3,492 research outputs found
Remote sensing applications in forestry. The development of an earth resources information system using aerial photographs and digital computers photographs and digital computers
Remote aerial sensing and automatic mapping for forest resources information syste
Self-assembly of the simple cubic lattice with an isotropic potential
Conventional wisdom presumes that low-coordinated crystal ground states
require directional interactions. Using our recently introduced optimization
procedure to achieve self-assembly of targeted structures (Phys. Rev. Lett. 95,
228301 (2005), Phys. Rev. E 73, 011406 (2006)), we present an isotropic pair
potential for a three-dimensional many-particle system whose classical
ground state is the low-coordinated simple cubic (SC) lattice. This result is
part of an ongoing pursuit by the authors to develop analytical and
computational tools to solve statistical-mechanical inverse problems for the
purpose of achieving targeted self-assembly. The purpose of these methods is to
design interparticle interactions that cause self-assembly of technologically
important target structures for applications in photonics, catalysis,
separation, sensors and electronics. We also show that standard approximate
integral-equation theories of the liquid state that utilize pair correlation
function information cannot be used in the reverse mode to predict the correct
simple cubic potential. We report in passing optimized isotropic potentials
that yield the body-centered cubic and simple hexagonal lattices, which provide
other examples of non-close-packed structures that can be assembled using
isotropic pair interactions.Comment: 16 pages, 12 figures. Accepted for publication in Physical Review
An order parameter equation for the dynamic yield stress in dense colloidal suspensions
We study the dynamic yield stress in dense colloidal suspensions by analyzing
the time evolution of the pair distribution function for colloidal particles
interacting through a Lennard-Jones potential. We find that the equilibrium
pair distribution function is unstable with respect to a certain anisotropic
perturbation in the regime of low temperature and high density. By applying a
bifurcation analysis to a system near the critical state at which the stability
changes, we derive an amplitude equation for the critical mode. This equation
is analogous to order parameter equations used to describe phase transitions.
It is found that this amplitude equation describes the appearance of the
dynamic yield stress, and it gives a value of 2/3 for the shear thinning
exponent. This value is related to the mean field value of the critical
exponent in the Ising model.Comment: 8 pages, 2 figure
Electric-field-induced displacement of a charged spherical colloid embedded in an elastic Brinkman medium
When an electric field is applied to an electrolyte-saturated polymer gel
embedded with charged colloidal particles, the force that must be exerted by
the hydrogel on each particle reflects a delicate balance of electrical,
hydrodynamic and elastic stresses. This paper examines the displacement of a
single charged spherical inclusion embedded in an uncharged hydrogel. We
present numerically exact solutions of coupled electrokinetic transport and
elastic-deformation equations, where the gel is treated as an incompressible,
elastic Brinkman medium. This model problem demonstrates how the displacement
depends on the particle size and charge, the electrolyte ionic strength, and
Young's modulus of the polymer skeleton. The numerics are verified, in part,
with an analytical (boundary-layer) theory valid when the Debye length is much
smaller than the particle radius. Further, we identify a close connection
between the displacement when a colloid is immobilized in a gel and its
velocity when dispersed in a Newtonian electrolyte. Finally, we describe an
experiment where nanometer-scale displacements might be accurately measured
using back-focal-plane interferometry. The purpose of such an experiment is to
probe physicochemical and rheological characteristics of hydrogel composites,
possibly during gelation
Electrophoresis of a polyelectrolyte through a nanopore
A hydrodynamic model for determining the electrophoretic speed of a
polyelectrolyte through a nanopore is presented. It is assumed that the speed
is determined by a balance of electrical and viscous forces arising from within
the pore and that classical continuum electrostatics and hydrodynamics may be
considered applicable. An explicit formula for the translocation speed as a
function of the pore geometry and other physical parameters is obtained and is
shown to be consistent with experimental measurements on DNA translocation
through nanopores in silicon membranes. Experiments also show a weak dependence
of the translocation speed on polymer length that is not accounted for by the
present model. It is hypothesized that this is due to secondary effects that
are neglected here.Comment: 5 pages, 2 column, 2 figure
Colloidal Electrostatic Interactions Near a Conducting Surface
Charge-stabilized colloidal spheres dispersed in deionized water are supposed
to repel each other. Instead, artifact-corrected video microscopy measurements
reveal an anomalous long-ranged like-charge attraction in the interparticle
pair potential when the spheres are confined to a layer by even a single
charged glass surface. These attractions can be masked by electrostatic
repulsions at low ionic strengths. Coating the bounding surfaces with a
conducting gold layer suppresses the attraction. These observations suggest a
possible mechanism for confinement-induced attractions.Comment: 4 pages, 2 figure
Integration through transients for Brownian particles under steady shear
Starting from the microscopic Smoluchowski equation for interacting Brownian
particles under stationary shearing, exact expressions for shear-dependent
steady-state averages, correlation and structure functions, and
susceptibilities are obtained, which take the form of generalized Green-Kubo
relations. They require integration of transient dynamics. Equations of motion
with memory effects for transient density fluctuation functions are derived
from the same microscopic starting point. We argue that the derived formal
expressions provide useful starting points for approximations in order to
describe the stationary non-equilibrium state of steadily sheared dense
colloidal dispersions.Comment: 17 pages, Submitted to J. Phys.: Condens. Matter; revised version
with minor correction
Transporters: Importance in Drug Absorption, Distribution, and Removal
Abstract There is an increasing appreciation of the role that transport proteins play in the absorption, distribution, and elimination of a wide variety of drugs in clinical use. These transporters can be divided into efflux transporters belonging to the ATP-binding cassette (ABC) family and solute carrier (SLC) family members that mediate the influx or bidirectional movement of drugs across the cell membrane. Their coordinated expression and activities at the basolateral and apical side of transporting epithelia are significant determinants of drug disposition, drug-drug interactions, and variability in drug response and toxicity. This chapter focuses on the major SLC and ABC drug transporters expressed in intestine, liver, and kidney, with special emphasis on their distribution, mode of action, and drug substrate specificity
Non--Newtonian viscosity of interacting Brownian particles: comparison of theory and data
A recent first-principles approach to the non-linear rheology of dense
colloidal suspensions is evaluated and compared to simulation results of
sheared systems close to their glass transitions. The predicted scenario of a
universal transition of the structural dynamics between yielding of glasses and
non-Newtonian (shear-thinning) fluid flow appears well obeyed, and calculations
within simplified models rationalize the data over variations in shear rate and
viscosity of up to 3 decades.Comment: 6 pages, 2 figures; J. Phys. Condens. Matter to be published (Jan.
2003
Shear-induced reaction-limited aggregation kinetics of Brownian particles at arbitrary concentrations
The aggregation of interacting Brownian particles in sheared concentrated
suspensions is an important issue in colloid and soft matter science per se.
Also, it serves as a model to understand biochemical reactions occurring in
vivo where both crowding and shear play an important role. We present an
effective medium approach within the Smoluchowski equation with shear which
allows one to calculate the encounter kinetics through a potential barrier
under shear at arbitrary colloid concentrations. Experiments on a model
colloidal system in simple shear flow support the validity of the model in the
range considered. By generalizing Kramers' rate theory to the presence of
collective hydrodynamics, our model explains the significant increase in the
shear-induced reaction-limited aggregation kinetics upon increasing the colloid
concentration
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