. The third
order susceptibility (\chi_3) is used to differentiate this transition from a
spin or cluster glass like freezing mechanism. These clusters are found to be
mesoscopic and robust to electronic phase separation which only enriches the
antiphase domain walls with holes at the cost of the bulk, without changing the
size of these clusters. This implies that Al substitution provides sufficient
disorder to quench the length scales of the striped phases.Comment: 4 Post Script Figure
X-ray Resonant Scattering Studies of Orbital and Charge Ordering in PrCaMnO
We present the results of a systematic x-ray scattering study of the charge
and orbital ordering in the manganite series PrCaMnO with
=0.25, 0.4 and 0.5. The temperature dependence of the scattering at the
charge and orbital wavevectors, and of the lattice constants, was characterized
throughout the ordered phase of each sample. It was found that the charge and
orbital order wavevectors are commensurate with the lattice, in striking
contrast to the results of earlier electron diffraction studies of samples with
=0.5. High momentum-transfer resolution studies of the x=0.4 and 0.5 samples
further revealed that while long-range charge order is present, long-range
orbital order is never established. Above the charge/orbital ordering
temperature T, the charge order fluctuations are more highly correlated
than the orbital fluctuations. This suggests that charge order drives orbital
order in these samples. In addition, a longitudinal modulation of the lattice
with the same periodicity as the charge and orbital ordering was discovered in
the x=0.4 and 0.5 samples. For x=0.25, only long-range orbital order was
observed with no indication of charge ordering, nor of an additional lattice
modulation. We also report the results of a preliminary investigation of the
loss of charge and orbital ordering in the x=0.4 sample by application of a
magnetic field. Finally, the polarization and azimuthal dependence of the
charge and orbital ordering in these compounds is characterized both in the
resonant and nonresonant limits, and compared with the predictions of current
theories. The results are qualitatively consistent with both cluster and LDA+U
calculations of the electronic structure.Comment: 37 pages, 22 figure
High magnetic field transport measurement of charge-ordered PrCaMnO strained thin films
We have investigated the magnetic-field-induced phase transition of
charge-ordered (CO) PrCaMnO thin films, deposited onto
(100)-oriented LaAlO and (100)-oriented SrTiO substrates using the
pulsed laser deposition technique, by measuring the transport properties with
magnetic fields up to 22T. The transition to a metallic state is observed on
both substrates by application of a critical magnetic field ( at 60K).
The value of the field required to destroy the charge-ordered insulating state,
lower than the bulk compound, depends on both the substrate and the thickness
of the film. The difference of the critical magnetic field between the films
and the bulk material is explained by the difference of in-plane parameters at
low temperature (below the CO transition). Finally, these results confirm that
the robustness of the CO state, depends mainly on the stress induced by the
difference in the thermal dilatations between the film and the substrate.Comment: 10 pages, 6 figures. To be published in Phys. Rev.
- …