Role of Solvent Compatibility in the Phase Behavior of Binary Solutions of Weakly Associating Multivalent Polymers

[Image: see text] Condensate formation of biopolymer solutions, prominently those of various intrinsically disordered proteins (IDPs), is often driven by “sticky” interactions between associating residues, multivalently present along the polymer backbone. Using a ternary mean-field “stickers-and-spacers” model, we demonstrate that if sticker association is of the order of a few times the thermal energy, a delicate balance between specific binding and nonspecific polymer–solvent interactions gives rise to a particularly rich ternary phase behavior under physiological circumstances. For a generic system represented by a solution comprising multiassociative scaffold and client polymers, the difference in solvent compatibility between the polymers modulates the nature of isothermal liquid–liquid phase separation (LLPS) between associative and segregative. The calculations reveal regimes of dualistic phase behavior, where both types of LLPS occur within the same phase diagram, either associated with the presence of multiple miscibility gaps or a flip in the slope of the tie-lines belonging to a single coexistence region

Heavy fermion superconductivity and magnetic order in non-centrosymmetric CePt3SiCePt_3Si

$\rm CePt_3Si$ is a novel heavy fermion superconductor, crystallising in the $\rm CePt_3B$ structure as a tetragonally distorted low symmetry variant of the $\rm AuCu_3$ structure type. $\rm CePt_3Si$ exhibits antiferromagnetic order at $T_N \approx 2.2$ K and enters into a heavy fermion superconducting state at $T_c \approx 0.75$ K. Large values of $H_{c2}' \approx -8.5$ T/K and $H_{c2}(0) \approx 5$ T refer to heavy quasiparticles forming Cooper pairs. Hitherto, $\rm CePt_3Si$ is the first heavy fermion superconductor without a center of symmetry.Comment: 4 pages, 4 figure

AC/DC Susceptibility of the Heavy-Fermion Superconductor CePt3Si under Pressure

We have investigated the pressure dependence of ac and dc susceptibilities of the heavy-fermion superconductor CePt3Si (Tc= 0.75 K) that coexists with antiferromagnetism (TN = 2.2 K). As hydrostatic pressure is increased, Tc first decreases rapidly, then rather slowly near the critical pressure Pc = 0.6 GPa and shows a stronger decrease again at higher pressures, where Pc is the pressure at which TN becomes zero. A transition width and a difference in the two transition temperatures defined in the form of structures in the out-of-phase component of ac susceptibilities also become small near Pc, indicating that a double transition observed in CePt3Si is caused by some inhomogeneous property in the sample that leads to a spatial variation of local pressure. A sudden increase in the Meissner fraction above Pc suggests the influence of antiferromagnetism on superconductivity.Comment: 4 pages with 5 figures. This paper will be published in J. Phys. Soc. Jp

Low field extension for magnetometers (TinyBee) used for investigations on low-dimensional superconductors with Bc1 < 5G

In this article a simple and easy to install low magnetic field extension of the SQUID magnetometer Quantum Design MPMS-7 is described. This has been accomplished by complementing the MPMS-7 magnet control system with a laboratory current supply for the low magnetic field region (B \leq 200G). This hard- and software upgrade provides a significant gain in the magnetic field accuracy up to an order of magnitude compared with the standard instrument's setup and is improving the resolution to better than 0.01G below 40G. The field control has been integrated into the Quantum Design MultiVu software for a transparent and user-friendly operation of this extension. The improvements achieved are especially useful, when low magnetic field strengths (B < 1G) are required at high precision. The specific advantages of this application are illustrated by sophisticated magnetic characterisation of lowdimensional superconductors like Sc3CoC4 and SnSe2{Co({\eta}-C5H5)2}x.Comment: 16 pages, 7 figure

Heavy-Fermions in LiV2O4: Kondo-Compensation vs. Spin-Liquid Behavior?

7Li NMR measurements were performed in the metallic spinel LiV2O4. The temperature dependencies of the line width, the Knight shift and the spin-lattice relaxation rate were investigated in the temperature range 30 mK < T < 280 K. For temperatures T < 1 K we observe a spin-lattice relaxation rate which slows down exponentially. The NMR results can be explained by a spin-liquid behavior and the opening of a spin gap of the order 0.6 K

Transport properties of moderately disordered UCu4_4Pd

We present a detailed study on the (magneto)transport properties of as-cast and heat treated material UCu$_4$Pd. We find a pronounced sample dependence of the resistivity $\rho$ of as-cast samples, and reproduce the annealing dependence of $\rho$. In our study of the Hall effect we determine a metallic carrier density for all samples, and a temperature dependence of the Hall constant which is inconsistent with the Skew scattering prediction. The magnetoresistive response is very small and characteristic for spin disorder scattering, suggesting that overall the resistivity is controlled mostly by nonmagnetic scattering processes. We discuss possible sources for the temperature and field dependence of the transport properties, in particular with respect to quantum criticality and electronic localization effects.Comment: 11 pages, 9 figures, submitted PR

Probiotics in Aquaculture Review: Current Status and Application in Tambaqui Cultivation (Colossoma macropomum)

The development of aquaculture guarantees the supply of animal protein of great nutritional value, contributing to food security. Currently one of the main problems faced is the occurrence of diseases, responsible for a worldwide economic loss, equivalent to US $ 9 billion per year. Aiming to increase resistance to diseases, increasing growth rates and food efficiency in intensive crops, some strategies have been developed, one of them is the use of probiotic bacteria. These, when in contact with the digestive tract of the host generates a series of benefits, among them, the modulation of the immune system, developing defense mechanisms and increasing resistance to stress. However, there are few documented reports on the efficiency of probiotics in native species, such as tambaqui (Colossoma macropomum). This species shows some resistance to stress, through physiological mechanisms of adaptation, such as lip expansion when subjected to hypoxia situations, which added to the positive effects of using probiotics would represent an increase in its resistance. The purpose of this work is to review the literature on the use of probiotics in aquaculture in order to provide a comprehensive synthesis of the current knowledge about its use in aquaculture, with emphasis on the intensive cultivation of tambaqui

Evolution of quantum criticality in the system CeNi9Ge4

The heavy fermion system CeNi9Ge4 exhibits a paramagnetic ground state with remarkable features such as: a record value of the electronic specific heat coefficient in systems with a paramagnetic ground state, \gamma = C/T \simeq 5.5 J/molK^2 at 80 mK, a temperature-dependent Sommerfeld-Wilson ratio, R=\chi/\gamma, below 1 K and an approximate single ion scaling of the 4f-magnetic specific heat and susceptibility. These features are related to a rather small Kondo energy scale of a few Kelvin in combination with a quasi-quartet crystal field ground state. Tuning the system towards long range magnetic order is accomplished by replacing a few at.% of Ni by Cu or Co. Specific heat, susceptibility and resistivity studies reveal T_N \sim 0.2 K for CeNi8CuGe4 and T_N \sim 1 K for CeNi8CoGe4. To gain insight whether the transition from the paramagnetic NFL state to the magnetically ordered ground state is connected with a heavy fermion quantum critical point we performed specific heat and ac susceptibility studies and utilized the \mu SR technique and quasi-elastic neutron scattering.Comment: 8 pages, 3 figures, will be published in J.Phys.: Conf. Series (Proceedings of the International & Interdisciplinary Workshop on Novel Phenomena in Intergrated Comples Sciences: From Living to Non-living Systems, Japan, held in Kyoto, October 11-14, 2010